Method and apparatus for pyrolytically decomposing waste plastic

• US 6,172,275 B1
• Filed: 03/03/1998
• Issued: 01/09/2001
• Est. Priority Date: 12/20/1991
• Status: Expired due to Fees

• Current Assignee: Hispano Suiza Aerostructures (Safran SA), Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Original Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Inventors: Kanazawa, Satoshi, Ito, Isao, Tezuka, Fuminobu, Gotanda, Takeshi, Koyama, Masao, Hayata, Terunobu, Kano, Jiro, Shimada, Hideki, Suzuki, Kazuo, Tadauchi, Masahiro, Maezawa, Yukishige
• Primary Examiner(s): Griffin, Steven P.
• Assistant Examiner(s): Hendrickson, Stuart L.
• Application Number:
  US09/033,921
• Time in Patent Office: 1,043 Days
• Field of Search: 585/240, 585/241, 423/481, 423/488, 201/2.5, 588/213, 588/216, 588/226, 588/228
• US Class Current: 423/481
• CPC Class Codes: C10G 1/00 Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal mechanical winning of oil from oil-shales, oil-sand, or the like B03B
• CPC Class Codes: C10G 1/006 Combinations of processes provided in groups C10G1/02 - C10G1/08
• CPC Class Codes: C10G 1/02 by distillation
• CPC Class Codes: C10G 1/10 from rubber or rubber waste

Abstract

Disclosed is a method and apparatus for pyrolytically decomposing waste plastic which may contain halogen-containing polymer such as PVC. The plastic is heated at 270° to 350° C., whereby a plasticizer contained in the plastic material is decomposed and vaporized, and a chlorine-containing polymer is dechlorinated to produce hydrogen chloride. The vaporized decomposition matter and the hydrogen chloride are removed from the plastic, and the vaporized decomposition matter is separated from the hydrogen chloride. Then isolated plastic is further heated to 450° C. or higher to produce a pyrolysis product. Alternatively, the former heating step is divided into two steps of: heating at a temperature lower than 270° C., whereby a plasticizer is decomposed; and heating to 270° to 350° C., whereby a chlorine-containing polymer contained in the plastic material is dechlorinated. Accordingly, the decomposition matter of plasticizer and hydrogen chloride are separately removed from the plastic.

Claims

1. A method of pyrolytically decomposing a plastic material, comprising the steps of:

heating the plastic material at approximately 270 to 350°

C., whereby a plasticizer contained in the plastic material is decomposed into a decomposition matter which is vaporized, and a chlorine-containing polymer contained in the plastic material is dechlorinated to produce a dechlorinated matter and hydrogen chloride;

removing the vaporized decomposition matter and the hydrogen chloride, from the plastic material heated at the heating step;

separating the vaporized decomposition matter from the hydrogen chloride by cooling the vaporized decomposition matter with a cooling oil which absorbs the decomposition matter and condensing the vaporized decomposition matter; and

pyrolytrically decomposing the plastic material after the removing step, by heating the plastic material at approximately 450°

C. or a temperature higher than 450°

C. to produce a pyrolysis product.

2. The pyrolytic decomposition method of claim 1, wherein the plasticizer includes a phthalic ester which is selected from the group consisting of di(2-ethylhexyl) phthalate, dibutyl phthalate, diheptyl phthalate, di(isodecyl) phthalate and di(isononyl) phthalate.

3. The pyrolytic decomposition method of claim 1, wherein the plasticizer includes a phthalic ester which is selected from the group consisting of di(2-ethylhexyl) isophthalate, di(n-octyl) phthalate, dinonyl phthalate, dilauryl phthalate, butyl lauryl phthalate, butyl benzyl phthalate, dihydroabietyl phthalate, di(butoxyethyl) phthalate, di(2-methoxyethyl) phthalate, dicapryl phthalate, di(ethoxyethyl) phthalate, di(2-ethylbutyl) phthalate, diethyl phthalate, di(isoamyl) phthalate, di(isobutyl) phthalate, di(isooctyl) phthalate, di(isooctyl) isophthalate, di(methylcyclohexyl) phthalate, dimethylisobutylcarbinyl phthalate, dimethyl isophthalate, n-octyl, n-decyl phthalate, diphenyl phthalate, dipropyl phthalate and ditetrahydrofurfuryl phthalate.

4. The pyrolytic decomposition method of claim 1, wherein the chlorine-containing polymer includes a polymer selected from the group consisting of polyvinyl chloride, polyvinylidene chloride, polyvinylidene chloride-polyvinyl chloride copolymer, chlorinated polyether, chlorinated polyvinyl chloride and chlorinated polyolefin which includes chlorinated polyethylene and chlorinated polypropylene.

5. The pyrolytic decomposition method of claim 1, wherein the removing step comprises:

reducing the pressure of the atmosphere surrounding the plastic material so that the vaporized decomposition matter and the hydrogen chloride are biased to move out of the heated plastic material.

6. The pyrolytic decomposition method of claim 1, wherein the removing step comprises:

carrying away the vaporized decomposition matter and the hydrogen chloride from the heated plastic material with a non-oxidizing carrier gas flow to the heated plastic material.

7. The pyrolytic decomposition method of claim 1, further comprising:

contacting the hydrogen chloride separated at the separating step with water to recover the hydrogen chloride as hydrochloric acid.

8. A method of pyrolytically decomposing a plastic material, comprising the steps of:

heating the plastic material at approximately 270 to 350°

C. whereby a plasticizer, including an ester compound and contained in the plastic material, is decomposed into a decomposition matter which is vaporized, and a chlorine-containing polymer contained in the plastic material is dechlorinated to produce a dechlorinated matter and hydrogen chloride;

removing the vaporized decomposition matter and the hydrogen chloride, from the heated plastic material;

separating the vaporized decomposition matter and the hydrogen chloride by cooling the vaporized decomposition matter with a cooling oil which absorbs the decomposition matter, and condensing the vaporized decomposition matter; and

pyrolytically decomposing the plastic material after removal of the vaporized decomposition matter and the hydrogen chloride, by heating the plastic material at approximately 450°

C. or a temperature higher than 450°

C. to produce a pyrolysis product.