Image forming method

• US 6,174,646 B1
• Filed: 10/16/1998
• Issued: 01/16/2001
• Est. Priority Date: 10/21/1997
• Status: Expired due to Term

• Current Assignee: Konica Corporation (Konica Minolta Inc.)
• Original Assignee: Konica Corporation (Konica Minolta Inc.)
• Inventors: Honda, Junko, Hirai, Katsura, Hattori, Ryoji
• Primary Examiner(s): Baxter, Janet
• Assistant Examiner(s): GILLIAM, BARBARA LEE
• Application Number:
  US09/174,058
• Time in Patent Office: 823 Days
• Field of Search: 430/270.1, 430/302, 430/325, 430/330, 430/944, 430/399, 396/626, 396/604, 396/627
• US Class Current: 430/302
• CPC Class Codes: B41C 1/1008 by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials
• CPC Class Codes: B41C 1/1016 characterised by structural details, e.g. protective layers, backcoat layers or several imaging layers
• CPC Class Codes: B41C 2201/06 Backcoats; Back layers
• CPC Class Codes: B41C 2201/10 characterised by inorganic compounds, e.g. pigments
• CPC Class Codes: B41C 2210/02 Positive working, i.e. the exposed (imaged) areas are removed
• CPC Class Codes: B41C 2210/04 Negative working, i.e. the non-exposed (non-imaged) areas are removed
• CPC Class Codes: B41C 2210/06 Developable by an alkaline solution
• CPC Class Codes: B41C 2210/22 characterised by organic non-macromolecular additives, e.g. dyes, UV-absorbers, plasticisers
• CPC Class Codes: B41C 2210/24 characterised by a macromolecular compound or binder obtained by reactions involving carbon-to-carbon unsaturated bonds, e.g. acrylics, vinyl polymers
• CPC Class Codes: B41C 2210/262 Phenolic condensation polymers, e.g. novolacs, resols
• CPC Class Codes: Y10S 430/145 Infrared

Abstract

Disclosed is an image forming method comprising the steps of imagewise heating or imagewise exposing to a laser with a wavelength of 700 to 1200 nm an image forming material; and continuously developing the exposed or heated material with a developer, while the developer is replenished with a developer replenisher, wherein the image forming material comprises a support and provided thereon, a radiation sensitive layer containing a dye having an absorption band in the wavelength region of from 700 nm to 1200 nm, an acid generating compound capable of generating an acid on irradiation of heat or actinic light, and an acid decomposable compound having a bond capable of being decomposed by an acid, the acid decomposable compound being decomposed by an acid to produce a diol compound containing an ethylene glycol component or a propylene glycol component.

Claims

1. An image forming method comprising:

a) imagewise heating, or imagewise exposing, an image forming material to a laser with a wavelength of 700 to 1200 nm; and

b) developing the exposed or heated material with a developer,

wherein the image forming material comprises a support and provided thereon, a radiation sensitive layer containing a dye having an absorption band in the wavelength region of from 700 nm to 1200 nm, an acid generating compound capable of generating an acid on irradiation of heat or actinic light, and an acid decomposable compound having a bond capable of being decomposed by an acid, the acid decomposable compound being decomposed by an acid to produce a diol compound containing an ethylene glycol component or a propylene glycol component, and wherein the dye is a cyanine dye represented by formula (2or (3);

 

wherein Z₁ and Z₂ independently represent a sulfur atom, a selenium atom or an oxygen atom;

X₁ and X₂ independently represent a non-metallic atomic group necessary to form a benzene or naphthalene ring, which may have a substituent;

R₃ and R₄ independently represent a substituent;

R₅, R₆, R₇ and R₈ independently represent a hydrogen atom, a halogen atom or an alkyl group having 1 to 3 carbon atoms; and

L represents a linkage with a conjugated bond having 5 to 13 carbon atoms.

2. The image forming method of claim 1, wherein the acid generating compound does not have an absorption band in the wavelength region of 400 nm or more.

3. The image forming method of claim 2, wherein the acid generating compound is at least one selected from an organic halogen containing compound and a diphenyl iodonium salt.

4. The image forming method of claim 3, wherein the organic halogen containing compound is an s-triazine compound.

5. The image forming method of claim 1, wherein an absorption maximum wavelength λ

max of the acid generating compound is in the range of from 200 to 360 nm.

6. The image forming method of claim 1, wherein the radiation sensitive layer further contains a resin which is insoluble in water and is soluble in an alkali.

7. The image forming method of claim 1, wherein the acid decomposable compound is an acetal or a silyl ether.

8. The image forming method of claim 1, wherein the acid decomposable compound is decomposed by an acid to produce an aldehyde, a ketone or a silyl compound each having a solubility in 25°

C. water of 1 to 100 g/liter.

9. The image forming method of claim 1, wherein the developer contains a silicate.

10. The image forming method of claim 9, wherein the content ratio by mole of the silicate to an alkali metal in the developer is in the range of from 0.15 to 1.0.

11. The image forming method of claim 1, wherein the developer further contains an organic solvent having a solubility in 25°

C. water of 10 weight % or less.

12. The image forming method of claim 1, wherein the developing is continuously carried out while the developer is replenished with a developer replenisher.

13. The image forming method of claim 1 wherein at least 500 m² of exposed or heated image forming materials is continuously developed with the developer.

14. The image forming method of claim 13, wherein 1000 m² or more of exposed image forming materials are continuously developed.

15. The image forming method of claim 13, wherein 3000 m² or more of exposed image forming materials are continuously developed.

16. The image forming method of claim 13 wherein the developer is replenished with a developer replenisher and the replenishing amount of the developer replenisher is 5 to 100 ml per m² of image forming material to be processed.

17. The image forming method of claim 16, wherein the developer is replenished with the developer replenisher in an amount of 5 to 50 ml per m² of image forming material to be processed.

18. The image forming method of claim 16, wherein the developer is replenished with the developer replenisher in an amount of 5 to 25 ml per m² of image forming material to be processed.

19. The image forming method of claim 1 wherein R₃ and R₄ independently represent an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, or —

((CH₂)_n—

O—

)_k—

(CH₂)_mOR, in which each of n and m independently is an integer of 1 to 3, k is 0 or 1, and R is an alkyl group having 1 to 5 carbon atoms;

or one of R₃ or R₄ is —

RSO₃M, and the other is —

RSO₃⁻

, wherein R represents an alkylene group having 1 to 5 carbon atoms, and M represents an alkali metal atom;

or one of R₃ and R₄ is —

RCOOM, and the other is —

RCOO⁻

, wherein R represents an alkylene group having 1 to 5 carbon atoms, and M represents an alkali metal atom.

20. An image forming material comprising

a support, and

a radiation sensitive layer containing a dye having an absorption band in a wavelength region of from 700 nm to 1200 nm, an acid generating compound capable of generating an acid on irradiation of heat or actinic light, and an acid decomposable compound having a bond capable of being decomposed by an acid,

wherein the acid decomposable compound is decomposed by an acid to produce a diol compound containing an ethylene glycol component or a propylene glycol component, and wherein the dye is a cyanine dye represented by formula (2) or (3):

 

wherein Z₁ and Z₂ independently represent a sulfur atom, a selenium atom or an oxygen atom;

X₁ and X₂ independently represent a non-metallic atomic group necessary to form a benzene or naphthalene ring, which may have a substituent;

R₃ and R₄ independently represent a substituent;

R₅, R₆, R₇ and R₈ independently represent a hydrogen atom, a halogen atom or an alkyl group having 1 to 3 carbon atoms; and

L represents a linkage with a conjugated bond having 5 to 13 carbon atoms.

21. The image forming material of claim 20 wherein R₃ and R₄ independently represent an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, or —

((CH₂)_n—

O—

)_k—

(CH₂)_mOR, in which each of n and m independently is an integer of 1 to 3, k is 0 or 1, and R is an alkyl group having 1 to 5 carbon atoms;

or one of R₃ and R₄ is —

RSO₃M, and the other is —

RSO₃⁻

, in which R represents an alkylene group having 1 to 5 carbon atoms, and M represents an alkali metal atom;

or one of R₃ and R₄ is —

RCOOM, and the other is —

RCOO⁻

, in which R is an alkylene group having 1 to 5 carbon atoms, and M is an alkali metal atom.