Water-based coloring compositions containing submicron polymeric particles

• US 6,174,938 B1
• Filed: 05/21/1999
• Issued: 01/16/2001
• Est. Priority Date: 05/21/1999
• Status: Expired due to Term

• Current Assignee: Crayola LLC (Hallmark Cards Incorporated)
• Original Assignee: Binney & Smith Inc.
• Inventors: Miller, Richard E., Santini, Andree F., Sutton, Terry L. Sr.
• Primary Examiner(s): Cain, Edward J.
• Assistant Examiner(s): WYROZEBSKI LEE, KATARZYNA I
• Application Number:
  US09/316,464
• Time in Patent Office: 606 Days
• Field of Search: 523/160, 523/161, 523/164, 428/402, 428/402.21, 428/402.22, 428/403, 106/31.25, 106/31.65, 106/31.71, 106/31.6, 524/421
• US Class Current: 523/164
• CPC Class Codes: C09D 11/16 Writing inks

Abstract

A water-based coloring composition suitable for use in children'"'"'s markers comprising a carrier, submicron polymeric particles, and a neutral buoyancy additive. The coloring compositions produce unique opaque images on a wide variety of writing surfaces. Additionally, the invention includes a water-based dry erase coloring composition suitable for use in children'"'"'s markers comprising a carrier, submicron polymeric particles, a neutral buoyancy additive, and a release agent.

Claims

1. A water-based coloring composition suitable for use in markers comprising:

(a) a carrier comprising water;

(b) submicron polymeric particles; and

,

(c) a neutral buoyancy additive present in an amount sufficient to render the specific gravity of said carrier about equal to or greater than the specific gravity of said polymeric particles.

2. The water-based coloring composition according to claim 1, wherein said submicron polymeric particles are modified with compounds selected from the group consisting of dyes, pigments, and mixtures thereof.

3. The water-based coloring composition according to claim 1, wherein said submicron polymeric particles are solid.

4. The water-based coloring composition according to claim 1, wherein said submicron polymeric particles have an outer polymeric shell which defines an inner hollow region.

5. The water-based coloring composition according to claim 4, wherein the inner hollow region of said submicron polymeric particles contains water.

6. The water-based coloring composition according to claim 5, further comprising solid submicron polymeric particles.

7. The water-based coloring composition according to claim 3, further comprising modified submicron polymeric particles.

8. The water-based coloring composition according to claim 4, further comprising modified submicron polymeric particles.

9. The water-based coloring composition according to claim 1, wherein said submicron polymeric particles are microspheres.

10. The water-based coloring composition according to claim 1, wherein said submicron polymeric particles are present in an amount of from about 5% by weight to about 80% by weight of the coloring composition.

11. The water-based coloring composition according to claim 1, wherein said neutral buoyancy additive is a water-soluble inorganic salt.

12. The water-based coloring composition according to claim 11, wherein said water-soluble inorganic salt is selected from the group consisting of sodium sulfate, sodium chloride, sodium phosphate, and potassium chloride.

13. The water-based coloring composition according to claim 1, wherein said neutral buoyancy additive is a water-soluble organic compound.

14. The water-based coloring composition according to claim 13, wherein said water-soluble organic compound is selected from the group consisting of sugar, starch, glycerin, organic salt, and mixtures thereof.

15. The water-based coloring composition according to claim 1, wherein said coloring composition has a density of about 8.0 lbs/gal to about 9.0 lbs/gal.

16. The water-based coloring composition according to claim 15, wherein said neutral buoyancy additive is present in an amount of from about 0.5% to about 30% by weight of the coloring composition.

17. The water-based coloring composition according to claim 15, wherein said coloring composition has a viscosity of from about 1 to about 20 centipoises.

18. The water-based coloring compositions according to claim 15, further comprising a release agent.

19. The water-based coloring compositions according to claim 15, further comprising a colorant.

20. The water-based coloring composition according to claim 15, further comprising a dispersing agent.

21. The water-based coloring composition according to claim 15, further comprising an anionic dyeblocker in an amount sufficient to enhance the fugitivity of said compositions from skin.

22. The water-based coloring composition according to claim 21, wherein said anionic dyeblocker is an aromatic organic sulfonate.

23. The water-based coloring composition according to claim 22, wherein said aromatic organic sulfonate is 10 selected from the group consisting of a sulfonated phenol-formaldehyde condensation product, a naphthalene condensation product, and mixtures thereof.

24. A water-based dry erase coloring composition suitable for use in markers comprising:

(a) a carrier comprising water;

(b) submicron polymeric particles;

(c) a neutral buoyancy additive present in an amount sufficient to render the specific gravity of said carrier about equal to or greater than the specific gravity of said polymeric particles; and

,

(d) a release agent.

25. A marking instrument for applying a coloring composition comprising a nib and a reservoir wherein said reservoir contains a water-based coloring composition comprising:

(a) a carrier comprising water;

(b) submicron polymeric particles; and

,

(c) a neutral buoyancy additive present in an amount sufficient to render the specific gravity of said carrier about equal to or greater than the specific gravity of said polymeric particles.