Method for reducing formation of polychlorinated aromatic compounds during oxychlorination of C1-C3 hydrocarbons

• US 6,177,599 B1
• Filed: 11/17/1995
• Issued: 01/23/2001
• Est. Priority Date: 11/17/1995
• Status: Expired due to Term

• Current Assignee: OXY Vinyls LP (Occidental Petroleum Corporation)
• Original Assignee: OXY Vinyls LP (Occidental Petroleum Corporation)
• Inventors: Popiel, Lawrence, Johnston, Victor James, Cowfer, Joseph Allen
• Primary Examiner(s): Dees, Jose′ G.
• Assistant Examiner(s): Bembenick, Brian G.
• Application Number:
  US08/559,123
• Time in Patent Office: 1,894 Days
• Field of Search: 570/243, 570/245
• US Class Current: 570/245
• CPC Class Codes: C07C 17/15 with oxygen as auxiliary reagent, e.g. oxychlorination
• CPC Class Codes: C07C 17/152 of hydrocarbons
• CPC Class Codes: C07C 17/154 of saturated hydrocarbons
• CPC Class Codes: C07C 17/156 of unsaturated hydrocarbons
• CPC Class Codes: C07C 17/158 of halogenated hydrocarbons

Abstract

An improved process is disclosed for manufacturing chlorinated hydrocarbon by way of oxychlorination which yields reduced levels of environmental toxins such as, chlorobenzenes, polychlorinated biphenyls, polychlorinated dibenzodioxins and polychlorinated dibenzofurans. The process involves fixed bed or fluid bed catalyzed oxychlorination of a hydrocarbon reactant containing from 1 to 3 carbon atoms. The oxychlorination process consists of contacting the hydrocarbon reactant with oxygen or oxygenated gas and at least a portion of externally obtained hydrogen chloride in the presence of the oxychlorination catalyst in a heated reaction zone operated at from 150° C. to 600° C. and recovering chlorinated hydrocarbon from the effluents of the reaction zone. The improvement consists of the use of at least a portion of the hydrogen chloride from an external source other than from recovery of hydrogen chloride from the thermal pyrolysis of the product from the operated oxychlorination process, wherein the external hydrogen chloride, containing aromatic hydrocarbons, is pretreated before use in the operated oxychlorination process by a means for removal of the aromatic hydrocarbons.

Claims

1. An improved process for manufacturing chlorinated hydrocarbon with reduced formation of chlorobenzenes, polychlorinated biphenyls (PCBs), polychlorinated dibenzodioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs), said process starting with C₁ to C₃ hydrocarbon reactant selected from the group consisting of methane, ethane, ethylene, acetylene, propane, propylene, methylacetylene, and halogen substituted versions thereof, said process comprising:

contacting said reactant with oxygen or oxygenated gas and hydrogen chloride, wherein at least a portion of the hydrogen chloride to be consumed is obtained from an external source other than from recovery from the thermal cracking of the product produced in said oxychlorination process, said contacting is conducted in the presence of an oxychlorination catalyst in a heated reaction zone operating at from 150°

C. to 600°

C. wherein chlorinated hydrocarbon is recovered from the effluents of the reaction zone, the process is characterized by the fact that the hydrogen chloride is pretreated with a means for removal of the aromatic hydrocarbons.

2. The process of claim 1 wherein said means for removal of aromatic compounds from said hydrogen chloride is selected from the group consisting of distillation, adsorption, absorption, hydrogenation, and oxidation.

3. The process of claim 1 wherein said means for removal of aromatic compounds is selected from the group consisting of

(a) passing said hydrogen chloride through a vessel containing activated carbon,

(b) treating said hydrogen chloride with activated charcoal,

(c) treating said hydrogen chloride with silica,

(d) treating said hydrogen chloride with an aromatic compound adsorptive resin,

(e) subjecting said hydrogen chloride to a hydrogenation process,

(f) extraction with aliphatic liquid hydrocarbon, and

(g) subjecting said hydrogen chloride to an oxidation process.

4. The process of claim 1 wherein said hydrocarbon is selected from the group consisting of methane, ethane and propane and wherein said heated reaction zone is operated at from 300°

C. to 600°

C.

5. The process of claim 1 wherein said hydrocarbon is selected from the group consisting of ethylene, acetylene, propylene, and methylacetylene and wherein said heated reaction zone is operated at from 150°

C. to 300°

C.

6. The process of claim 1 wherein said hydrocarbon is ethylene.