Method of removing contaminants from used oil

• US 6,179,999 B1
• Filed: 10/15/1999
• Issued: 01/30/2001
• Est. Priority Date: 02/16/1999
• Status: Expired due to Term

• Current Assignee: Miami University
• Original Assignee: Miami University
• Inventors: Sherman, Jeffrey H., Taylor, Richard T.
• Primary Examiner(s): MYERS, HELANE ELEANORA
• Application Number:
  US09/418,448
• Time in Patent Office: 473 Days
• Field of Search: 208/179, 208/181, 208/183
• US Class Current: 208/183
• CPC Class Codes: C10G 19/00 Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
• CPC Class Codes: C10G 19/04 containing solubilisers, e.g. solutisers
• CPC Class Codes: C10M 175/00 Working-up used lubricants to recover useful products destructive distillation C10B; extraction and elimination of PCBs C10G7/006, C10G21/006, C10G25/006; combustion processes F23G; filtration, filters in general B01D; Cleaning in a mechanical way B08B; integrated processes C23; solid waste B09B
• CPC Class Codes: C10M 175/0016 with the use of chemical agents
• CPC Class Codes: C10M 175/0033 using distillation processes; devices therefor

Abstract

In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.

Claims

1. A method of purifying used oil comprising the steps of:

placing used oil into a continuous flow apparatus;

contacting the used oil with a base introduced at such a rate as to maintain the base at about 1 weight % to about 10 weight % of the oil composition;

contacting the used oil with a phase transfer catalyst introduced at such a rate as to maintain the phase transfer catalyst at about 1 weight % to about 10 weight % of the oil composition;

heating the composition to a temperature between about 200°

C. and about 275°

C.;

mixing the composition;

separating the resultant mixture using a first distillation at a temperature of from about 200°

C. to about 275°

C. and a pressure of from about 100 torr to about 200 torr; and

purifying the used oil using a second distillation at a temperature of from about 275°

C. to about 300°

C. and a pressure of from about 0.05 torr to about 0.20 torr.

2. The method as recited in claim 1 additionally comprising the step of:

heating the oil composition obtained from the first distillation to a temperature between about 200°

C. and about 300°

C.; and

mixing the composition after the first distillation but before the second distillation.

3. A method of purifying used oil comprising the steps of:

placing used oil into a continuous flow apparatus;

contacting the used oil with a base selected from the group including sodium hydroxide and potassium hydroxide introduced at such a rate as to maintain the base at about 1 weight % to about 10 weight % of the oil composition;

contacting the used oil with ethylene glycol introduced at such a rate as to maintain the phase transfer catalyst at about 1 weight % to about 10 weight % of the oil composition;

heating the composition to a temperature between about 200°

C. and about 275°

C.;

mixing the composition;

separating the resultant mixture using a first distillation at a temperature of from about 200°

C. to about 275°

C. and a pressure of from about 100 torr to about 200 torr; and

purifying the used oil using a second distillation at a temperature of from about 275°

C. to about 350°

C. and a pressure of from about 0.05 torr to about 0.20 torr.