Electrochemical power cells and method of improving electrochemical power cell performance

• US 6,180,284 B1
• Filed: 06/05/1998
• Issued: 01/30/2001
• Est. Priority Date: 06/05/1998
• Status: Expired due to Fees

• Current Assignee: Mine Safety Appliances Company (MSA Safety, Inc.)
• Original Assignee: Mine Safety Appliances Company (MSA Safety, Inc.)
• Inventors: Shah, Pinakin M., Warburton, Donald L., Bytella, Joseph J., Kronenberg, Marvin L., Bis, Richard F., Meshri, Dayal T.
• Primary Examiner(s): WEINER, LAURA S
• Application Number:
  US09/092,192
• Time in Patent Office: 970 Days
• Field of Search: 429/307, 429/342, 429/213, 429/231.8, 429/215, 429/217, 429/231.95, 429/218.1, 429/231.4, 429/231.7, 429/232, 429/199, 429/101, 429/102, 429/103
• US Class Current: 429/218.1
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/582 Halogenides
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: H01M 6/164 by the solvent
• CPC Class Codes: H01M 6/168 by additives
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A small, portable electrochemical power cell, having an output voltage of over 4 V, and preferably over 5 V, includes an anode, a cathode comprising a fluorine compound and an electrolyte to maintain ionic conductivity between the anode and the cathode. A method of fabricating such an electrochemical power cell includes the step of adding a fluorine compound to the cathode and/or to the electrolyte solvent.

Claims

1. An electrochemical power cell comprising:

an anode;

a cathode comprising a binder material, carbon and a fluorine compound with a water content less than approximately 150 ppm; and

an electrolyte to maintain electrical conductivity between the anode and the cathode;

the electrochemical power cell having a voltage greater than 4.0V.

2. The electrochemical power cell of claim 1 wherein the purity of the fluorine compound is at least approximately 99%.

3. The electrochemical power cell of claim 1 wherein the content of the binder material in the cathode ranges between approximately 5 and approximately 10 weight percent, the content of the carbon in the cathode ranges between approximately 10 and approximately 40 weight percent, and the content of the fluorine compound in the cathode ranges between approximately 50 and approximately 85 weight percent.

4. The electrochemical power cell of claim 1, further comprising an additive in the electrolyte, the additive adapted to produce a protective film on the anode.

5. The electrochemical power cell of claim 4 wherein the additive comprises sulfuryl chloride, thionyl chloride, or iodine pentafluoride.

6. The electrochemical power cell of claim 5 wherein the additive comprises iodine pentafluoride.

7. The electrochemical power cell of claim 1 wherein the fluorine compound is a metal fluoride, a nitrosonium fluoride or an oxyfluoride.

8. The electrochemical power cell of claim 1 wherein the fluorine compound is CoF₃, AgF₂, XeF₂, NO₂SbF₆, NO₂BF₄, or SbF₅S.

9. The electrochemical power cell of claim 1 wherein the electrolyte comprises an alkyl carbonate electrolyte solvent.

10. The electrochemical power cell of claim 1 wherein the anode comprises an alkali metal or an alkali earth metal.

11. The electrochemical power cell of claim 10 wherein the anode comprises lithium metal.

12. The electrochemical power cell of claim 11 wherein the specific energy of the electrochemical power cell is at least approximately 1000 Wh/kg.

13. The electrochemical power cell of claim 11 wherein the electrolyte comprises a lithium hexafluorophosphate solute.

14. A method of fabricating an electrochemical power cell having a voltage greater than 4.0V, the electrochemical cell including an anode, a cathode, and an electrolyte to maintain electrical conductivity between the anode and the cathode, the method comprising the step of incorporating a fluorine compound with a water content less than approximately 150 ppm in the cathode along with a binder material and carbon.

15. The method of claim 14 further comprising the step of adding a fluorine compound to the electrolyte solvent.

16. An electrochemical power cell comprising an anode, a cathode including a fluorine compound with a water content less than approximately 150 ppm, and an electrolyte with an additive therein to maintain electrical conductivity between the anode and the cathode, the additive adapted to produce a protective film on the anode, the electrochemical power cell having a voltage greater than 4.0V.

17. The electrochemical power cell of claim 16 wherein the additive comprises sulfuryl chloride, thionyl chloride, or iodine pentafluoride.

18. The electrochemical power cell of claim 17 wherein the additive comprises iodine pentafluoride.