Thermodynamic separation of heavier components from natural gas

• US 6,182,468 B1
• Filed: 02/22/1999
• Issued: 02/06/2001
• Est. Priority Date: 02/19/1999
• Status: Expired due to Fees

• Current Assignee: Ultimate Process Technology
• Original Assignee: Ultimate Process Technology
• Inventors: Stothers, William R.
• Primary Examiner(s): DOERRLER, WILLIAM CHARLES
• Application Number:
  US09/257,352
• Time in Patent Office: 715 Days
• Field of Search: 626/30, 626/21, 626/31
• US Class Current: 62/621
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/04 in a dual pressure main column system
• CPC Class Codes: F25J 2200/08 in a triple pressure main column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2200/78 Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
• CPC Class Codes: F25J 2210/06 Splitting of the feed stream, e.g. for treating or cooling in different ways
• CPC Class Codes: F25J 2240/40 Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
• CPC Class Codes: F25J 2245/02 Recycle of a stream in general, e.g. a by-pass stream
• CPC Class Codes: F25J 2270/90 External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: F25J 3/0242 separation of CnHm with 3 carbon atoms or more
• CPC Class Codes: F25J 3/0247 separation of CnHm with 4 carbon atoms or more

Abstract

A process for separation of particularly propane, methane or ethane from natural gas includes providing a distillation tower arrangement for separating the heavier components discharged at the bottom from lighter gas discharged at the top with at least two separate towers at different pressures such that the heavier product from the higher pressure tower is expanded and fed to the lower pressure tower. A feed gas containing the components under a first pressure is separated into a first proportion and a second proportion, where neither proportion is zero. The first proportion is fed to the tower. The second proportion is compressed to a pressure higher than the first pressure, heat is extracted from the compressed second proportion to effect condensation thereof, the compressed condensed second proportion is sub-cooled, expanded to the first pressure and supplied after expansion to the distillation tower arrangement at a position thereon adjacent the top of the distillation tower arrangement so as to cause cooling of the materials in the distillation tower arrangement. The method is particularly advantageous in a low pressure supply system in which the lighter gas discharged at the top of the tower arrangement is supplied at a pressure less than 100 psi and more preferably less than 75 psi.

Claims

1. A method of separating heavier components from natural gas comprising:

providing a distillation tower arrangement for separating the heavier components discharged at the bottom of the tower arrangement from lighter gas discharged at the top of the tower arrangement;

generating a residue gas stream from the lighter gas components for supply at a residue gas pressure to a downstream process;

providing a feed gas containing the components under a feed pressure;

separating the feed gas into a first proportion and a second proportion, where neither proportion is zero;

feeding the first proportion at the feed pressure to the distillation tower arrangement at a feed position thereon between the top and bottom thereof for separation within the distillation tower arrangement;

compressing the second proportion to an increased pressure higher than the feed pressure, the increased pressure being selected to provide a desired operating pressure in the distillation tower arrangement and being different from the residue gas pressure;

extracting heat from the compressed second proportion to effect condensation thereof;

sub-cooling the compressed condensed second proportion;

expanding the compressed condensed second proportion and supplying the second proportion after expansion to the distillation tower arrangement at a position thereon adjacent the top of the distillation tower arrangement so as to cause cooling of the materials in the distillation tower arrangement.

2. The method according to claim 1 wherein the residue gas pressure is less than 100 psi.

3. The method according to claim 1 wherein the second proportion is sub-cooled by cool from the lighter gas.

4. The method according to claim 3 wherein the second proportion is further sub-cooled by a refrigerant.

5. The method according to claim 1 wherein the feed gas is dehydrated prior to separation.

6. The method according to claim 5 wherein the feed gas is dehydrated by a molecular sieve.

7. The method according to claim 1 wherein the first proportion is cooled by cool from a re-boiler of the tower arrangement.

8. The method according to claim 1 wherein the tower arrangement includes at least two separate towers at different pressures thus defining a higher pressure tower and a lower pressure tower each arranged to separate a lighter product at the top and a heavier product at the bottom of the respective tower arranged such that the heavier product from the higher pressure tower is expanded and fed to the lower pressure tower and wherein at least a portion of the lighter gas from the top of the lower pressure tower is added to the second proportion for processing therewith and supply to the top of the higher pressure tower.

9. The method according to claim 8 wherein the lighter gas from the top of the lower pressure tower is fed back to the feed gas for reprocessing such that a portion only of the lighter gas is combined with the second proportion.

10. The method according to claim 1 wherein the residue gas pressure is of the order of 75 psi and wherein the residue gas is fed to a pipe line at said pressure.

11. The method according to claim 10 wherein the lighter gas from the top of the lower pressure tower is fed back to the feed gas for reprocessing such that a portion only of the lighter gas is combined with the second proportion.

12. The method according to claim 8 wherein the whole of the lighter gas from the top of the lower pressure tower is added to the second proportion for processing therewith and supply at a common point to the top of the higher pressure tower.

13. The method according to claim 1 wherein the supply gas is separated from a crude oil supply and wherein the separated heavier components are returned to the crude oil supply as a supplement thereto.

14. The method according to claim 13 wherein the seperated lighter gas is flared.

15. The method according to claim 13 wherein the whole of the lighter gas from the top of the lower pressure tower is added to the second proportion for processing therewith and supply at a common point to the top of the higher pressure tower.

16. The method according to claim 13 wherein the lighter gas from the top of the lower pressure tower is flared.

17. The method according to claim 13 wherein there is provided a third tower and wherein the heavier components from the bottom of the lower pressure tower are fed to the third tower.

18. A method of separating heavier components from natural gas comprising:

providing a distillation tower arrangement for separating the heavier components discharged at the bottom of the tower arrangement from lighter gas discharged at the top of the tower arrangement;

providing a feed gas containing the components for supply to the distillation tower arrangement;

the tower arrangement including at least two separate towers at different pressures thus defining a higher pressure tower and a lower pressure tower each arranged to separate a lighter product at the top and a heavier product at the bottom of the respective tower;

taking the heavier product from the bottom of the higher pressure tower which is then expanded and fed to the lower pressure tower;

separating the feed gas into a first proportion and a second proportion, where neither proportion is zero;

feeding the first proportion to the distillation tower arrangement at a feed position thereon between the top and bottom thereof for separation within the distillation tower arrangement;

adding at least a portion of the lighter gas from the top of the lower pressure tower to the second proportion for processing therewith and supply to the top of the higher pressure tower;

compressing said second proportion and said at least a portion of the lighter gas from the top of the lower pressure tower to a pressure higher than the feed pressure;

extracting heat from said second proportion and said at least a portion of the lighter gas from the top of the lower pressure tower to effect condensation thereof;

sub-cooling said second proportion and said at least a portion of the lighter gas from the top of the lower pressure tower;

expanding said second proportion and said at least a portion of the lighter gas from the top of the lower pressure tower;

and supplying said second proportion and said at least a portion of the lighter gas from the top of the lower pressure tower after expansion to the higher pressure tower together at a common position thereon adjacent the top so as to cause cooling of the materials in the distillation tower arrangement.

19. The method according to claim 18 wherein the lighter gas from the top of the lower pressure tower is fed back to the feed gas.

20. The method according to claim 18 wherein the whole of the lighter gas from the top of the lower pressure tower is added to the second proportion for processing therewith and supply to the top of the higher pressure tower.