Method for purifying gases

• US 6,187,277 B1
• Filed: 06/04/1999
• Issued: 02/13/2001
• Est. Priority Date: 06/04/1999
• Status: Expired due to Fees

• Current Assignee: Sheldon Kirshner
• Original Assignee: Leon Kirschner
• Inventors: Kirschner, Leon
• Primary Examiner(s): Griffin, Steven P.
• Assistant Examiner(s): Vanoy, Timothy C
• Application Number:
  US09/325,955
• Time in Patent Office: 620 Days
• Field of Search: 423/242.2, 423/243.01, 423/555, 423/554, 423/519.2, 423/430, 423/220, 423/226, 423/243.08, 952/36, 952/35
• US Class Current: 423/220
• CPC Class Codes: B01D 53/1418 Recovery of products
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: C01F 11/464 Sulfates of Ca from gases containing sulfur oxides
• CPC Class Codes: C01F 11/48 Sulfites
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A method is provided for removing sulfur dioxide and carbon dioxide out of gases from, for example, the combustion of sulfur containing fossil fuels. The sulfur dioxide and carbon dioxide contaminated gas is first contacted with an aqueous solution containing dimethyl sulfoxide and alkaline earth metal ions, wherein the aqueous solution is at an acidic pH, for example, at a pH of from about 2 to about less than 7, so that the sulfur dioxide in the gas is dissolved in the aqueous solution and, subsequently, reacts with the alkaline earth metal ions to form alkaline earth metal sulfates and alkaline earth metal sulfites. The gas is then contacted with an aqueous solution containing dimethyl sulfoxide and alkaline earth metal ions, wherein this aqueous solution is at a pH that is greater than 7 so that the carbon dioxide in the gas is dissolved in the aqueous solution and, subsequently, reacts with the alkaline earth metal ions to form alkaline earth metal carbonates. The alkaline earth metal sulfates/sulfites and alkaline earth metal carbonates are separated from the solution. The source of the alkaline earth metal ions may be from cement waste or limestone.

Claims

1. A method of removing SO₂ from a gas, comprising contacting the SO₂ containing gas with an aqueous solution of dimethyl sulfoxide while maintaining the pH of the aqueous solution acidic to dissolve SO₂ in the aqueous solution of dimethyl sulfoxide and thereafter reacting the dissolved SO₂ with alkaline earth metal ions to form a solid alkaline earth sulfate or a solid alkaline earth sulfite or mixtures thereof.

2. The method of claim 1, wherein the alkaline earth metal ions are calcium ions or magnesium ions from cement waste material.

3. The method of claim 2, wherein the calcium ions are from limestone.

4. The method of claim 1, wherein the gas containing the SO₂ is from the combustion of sulfur containing fossil fuels.

5. The method of claim 4, wherein the concention of dimethyl sulfoxide in the aqueous solution is in the range of from about 2% to about 70% by weight.

6. The method of claim 5, wherein the temperature of the aqueous solution of dimethyl sulfoxide is maintained in the range of from about ambient temperature to about 100°

C.

7. The method of claim 4, wherein the pH of the aqueous solution of dimethyl sulfoxide is maintained in the range of from about 2 to less than 7.

8. The method of claim 7, wherein the pH is maintained at about 5.

9. A method of removing CO₂ from a gas, comprising contacting the CO₂ containing gas with an aqueous solution of dimethyl sulfoxide while maintaining the pH of the aqueous solution basic to dissolve CO₂ in the aqueous solution of dimethyl sulfoxide, and reacting the dissolved CO₂ with alkaline earth metal ions to form solid alkaline earth CO₃.

10. The method of claim 9, wherein the pH of the aqueous solution of dimethyl sulfoxide is maintained in the range of from about 7.1 to about 12.

11. The method of claim 9, wherein the pH of the aqueous solution of dimethyl sulfoxide is maintained about 8 to about 9.

12. The method of claim 9, wherein the concentration of dimethyl sulfoxide present in the aqueous solution is in the range of from about 2 to about 70% by weight.

13. The method of claim 12, wherein the dimethyl sulfoxide is present in a concentration of about 10% by weight.

14. A method of removing SO₂ and CO₂ from a gas containing CO₂ and SO₂, comprising contacting the gas containing CO₂ and SO₂ with an aqueous solution of dimethyl sulfoxide at a pH less than 7 to dissolve SO₂ in the aqueous dimethyl sulfoxide solution, reacting the dissolved SO₂ with alkaline earth metal ions to form solid alkaline earth sulfate or alkaline earth sulfite or mixtures thereof, separating solid alkaline earth sulfate or alkaline earth sulfite from the aqueous dimethyl sulfoxide, thereafter contacting the gas containing CO₂ with an aqueous solution containing dimethyl sulfoxide at a pH greater than 7 to dissolve CO₂ in the solution containing aqueous dimethyl sulfoxide contacting, the dissolved CO₂ reacting with alkaline earth metal ions to form solid alkaline earth CO₃, and separating solid alkaline earth carbonate from the solution.

15. The method of claim 14, wherein the concentration of dimethyl sulfoxide in aqueous solution is in the range of from abut 2% to about 70% by weight.

16. The method of claim 15, wherein the temperature of the aqueous solutions of DMSO is maintained in the range of from about ambient temperature to about 100°

C.

17. The method of claim 16, wherein the alkaline earth metal ions are calcium ions or magnesium ions from cement waste material.

18. The method of claim 17, wherein the calcium ions are from limestone.

19. The method of claim 18, wherein the gas containing the SO₂ is from the combustion of fossil fuels.

20. The method of claim 19, wherein the pH of the dimethyl sulfoxide solution used to dissolve SO₂ is maintained from about 2 to less than 7.

21. The method of claim 20, wherein the pH of the dimethyl sulfoxide solution used to dissolve CO₂ is maintained in the range of from greater than 7 to about 12.

22. The method of 2 claim 21, wherein the pH of the dimethyl sulfoxide solution used to dissolve CO₂ is maintained between about 8 and about 9.

23. The method of claim 20, wherein the pH of the dimethyl sulfoxide solution used to dissolve SO₂ is maintained to about 5.