Golf balls comprising blends of polyamides and ionomers

• US 6,187,864 B1
• Filed: 03/13/1997
• Issued: 02/13/2001
• Est. Priority Date: 03/13/1997
• Status: Expired due to Fees

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Rajagopalan, Murali
• Primary Examiner(s): Buttner, David J.
• Application Number:
  US08/815,659
• Time in Patent Office: 1,433 Days
• Field of Search: 525/183, 473/372, 473/377, 473/378, 473/385
• US Class Current: 525/183
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0024 Materials other than ionomers or polyurethane
• CPC Class Codes: A63B 37/0037 Flexural modulus; Bending stiffness
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

The present invention relates to a golf ball, comprising a cover, a core and optional intermediate layers, wherein the various ball components are formed from compositions comprising compatible blends of a relatively hard polyamide, in the form of a homopolymer, copolymer or block copolymer, with a relatively soft ionomer resin. The compositions include a substantially compatibilizer-free blend of about 10% to 80% of an ionomer resin and about 90% to 20% of at least one polyamide polymer, with the proviso that the polyamide polymer is not a block polyamide copolymer comprising main-chain polyether blocks. The present invention also relates to a golf ball comprising a cover layer, a core layer and at least one intermediate layer interposed there-between, wherein at least one of said layers consists essentially of up to about 99 wt. % of an ionomer and about 100 wt. % to about 1 wt. % of at least one polyamide polymer, with the proviso that the polyamide polymer is not a block polyamide copolymer comprising main-chain polyether blocks and further that the cover consists essentially of at least one material selected from the group consisting of nonionomer polymer materials and non-olefin ionomers.

Claims

1. A golf ball comprising a cover and a core, said cover comprising at least one layer, wherein an outermost layer of said cover is formed of a composition of a substantially compatibilizer-free blend, said blend consisting of polymeric components comprising from about 10 wt. % to about 50 wt. % of at least one ionomer and about 90 wt. % to about 50 wt. % of at least one polyamide polymer and, optionally, further consisting of at least one additive selected from dyes, whitening agents, UV absorbers, antioxidants, stabilizers, softening agents, plasticizers, impact modifiers, toughening agents, reinforcing materials, nucleating agents and combinations of these additives, wherein the polyamide polymer is selected from the group consisting of polyamide homopolymers, polyamide copolymers and mixtures thereof.

2. The golf ball of claim 1, wherein the flexural modulus of the polyamide polymer is at least about 50,000 psi.

3. The golf ball of claim 1, wherein the polyamide polymer is a copolymer selected from the group consisting of nylon 6/6,6, nylon 6,6/6,10, nylon 6/6,T, nylon 6/6,6/6,10 and mixtures thereof.

4. The golf ball of claim 1, wherein the polyamide polymer is a homopolymer selected from the group consisting of nylon 6, nylon 11, nylon 12, nylon 4,6, nylon 6,6, nylon 6,9, nylon 6,10, nylon 6,12 and mixtures thereof.

5. The golf ball of claim 4, wherein the polyamide homopolymer is selected from the group consisting of nylon 11 and nylon 12.

6. The golf ball of claim 1, wherein the ionomer comprises a copolymer of ethylene and (meth)acrylic acid at least partially neutralized with a metal ion, the polyamide homopolymer polymer comprises polyamide 12, and the core comprises polybutadiene.

15. The golf ball of claim 6, wherein the flexural modulus of the polyamide polymer is from at least about 75,000 psi to about 500,000 psi.

7. A golf ball comprising a cover and a core, said cover comprising at least one layer, wherein an outermost layer of said cover is formed of a composition of a substantially compatibilizer-free blend, said blend consisting of polymeric components comprising from about 10 wt. % to about 50 wt. % of at least one ionomer and about 90 wt. % to about 50 wt. % of at least one polyamide polymer and, optionally, further consisting of at least one additive selected from dyes, whitening agents, UV absorbers, antioxidants, stabilizers, softening agents, plasticizers, impact modifiers, toughening agents, reinforcing materials, nucleating agents and combinations of these additives, with the proviso that the polyamide polymer is not a block polyamide copolymer comprising main-chain polyether blocks.

8. The golf ball of claim 7, wherein the flexural modulus of the ionomer is from at least about 1,000 psi to about 150,000 psi.

9. The golf ball of claim 7, wherein the ionomer is selected from the group consisting of olefin, polyester, copoly(ether-ester), copoly(ester-ester), polyamide, polyether, polyurethane, polyacrylate, polystyrene, SBS, SEBS, and polycarbonate homopolymer, copolymer and block copolymer ionomers.

10. The golf ball of claim 9, wherein the ionomer comprises a copolymer of an olefin and an α

,β

-ethylenically unsaturated carboxylic acid, where at least a portion of the carboxylic acid groups are neutralized with a metal ion.

11. The golf ball of claim 10, wherein the olefin is ethylene, the α

,β

-ethylenically unsaturated carboxylic acid is acrylic or methacrylic acid present in an amount of from about 5 wt. % to about 30 wt. %, and the metal ion is selected from the group consisting of zinc, sodium, magnesium, manganese, calcium, lithium and potassium.

12. The golf ball of claim 11, wherein the carboxylic acid is present in an amount of from about 10 wt. % to about 20 wt. % and the metal ion is zinc.

13. The golf ball of claim 7, wherein the polyamide polymer is selected from the group consisting of polyamide homopolymers, polyamide copolymers, block polyamide copolymers and mixtures thereof.

14. The golf ball of claim 13, wherein the block polyamide copolymer comprises main-chain blocks selected from the group consisting of polyester, polyurethane, α

,ω

-hydroxybutadiene oligomer, at least partially hydrogenated α

,ω

-hydroxybutadiene oligomer, and mixtures thereof.

16. The golf ball of claim 7, wherein the ionomer comprises a copolymer of ethylene and (meth)acrylic acid at least partially neutralized with a metal ion, the polyamide polymer comprises polyamide 12, and the core comprises polybutadiene.

17. A golf ball comprising a cover and a core, said cover comprising at least one layer, wherein an outermost cover layer is formed of a composition which consists of about 5 wt. % to about 50 wt. % of at least one ionomer and about 95 wt. % to about 50 wt. % of at least one polyamide polymer and, optionally, further consisting of at least one additive selected from dyes, whitening agents, UV absorbers, antioxidants, stabilizers, softening agents, plasticizers, compatibilizers, impact modifiers, toughening agents, reinforcing materials, nucleating agents and combinations of these additives, with the proviso that the polyamide polymer is not a block polyamide copolymer comprising main-chain polyether blocks.

18. The golf ball of claim 17, wherein the polyamide polymer is selected from the group consisting of nylon 6, nylon 11, nylon 12, nylon 4,6, nylon 6,6, nylon 6,9, nylon 6,10, nylon 6,12 and mixtures thereof.

19. The golf ball of claim 17, wherein the ionomer comprises a copolymer of ethylene and about 5 wt. % to about 30 wt. % of acrylic or methacrylic acid, and wherein at least a portion of the carboxylic acid groups are neutralized with a metal ion selected from the group consisting of zinc, sodium, magnesium, manganese, calcium, lithium, and potassium.

20. The golf ball of claim 17, wherein the ionomer comprises a copolymer of ethylene and (meth)acrylic acid at least partially neutralized with a metal ion, the polyamide polymer comprises polyamide 12, and the core comprises polybutadiene.

21. A method of making a golf ball, comprising:

forming a golf ball core;

forming a substantially compatibilizer-free blend, said blend consisting of polymeric components comprising from about 10 wt. % to about 50 wt. % of at least one ionomer and about 90 wt. % to about 50 wt. % of at least one polyamide polymer and, optionally, further consisting of at least one additive selected from dyes, whitening agents, UV absorbers, antioxidants, stabilizers, softening agents, plasticizers, impact modifiers, toughening agents, reinforcing materials nucleating agents and combinations of these additives, with the proviso that the polyamide polymer is not a block polyamide copolymer comprising main-chain polyether blocks; and

forming an outermost cover layer upon said ball by molding the blend around the golf ball core.

22. The method of claim 21, further comprising choosing the polyamide such that its flexural modulus is from at least about 75,000 psi to about 500,000 psi.

23. The method of claim 21, further comprising choosing the ionomer such that its flexural modulus is from at least about 1,000 psi to about 150,000 psi.

24. The method of claim 21, further comprising selecting the ionomer from the group consisting of olefin, polyester, copoly(ether-ester), copoly(ester-ester), polyamide, polyether, polyurethane, polyacrylate, polystyrene, styrene-butadiene-styrene, styrene-(hydrogenated butadiene)-styrene, and polycarbonate homopolymer, copolymer and block copolymer ionomers.

25. The method of claim 24, further comprising selecting an ionomer comprised of a copolymer of an olefin and an α

,β

-ethylenically unsaturated carboxylic acid, where at least a portion of the carboxylic acid groups are neutralized with a metal ion.

26. The method of claim 25, further comprising selecting ethylene as the olefin, selecting as the α

,β

-ethylenically unsaturated carboxylic acid acrylic or methacrylic acid, and selecting the metal ion from the group consisting of zinc, sodium, magnesium, manganese, calcium, lithium and potassium.

27. The method of claim 21, further comprising selecting the polyamide polymer from the group consisting of polyamide homopolymers, polyamide copolymers, block polyamide copolymers and mixtures thereof.

28. The method of claim 27, further comprising choosing the block polyamide copolymer such that it comprises main-chain blocks selected from the group consisting of polyester, polyurethane, α

,ω

-hydroxybutadiene oligomer, at least partially hydrogenated α

,ω

-hydroxybutadiene oligomer, and mixtures thereof.

29. The method of claim 27, further comprising selecting the polyamide copolymer from the group consisting of nylon 6/6,6, nylon 6,6/6,10, nylon 6/6,T, nylon 6/6,6/6,10 and mixtures thereof.

30. The method of claim 24, further comprising choosing the polyamide copolymer such that its flexural modulus is at least about 50,000 psi.

31. The method of claim 27, further comprising selecting the polyamide homopolymer from the group consisting of nylon 6, nylon 11, nylon 12, nylon 4,6, nylon 6,6, nylon 6,9, nylon 6,10, nylon 6,12 and mixtures thereof.

32. The method of claim 31, further comprising choosing the polyamide homopolymer such that its flexural modulus is at least about 50,000 psi.

33. The method of claim 31, further comprising selecting the polyamide homopolymer from the group consisting of nylon 11 and nylon 12.

34. The golf ball of claim 21, further comprising selecting the ionomer to comprise a copolymer of ethylene and (meth)acrylic acid at least partially neutralized with a metal ion, selecting the polyamide polymer to comprise polyamide 12, and selecting the core to comprise polybutadiene.

35. A method of making a golf ball, comprising:

forming a golf ball core;

forming a cover blend that consists of about 5 wt. % to about 50 wt. % of at least one ionomer and about 95 wt. % to about 50 wt. % of at least one polyamide polymer and, optionally, further consisting of at least one additive selected from dyes, whitening agents, UV absorbers, antioxidants, stabilizers, softening agents, plasticizers, compatibilizers, impact modifiers, toughening agents, reinforcing materials, nucleating agents and combinations of these additives, with the proviso that the polyamide polymer is not a block polyamide copolymer comprising main-chain polyether blocks; and

forming an outermost cover layer upon said ball by molding the blend around the golf ball core.

36. The method of claim 35, further comprising selecting the polyamide from the group consisting of nylon 6, nylon 11, nylon 12, nylon 4,6, nylon 6,6, nylon 6,9, nylon 6,10, nylon 6,12 and mixtures thereof.

37. The method of claim 35, further comprising selecting the ionomer to be a copolymer of ethylene and about 5 wt. % to about 30 wt. % of acrylic or methacrylic acid, wherein at least a portion of the carboxylic acid groups are neutralized with a metal ion selected from the group consisting of zinc, sodium, magnesium, manganese, calcium, lithium and potassium.

38. The golf ball of claim 35, further comprising selecting the ionomer to comprise a copolymer of ethylene and (meth)acrylic acid at least partially neutralized with a metal ion, selecting the polyamide polymer to comprise polyamide 12, and selecting the core to comprise polybutadiene.