Polymerisation process

• US 6,187,878 B1
• Filed: 12/23/1999
• Issued: 02/13/2001
• Est. Priority Date: 06/27/1997
• Status: Expired due to Term

• Current Assignee: Ineos Sales (Uk) Limited (Ineos AG)
• Original Assignee: BP Chemicals Ltd. (BP PLC)
• Inventors: Daire, Erick Dominique, Soulier, Bruno Patrice, Lalanne-Magne, Claudine Viviane, Isnard, Jean-Pierre
• Primary Examiner(s): TESKIN, FRED M
• Application Number:
  US09/471,419
• Time in Patent Office: 418 Days
• Field of Search: 526/67, 526/68, 526/901, 526/88
• US Class Current: 526/68
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 2/34 Polymerisation in gaseous state
• CPC Class Codes: Y10S 526/901 Monomer polymerized in vapor state in presence of transition metal containing catalyst

Abstract

A continuous gas fluidized bed process for the polymerization of olefin monomer(s) wherein the recycled gaseous stream withdrawn from the reactor is divided into two streams (A and B) and that (a) a first stream (A) having been cooled to a temperature at which liquid condenses out is then reintroduced directly into the fluidized bed in the reactor in such a way that, at any time, the condensed liquid is continuously introduced into the bed at a minimum rate of 10 liters of liquid per cubic meter of fluidized bed material per hour, and (b) a second stream (B), which by-passes the above cooling/condensing step, is passed through an exchanger and is then reintroduced into the reactor. The continuous introduction of a liquid into the reactor reduces or even eliminates fouling problems which can be encountered in conventional gas phase olefin polymerization processes.

Claims

1. A continuous gas-phase fluidised bed process for the polymerisation of olefin monomer selected from the group consisting of (a) ethylene, (b) propylene, (c) mixtures of ethylene and propylene, and (d) one or more other alpha-olefins mixed with (a), (b) or (c), in a fluidised bed reactor, said process comprising withdrawing a gaseous stream from the reactor containing at least some of the ethylene and/or propylene, continuously recycling the gaseous stream through the fluidised bed in said reactor in the presence of a polymerisation catalyst under reactive conditions, and dividing said recycling gaseous stream withdrawn from said reactor, before the stream is introduced into the reactor, into two streams, wherein

(a) a first stream (A) is cooled to a temperature at which liquid condenses out is then introduced directly into the fluidised bed in the reactor in such a way that, at any time, said condensed liquid is continuously introduced into said bed at a minimum rate of 10 liters of liquid per cubic meter of fluidised bed material per hour, and

(b) a second stream (B), which by-passes the above cooling/condensing step, is passed through an exchanger and is then introduced into the reactor.

2. Process according to claim 1 wherein the condensed liquid is introduced directly into the fluidised bed above the upper limit of the temperature gradient between the entering fluidising gas and the remainder of the bed.

3. Process according to claim 1 wherein the second stream (B) is sufficiently heated by the exchanger to accommodate the increase in cooling resulting from the injection of liquid thereby maintaining the heat balance in the process.

4. Process according to claim 1 wherein the second stream (B) is cooled by the exchanger to a temperature at which liquid condenses out, the condensed liquid being separated from the stream prior to its introduction into the bed.

5. Process according to claim 1 wherein the condensed liquid is separated from the gaseous stream before its introduction into the bed.

6. A start-up process of a continuous gas-phase fluidised bed process for the polymerisation of olefin monomer selected from the group consisting of (a) ethylene, (b) propylene, (c) mixtures of ethylene and propylene, and (d) one or more other alpha-olefins mixed with (a), (b) or (c), in a fluidised bed reactor, said process comprising withdrawing a gaseous stream from the reactor containing at least some of the ethylene and/or propylene, continuously recycling the gaseous stream through the fluidised bed in said reactor in the presence of a polymerisation catalyst under reactive conditions, and dividing said recycling gaseous stream withdrawn from said reactor, before the stream is introduced into the reactor, into two streams, wherein

(a) a first stream (A) is cooled to a temperature at which liquid condenses out is then introduced directly into the fluidised bed in the reactor in such a way that, at any time, said condensed liquid is continuously introduced into said bed at a minimum rate of 10 liters of liquid per cubic meter of fluidised bed material per hour, and

(b) a second stream (B), which by-passes the above cooling/condensing step, is passed through an exchanger and is then introduced into the reactor.

7. Process according to claim 6 wherein the second stream (B) is heated by the exchanger to accommodate the increase in cooling resulting from the injection of liquid thereby maintaining the heat balance in the process.

8. Process according claim 6 wherein the polymerisation catalyst is introduced into the fluidised bed directly with the condensed liquid stream.

9. Process according to claim 6 wherein the introduction of the condensed liquid in the reactor bed begins before the introduction of the polymerisation catalyst inside the reactor and/or before the polymerisation occurs.