Electrochemical process for removing low-valent sulfur from carbon
First Claim
1. A process for removing low-valent sulfur from carbon containing low-valent sulfur, comprising the steps of:
- placing carbon containing low-valent sulfur in an aqueous electrochemical cell, said electrochemical cell having a weak electrolyte solution of not greater than 0.05 molar wherein the said solution is selected from the group consisting of aqueous acid solutions, aqueous base solutions, and aqueous salt solutions, said electrochemical cell having a cathode a platinum anode;
electrochemically forming platinum oxide by applying a potential of 1.0 volt versus a hydrogen reference electrode to a platinum electrode in said cell and bringing said carbon containing low-valent sulfur into contact with said platinum oxide, for a time sufficient to remove a desired amount of low-valent sulfur from said carbon.
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Abstract
The present invention is, in one aspect, a process for removing low-valent sulfur from carbon containing such low-valent sulfur (sulfur-containing carbon), having the step of contacting the sulfur-containing carbon with a platinum oxide in an aqueous environment, for a time sufficient to remove a desired amount of low-valent sulfur from the sulfur-containing carbon, especially from the surface of the carbon. Another aspect of the invention is an electrode, comprising an electrocatalyst or active material for a fuel cell or battery, disposed in a carbon matrix, where the carbon matrix is essentially free of low-valent sulfur adjacent to the active material of the battery electrode or electrocatalyst of the fuel cell electrode. Such an electrode will be suitable for use in a fuel cell or in a battery. Another aspect of the invention is a fuel cell or a battery using this electrode.
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Citations
5 Claims
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1. A process for removing low-valent sulfur from carbon containing low-valent sulfur, comprising the steps of:
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placing carbon containing low-valent sulfur in an aqueous electrochemical cell, said electrochemical cell having a weak electrolyte solution of not greater than 0.05 molar wherein the said solution is selected from the group consisting of aqueous acid solutions, aqueous base solutions, and aqueous salt solutions, said electrochemical cell having a cathode a platinum anode;
electrochemically forming platinum oxide by applying a potential of 1.0 volt versus a hydrogen reference electrode to a platinum electrode in said cell and bringing said carbon containing low-valent sulfur into contact with said platinum oxide, for a time sufficient to remove a desired amount of low-valent sulfur from said carbon. - View Dependent Claims (2, 3, 4, 5)
removing said carbon from said platinum oxide, after said step of contacting said carbon containing low-valent sulfur with said platinum oxide.
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Specification