Electrochemical process for removing low-valent sulfur from carbon

• US 6,190,428 B1
• Filed: 03/25/1996
• Issued: 02/20/2001
• Est. Priority Date: 03/25/1996
• Status: Expired due to Fees

• Current Assignee: the united states of america as represented by the secretary of the navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: Swider, Karen E., Rolison, Debra R.
• Primary Examiner(s): MEDLEY, MARGARET B
• Application Number:
  US08/621,404
• Time in Patent Office: 1,793 Days
• Field of Search: 446/22, 446/24, 205/768, 205/696, 429/40
• US Class Current: 44/624
• CPC Class Codes: C10L 9/02 by chemical means

Abstract

The present invention is, in one aspect, a process for removing low-valent sulfur from carbon containing such low-valent sulfur (sulfur-containing carbon), having the step of contacting the sulfur-containing carbon with a platinum oxide in an aqueous environment, for a time sufficient to remove a desired amount of low-valent sulfur from the sulfur-containing carbon, especially from the surface of the carbon. Another aspect of the invention is an electrode, comprising an electrocatalyst or active material for a fuel cell or battery, disposed in a carbon matrix, where the carbon matrix is essentially free of low-valent sulfur adjacent to the active material of the battery electrode or electrocatalyst of the fuel cell electrode. Such an electrode will be suitable for use in a fuel cell or in a battery. Another aspect of the invention is a fuel cell or a battery using this electrode.

Claims

1. A process for removing low-valent sulfur from carbon containing low-valent sulfur, comprising the steps of:

placing carbon containing low-valent sulfur in an aqueous electrochemical cell, said electrochemical cell having a weak electrolyte solution of not greater than 0.05 molar wherein the said solution is selected from the group consisting of aqueous acid solutions, aqueous base solutions, and aqueous salt solutions, said electrochemical cell having a cathode a platinum anode;

electrochemically forming platinum oxide by applying a potential of 1.0 volt versus a hydrogen reference electrode to a platinum electrode in said cell and bringing said carbon containing low-valent sulfur into contact with said platinum oxide, for a time sufficient to remove a desired amount of low-valent sulfur from said carbon.

2. The method of claim 1, wherein said carbon is selected from the group consisting of vulcan carbon, pyrolytic carbon, glassy carbon, carbon blacks, coal, petroleum, and petroleum distillates.

3. The method of claim 1, wherein said carbon is a slurry, powder, or cloth.

4. The method of claim 1, wherein said contacting said carbon with said platinum oxide is by dispersing said carbon and said platinum oxide in water.

5. The method of claim 1, further comprising the step of:

removing said carbon from said platinum oxide, after said step of contacting said carbon containing low-valent sulfur with said platinum oxide.