Photocatalytic functional material and method for producing the same

• US 6,191,062 B1
• Filed: 05/15/1997
• Issued: 02/20/2001
• Est. Priority Date: 11/16/1994
• Status: Expired due to Term

• Current Assignee: Toto Limited
• Original Assignee: Toto Limited
• Inventors: Hayakawa, Makoto, Watanabe, Toshiya, Chikuni, Makoto
• Primary Examiner(s): Wood, Elizabeth D.
• Application Number:
  US08/849,645
• Time in Patent Office: 1,377 Days
• Field of Search: 502/159, 502/527.12, 430/531, 430/947, 427/126.1, 427/126.3, 427/126.5, 427/126.6, 427/212, 427/217, 428/312.2, 428/312.6, 428/312.8
• US Class Current: 502/159
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: Y10S 430/148 Light sensitive titanium compound containing
• CPC Class Codes: Y10T 428/249967 Inorganic matrix in void-containing component
• CPC Class Codes: Y10T 428/249969 Of silicon-containing material [e.g., glass, etc.]
• CPC Class Codes: Y10T 428/24997 Of metal-containing material

Abstract

A photocatalytic functional material having an excellent photocatalytic activity even by a low temperature heat treatment and having a high mechanical strength of the surface.

The photocatalytic functional material of the present invention comprises a surface layer (a photocatalytic functional layer) containing a photocatalyst, an electron trapping metal and a photodegradation-resistant matrix. Though the major proportion of the photocatalyst (TiO₂ particles, and the like) in the photocatalytic functional layer are covered with the photodegradation-resistant matrix (a thermosetting resin, and the like), the electron-trapping metal effectively traps the electrons generated by the photocatalytic reaction, retains positive holes and generates active oxygen species, so that the photocatalytic function such as deodorant and antimicrobial activities can be fully exhibited.

Claims

1. A photocatalytic functional material, comprising:

a substrate and a photocatalytic functional layer fixed to a surface of said substrate;

said photocatalytic functional layer comprising;

(1) a mixture layer comprising photocatalytic particles and a photodegradation-resistant matrix, and

(2) a coating formed over said mixture layer, said coating being comprised of an electron-trapping metal;

wherein said photodegradation-resistant matrix is a thermosetting resin.

2. A photocatalytic functional material as defined in claim 1, further comprising:

a binder layer between said substrate and said photocatalytic functional layer, wherein said binder layer is adherent to both said substrate and said photocatalytic functional layer.

3. A photocatalytic functional material as defined in any one of claims 1, wherein the thickness of said photocatalytic functional layer is 0.1 to 5 μ

m.

4. A photocatalytic functional material as defined in any one of claims 1 and 2, wherein the concentration of said electron-trapping metal at the ultraviolet ray reaching depth of said photocatalytic functional layer is at least 0.006% by weight of the combined weight of said photocatalytic particles and said photodegradation-resistant matrix.

5. A photocatalytic functional material as defined in any one of claims 1 and 2, wherein the mixing ratio (resin weight/(resin weight +photocatalyst weight)) of said thermosetting resin and said photocatalyst particles in said photocatalytic functional layer is within the range of 0.10 to 0.50.

6. A photocatalytic functional material as defined in any one of claims 1 and 2, wherein said substrate is a tile.

8. A photocatalytic functional material as in claim 1, wherein said metal is Cu or Ag.

7. A method for preparing a photocatalytic functional layer, comprising the steps of:

preparing a first liquid material containing a photocatalyst and a thermosetting resin;

applying said first liquid material to the surface of a substrate;

curing said first liquid material to form a cured catalyst-resin mixture layer on said surface of said substrate;

preparing a second liquid material containing an electron-trapping metal;

applying said second liquid material to a surface of said cured catalyst-resin mixture layer; and

irradiating said second liquid material with ultraviolet light to support said metal to said surface of said cured catalyst-resin mixture layer.