Method for making high refractive index (HRI) film by adjusting the flow rate of a vaporized material

• US 6,194,031 B1
• Filed: 04/21/1999
• Issued: 02/27/2001
• Est. Priority Date: 06/04/1997
• Status: Expired due to Fees

• Current Assignee: Crown Roll Leaf, Inc.
• Original Assignee: Crown Roll Leaf, Inc.
• Inventors: Gervais, Joseph R., Barnard, Gary S.
• Primary Examiner(s): Meeks, Timothy
• Assistant Examiner(s): CHEN, BRET P
• Application Number:
  US09/295,859
• Time in Patent Office: 678 Days
• Field of Search: 427/248.1, 427/255.33, 427/255.5, 427/255.6
• US Class Current: 427/255.5
• CPC Class Codes: C23C 14/0629 of zinc, cadmium or mercury
• CPC Class Codes: C23C 14/243 Crucibles for source material C23C14/28, C23C14/30 take precedence
• CPC Class Codes: C23C 14/26 by resistance or inductive heating of the source
• CPC Class Codes: C23C 14/562 for coating elongated substrates

Abstract

This invention includes a method for heating a deposition material to form a vapor that may be deposited on a polymer film and thereby create a holographic film or similar material. Included within this method is a vaporizer that has an adjustable aperture. The vaporizer may have (i) a flexible wall that defines a cavity in which a deposition material is heated (ii) a first lip extending outward from a first side of the flexible wall and (iii) a second lip extending outward from a second side of the flexible wall. The aperture size can be adjusted to a desired cross-sectional opening by adjusting the distance of separation between the first lip and the second lip. By adjusting the size of the aperture, the flow rate of the vapor from the vaporizer can be adjusted to achieve a desired flow rate. Heat from a heat source in thermal communication with the vaporizer may be employed to heat the deposition material to form a vapor. The vaporizer may be disposed within a vacuum chamber, which has a feed roll and a take up roll. Film may be transferred from the feed roll to the take up roll so that, the vapor is deposited on the film.

Claims

1. A method of depositing a layer of a depositing material onto a film by forming a deposition vapor from the deposition material, comprising:

providing an apparatus comprising;

(a) a vacuum chamber;

(b) a feed roll, disposed within the vacuum chamber and around which a polymer film is disposed;

(c) a take-up roll, disposed within the vacuum chamber, the polymer film extending from the feed roll to the take-up roll and being moveable from the feed roll to the take up roll as the deposition vapor is deposited on the polymer film;

(d) a vaporizer, disposed below the feed roll and the take-up roll, the vaporizer having (i) a flexible wall that defines a cavity in which the deposition material is heated to form the vapor for depositing on the polymer film as the polymer film is moved from the feed roll to the take-up roll, (ii) a first lip extending outward from a first side of the flexible wall and (iii) a second lip extending outward from a second side of the flexible wall, the first lip and the second lip being separated to define an aperture through which the deposition vapor flows when the deposition material is vaporized, a size of the aperture being adjustable by adjusting the distance of separation between the first lip and the second lip; and

(e) a heat source in thermal communication with the vaporizer that is operable to transfer heat through the vaporizer to the deposition material to form the deposition vapor;

adjusting the aperture to a desired cross-sectional opening by adjusting the distance of separation between the first lip and the second lip to thereby provide a desired rate of flow of vaporized deposition material from the vaporizer;

heating the vaporizer and the deposition material to produce a vapor; and

transferring film from a feed roll to a take up roll and passing the film near the aperture so that the vapor can deposit on the film as the film is being transferred.

2. The method of claim 1, wherein the step of transferring further comprises transferring the film at a rate of about 1500 feet per minute.

3. The method of claim 1, wherein the step of adjusting further comprising clamping the first lip and the second lip of the vaporizer in a retainer.

4. The method of claim 1, wherein the deposition material comprises zinc sulfide.

5. The method of claim 1, wherein the flexible wall of the vaporizer comprises a substantially circular cross section.

6. The method of claim 1, further comprising a support structure disposed beneath and around the vaporizer that mechanically supports the vaporizer, a first contact block mounted to the support structure with at least a portion of the first lip being retained between the first contact block and the support structure and a second contact block mounted to the support structure with at least a portion of the second lip being retained between the second contact block and the support structure, the size of aperture being adjustable by adjusting the amount of the portion of the first lip that is retained between the first contact block and the support structure and the amount of the second lip that is retained between the second contact block and the support structure, and wherein the method further comprises adjusting the size of the aperture by adjusting the amount of the portion of the first lip that is retained between the first contact block and the support structure and the amount of the second lip that is retained between the second contact block and the support structure.