Photocatalyst and method of making

• US 6,194,346 B1
• Filed: 12/28/1999
• Issued: 02/27/2001
• Est. Priority Date: 08/05/1996
• Status: Expired due to Fees

• Current Assignee: Nippon Sheet Glass Company Limited (Nippon Telegraph and Telephone Corporation), NSG Techno-Research Co., Ltd.
• Original Assignee: Nippon Sheet Glass Company Limited (Nippon Telegraph and Telephone Corporation), NSG Techno-Research Co., Ltd.
• Inventors: Hattori, Akihiko, Shimoda, Koji, Ito, Toshiya, Tada, Hiroaki
• Primary Examiner(s): Wood, Elizabeth D.
• Application Number:
  US09/472,832
• Time in Patent Office: 427 Days
• Field of Search: 502/527.12, 502/224, 502/226, 502/227, 502/228, 502/229, 502/231, 502/208, 502/216
• US Class Current: 502/224
• CPC Class Codes: B01D 2255/802 Photocatalytic
• CPC Class Codes: B01D 53/8687 Organic components
• CPC Class Codes: B01D 53/885 Devices in general for catalytic purification of waste gases
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: C03C 17/256 Coating containing TiO2
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/212 TiO2
• CPC Class Codes: C03C 2217/241 with halides
• CPC Class Codes: C03C 2217/71 Photocatalytic coatings
• CPC Class Codes: C03C 2218/10 Deposition methods

Abstract

Fluorine contained within a photocatalyst layer containing titanium oxide and other metallic oxide semiconductors increases the metallic oxide'"'"'s photocatalytic activity. The described photocatalyst may be in the form of either film, flake, particulate, or fiber. In addition, it can be used for coating the surface of a base material of various forms, such as sheet, film, flake, particulate, bar, or fiber. When using a base material that has an alkaline-containing glass composition, establishing a fluorine-containing layer, such as a layer of fluorine-containing silicon dioxide and other metallic oxide, between the photocatalyst film and the base material can prevent the deterioration of photocatalytic activity of the photocatalyst layer. The fluorine-containing layer functions as an alkaline barrier that controls the diffusion and migration of alkali metallic ions in the glass fibers, such as Na ions, into the photocatalyst layer. Inorganic fiber- and glass sheet-based photocatalyst bearing materials have an excellent capability to decompose rarefied harmful organic gases, and are suitable for use as interior wall and air filters in super clean enclosed spaces and conveyance spaces for semiconductor production, clean rooms for various other purposes, and office and residential buildings, and for other purposes including air cleaning, antibacterial action, anti-fouling action, and defogging of clear sheets (maintaining hydrophilicity).

Claims

1. An article having photocatalytic effect, comprising:

a base material; and

a photocatalytic film comprising fluorine-containing crystalline metallic oxide semiconductor, the photocatalytic film covering the base material.

2. The article according to claim 1, wherein the photocatalyst film has a thickness of 20-500 nm.

3. The article according to claim 1, wherein the article is in the form of film, flake powder, or fiber.

4. The article according to claim 1, wherein the photocatalyst film comprises titanium oxide.

5. The article according to claim 1, wherein the base material comprises an inorganic or metallic material in the form of sheet, film flake, particulate, powder, bar, fiber, woven cloth, or nonwoven cloth.

6. The article according to claim 1, wherein a fluorine-containing film is present between the base material and the photocatalyst film.

7. The article according to claim 6, wherein the photocatalytic film has a portion where fluorine concentration within the photocatalytic film gradually changes in the thickness direction.

8. The article according to claim 6, wherein the fluorine-containing film has an alkaline component shielding capability.

9. The article according to claim 6, wherein the fluorine-containing film has a thickness of 20-200 nm.

10. The article according to claim 6, wherein the fluorine-containing film is a fluorine-containing silica film.

11. The article according to claim 1, wherein an alkaline shielding film, which shields diffusion of alkaline composition, is present between the base material and the photocatalyst film.

12. The article according to claim 11, wherein the alkaline shielding film has a thickness of 20-200 nm.

13. The article according to claim 11, wherein the alkaline shielding film contains fluorine in the amount of 0.1-20 percentage by atom.

14. The article according to claim 11, wherein the alkaline shielding film comprises silica.

15. The article according to claim 1, wherein the photocatalyst film comprises titanium oxide.

16. The article according to claim 1, wherein the photocatalyst film has a thickness of 5 nm to 2 μ

m.

17. The article according to claim 5, wherein the base material comprises glass fibers of soda-lime silicate glass.

18. The article according to claim 5 or 17, wherein the fiber have an average diameter of 0.20 to 5 μ

m, a thickness of 0.1-2 mm, and an air-flow resistance expressed by 3-50 mmH₂O at a air-flow speed of 320 cm/min.

19. The article according to claim 1, wherein the base material is a light transmitting, alkaline-containing glass material.

20. The article according to claim 1, wherein the photocatalytic film comprises anatase-type titanium oxide.

21. An article having photocatalytic effect, comprising:

a base material;

a photocatalytic film comprising fluorine-containing metallic oxide semiconductor, the photocatalytic film covering the base material; and

a fluorine-containing film which is present between the base material and photocatalytic film.

22. The article according to claim 21, wherein the photocatalytic film has a portion where fluorine concentration within the photocatalytic film gradually changes in the thickness direction.

23. The article according to claim 21, wherein the fluorine-containing film has an alkaline component shielding capability.

24. The article according to claim 21, wherein the fluorine-containing film has a thickness of 20-200 nm.

25. The article according to claim 21, wherein the fluorine-containing film is a fluorine-containing silica film.

26. The article according to claim 21, wherein an alkaline shielding film, which shields the diffusion of alkaline composition, is present between the base material and the photocatalytic film.

27. The article according to claim 26, wherein the alkaline shielding film has a thickness of 20-200 nm.