Electrically deposited coating agent

• US 6,200,447 B1
• Filed: 05/13/1998
• Issued: 03/13/2001
• Est. Priority Date: 11/06/1995
• Status: Expired due to Fees

• Current Assignee: BASF Coatings AG (BASF SE)
• Original Assignee: BASF Coatings AG (BASF SE)
• Inventors: Brücken, Thomas, Ott, Günther
• Primary Examiner(s): Mayekar, Kishor
• Application Number:
  US09/068,041
• Time in Patent Office: 1,035 Days
• Field of Search: 204/499, 204/501, 204/502
• US Class Current: 204/499
• CPC Class Codes: C09D 5/4492 containing special additives, e.g. grinding agents

Abstract

The present invention relates to an electrodepositable coating composition comprising binders, pigments, fillers, corrosion protection inhibitors, paint auxiliaries, catalysts if desired, organic solvents and water, which additionally comprises an organic amine salt.

Claims

1. An electrodepositable coating composition comprising a cathodically depositable binder selected from acid salts of amino-containing resins, organic solvent, water, optionally one or more additives selected from the group consisting of pigments, fillers corrosion protection inhibitors, paint auxiliaries, catalysts, and mixtures thereof, and an organic amine salt which is not reactive with the binder or an ammonium salt of formic acid, acetic acid, propionic acid or lactic acid which is not reactive with the binder.

2. The electrodepositable coating composition of claim 1, wherein the organic amine salt which is not reactive with the binder has a low molecular mass.

3. The electrodepositable coating composition of claim 2, wherein the number-average molecular mass distribution of the amine salt M_n is <

500.

4. The electrodepositable coating composition of claim 3, wherein the number-average molecular mass distribution of the amine salt M_n is <

300.

7. The electrodepositable coating composition of claim 1, comprising from 0.001 to 5% by weight of the organic amine salt.

8. The electrodepositable coating composition of claim 7, comprising from 1 to 3% by weight of the organic amine salt.

9. The electrodepositable coating composition of claim 1, wherein the binder comprises the reaction product of a resin selected from the group consisting of polyurethane resins, epoxy resins, and mixtures thereof, and one or more basic amino compounds.

10. The electrodepositable coating composition of claim 1, comprising

a) from 30 to 60% by weight of the binder,

b) from 0.001 to 5% by weight of the organic amine salt,

c) from 7 to 15% by weight of one or more pigments, and

d) from 20 to 62% by weight of water.

11. The electrodepositable coating composition of claim 10, comprising

a) from 34 to 40% by weight of the binder,

b) from 1 to 3% by weight of the organic amine salt,

c) from 8 to 10% by weight of the one or more pigments, and

d) from 47 to 57% by weight of water.

12. The electrodepositable coating composition of claim 1, having a pH below 7.

13. The electrodepositable coating composition of claim 12, having a pH between 5 and 6.8.

14. The electrodepositable coating composition of claim 1, to form a mixture and subsequently adding one or more pigments to the mixture.

15. The electrodepositable coating composition of claim 1, wherein the binder is selected from amine modified polyurethanes and amine modified epoxy resins.

16. A method of coating a substrate, comprising

providing a substrate, and

coating the substrate with the electrodepositable coating composition of claim 1.

17. The method of claim 16, wherein the substrate is a radiator.

5. The electrodepositable coating composition of clam 1, wherein the amine salt is prepared by reacting an organic amine selected from the group consisting of triethylamine, N,N-dimethylethanolamine, diisopropylamine, alkanolamines and mixtures thereof, with an organic acid selected from the group consisting of formic acid, acetic acid, propionic acid, lactic acid and mixtures thereof.

6. The electrodepositable coating composition of claim 5, wherein the amine salt is selected from the group consisting of N,N-dimethyl-N-(2-hydroxyethyl)ammonium acetate and N,N-dimethyl-N-(2-hydroxyethyl)ammonium lactate.