Organic electroluminescent device

• US 6,200,695 B1
• Filed: 12/09/1998
• Issued: 03/13/2001
• Est. Priority Date: 06/26/1998
• Status: Expired due to Term

• Current Assignee: Futaba Corporation
• Original Assignee: TDK Corporation
• Inventors: Arai, Michio, Mitsuhashi, Etsuo, Kobori, Isamu
• Primary Examiner(s): Krynski, William
• Assistant Examiner(s): Garrett, Dawn L.
• Application Number:
  US09/207,660
• Time in Patent Office: 825 Days
• Field of Search: 428/690, 428/917, 313/504, 313/505, 313/506
• US Class Current: 428/690
• CPC Class Codes: H10K 50/17 Carrier injection layers

Abstract

An organic EL device has a hole injecting electrode (2), an electron injecting electrode (3), an organic layer (5) between the electrodes, and an inorganic insulating hole injecting layer (4) between the hole injecting electrode (2) and the organic layer (5). The inorganic insulating hole injecting layer (4) consists essentially of silicon oxide or germanium oxide or a mixture of silicon oxide and germanium oxide in an average composition represented by (Si_1-xGe_x)O_y wherein x and y are 0≦x≦1 and 1.7≦y≦1.99, as analyzed by Rutherford back-scattering. The device has the advantages of both organic and inorganic materials as well as a long lifetime, improved efficiency, low operating voltage, and low cost.

Claims

1. An organic electroluminescent device comprising a hole injecting electrode, an electron injecting electrode, at least one organic layer between the electrodes, and an inorganic insulating hole injecting layer between said hole injecting electrode and said at least one organic layer,

said inorganic insulating hole injecting layer consisting essentially of silicon oxide or germanium oxide or a mixture of silicon oxide and germanium oxide and having an average composition represented by the formula:

(Si_1-xGe_x)O_y wherein x is from 0 to 1 and y is from 1.7 to 1.99, as analyzed by Rutherford back-scattering.

2. The organic electroluminescent device of claim 1 wherein x is from 0 to 1 and y is from 1.85 to 1.98.

3. The organic electroluminescent device of claim 1 wherein said inorganic insulating hole injecting layer has a thickness of 0.05 to 10 nm.

4. The organic electroluminescent device of claim 1 wherein said inorganic insulating hole injecting layer has a thickness of 0.1 to 5 nm.

5. The organic electroluminescent device of claim 1 wherein said inorganic insulating hole injecting layer has a thickness of 0.5 to 3 nm.

6. An organic electroluminescent device comprising a hole injecting electrode, an electron injecting electrode, at least one organic layer between the electrodes, and an inorganic insulating hole injecting layer between said hole injecting electrode and said at least one organic layer,

said inorganic insulating hole injecting layer consisting of silicon oxide or germanium oxide or a mixture of silicon oxide and germanium oxide and having an average composition represented by the formula: