Multi-layer golf ball utilizing silicone materials

• US 6,204,331 B1
• Filed: 03/27/1998
• Issued: 03/20/2001
• Est. Priority Date: 06/01/1993
• Status: Expired due to Fees

• Current Assignee: Callaway Golf Company (Topgolf Callaway Brands Corp.)
• Original Assignee: Spalding Sports Worldwide, Inc. (Berkshire Hathaway Incorporated)
• Inventors: Sullivan, Michael J., Keller, Viktor, Binette, Mark
• Primary Examiner(s): LE, MARK T
• Application Number:
  US09/049,769
• Time in Patent Office: 1,089 Days
• Field of Search: 525/221, 473/372, 473/373, 473/374, 473/376, 473/377
• US Class Current: 525/221
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0033 Thickness
• CPC Class Codes: A63B 37/008 Diameter
• CPC Class Codes: A63B 37/02 Special cores balls with finger holes A63B37/0001, golf ball cores A63B37/005
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 23/0876 Neutralised polymers, i.e. ionomers
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• CPC Class Codes: C08L 75/04 Polyurethanes

Abstract

The present invention is directed to an improved multi-layer golf ball comprising a core, an inner cover layer and an outer cover layer. The inner cover layer is comprised of a high acid ionomer or ionomer blend. The outer cover layer is comprised of a soft, very low modulus ionomer or ionomer blend, or a non-ionomeric thermoplastic elastomer such as polyurethane, polyester or polyesteramide. The present invention golf ball further comprises at least one interior layer and/or a core comprising a silicone material. The resulting multi-layered golf ball of the present invention provides for enhanced distance without sacrificing playability or durability when compared to known multi-layer golf balls.

Claims

1. A golf ball comprising:

a core;

at least one interior layer surrounding said core and disposed between said core and a cover layer, wherein said at least one interior layer comprises an ionomeric resin including at least 16% by weight of an alpha, beta-unsaturated carboxylic acid, and

wherein at least one interior layer comprises a silicone material selected from the group consisting of silicone polymers, silicone fluids, silicone elastomers, and combinations thereof.

2. A golf ball according to claim 1 wherein said silicone material is a silicone polymer.

3. A golf ball according to claim 1 wherein said silicone material is a silicone elastomer.

4. A golf ball according to claim 1 wherein said cover layer comprises an inner cover layer molded on at least one interior layer, and an outer cover layer molded on said inner cover layer.

5. A multi-layer golf ball comprising a silicone material;

a spherical core comprising a silicone material;

an inner cover layer disposed about said spherical core to form a spherical intermediate ball, said inner cover layer comprising an ionomeric resin including about 17% to about 25% by weight of an alpha, beta-unsaturated carboxylic acid an having a modulus of from about 15,000 to about 70,000 psi;

an outer cover layer molded over said spherical intermediate ball to form a multi-layer golf ball, the outer layer comprising a non-ionomeric thermoplastic selected from the group consisting of polyester elastomer, polyester polyurethane and polyester amide, said outer cover layer having a modulus in a range of about 1,000 to about 30,000 psi; and

at least one interior layer disposed about said core and said outer cover layer, said interior layer comprising a silicone material.

6. A golf ball comprising:

a core;

an inner cover layer disposed about said core, the inner cover layer comprising a high acid ionomer including at least 16% by weight of an alpha, beta-unsaturated carboxylic acid;

an outer cover layer molded on said inner cover layer, said outer cover layer comprising a relatively soft polymeric material selected from the group consisting of low flexural modulus ionomer resins and non-ionomeric thermoplastic elastomers; and

at least one interior layer disposed between said core and said outer cover layer, said interior layer comprising a silicone material.

7. A golf ball according to claim 6 wherein the inner cover layer comprises a high acid ionomer resin comprising a copolymer of about 17% to about 25% by weight of an alpha, beta-unsaturated carboxylic acid.

8. A golf ball according to claim 6 wherein the inner cover layer comprises a high acid ionomer resin comprising a copolymer of about 18.5% to about 21.5% by weight of an alpha, beta-unsaturated carboxylic acid.

9. A golf ball according to claim 6, wherein the inner cover layer has a thickness of about 0.100 to about 0.010 inches and the outer cover layer has a thickness of about 0.010 to about 0.05 inches, the golf ball having an overall diameter of 1.680 inches or more.

10. A golf ball according to claim 6 wherein the inner cover layer has a thickness of about 0.0300 to 0.375 inches and the outer cover layer has a thickness of about 0.030 to 0.375 inches, the golf ball having an overall diameter of 1.680 inches or more.

11. A golf ball according to claim 6 wherein the outer layer comprises a low flexural modulus ionomer resin which includes a blend of a hard high modulus ionomer with a soft low modulus ionomer, the high modulus ionomer being a sodium, zinc, magnesium or lithium salt of a copolymer having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, the low modulus ionomer being a sodium or zinc salt of a terpolymer of an olefin having 2 to 8 carbon atoms, acrylic acid and an unsaturated monomer of the acrylate ester class having from 1 to 21 carbon atoms.

12. A golf ball according to claim 11 wherein the outer layer composition includes 90 to 10 percent by weight of the hard high modulus ionomer resin and about 10 to 90 percent by weight of the soft low modulus ionomer resin.

13. A golf ball according to claim 11 wherein the outer layer composition includes 75 to 25 percent by weight of the hard high modulus ionomer resin and about 25 to 75 percent by weight of the soft low modulus ionomer resin.

14. A golf ball according to claim 6 wherein the non-ionomeric thermoplastic elastomer is a polyester polyurethane.

15. A golf ball according to claim 14 wherein the inner cover layer comprises a high acid ionomer resin comprising a copolymer of about 18.5% to about 21.5% by weight of an alpha, beta-unsaturated carboxylic acid.

16. A golf ball according to claim 14 wherein the inner cover layer has a thickness of about 0.030 to 0.375 inches and the outer cover layer has a thickness of about 0.030 to 0.375 inches, the golf ball having an overall diameter of 1.680 inches or more.

17. A golf ball according to claim 6 wherein the non-ionomeric thermoplastic elastomer is a polyester elastomer.

18. A golf ball according to claim 6 wherein the non-ionomeric thermoplastic elastomer is a polyester amide.

19. A golf ball according to claim 6 wherein said silicone material, upon curing, has a Shore 00 hardness of from about 55 to about 100.

20. A golf ball according to claim 6 wherein said silicone material, upon curing, has a tensile strength of from about 300 psi to about 600 psi.

21. A golf ball according to claim 6 wherein said silicone material, upon curing, exhibits an elongation of from about 350% to about 650%.

22. A multi-layer golf ball comprising:

a spherical core;

an inner cover layer disposed about said spherical core to form a spherical intermediate ball, said inner cover layer comprising an ionomeric resin including at least 16% by weight of an alpha, beta-unsaturated carboxylic acid and having a modulus of from about 15,000 to about 70,000 psi;

an outer cover layer molded over said spherical intermediate ball to form a multi-layer golf ball, the outer layer comprising a blend of i) a sodium or zinc salt of a copolymer having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, and ii) a sodium or zinc salt of a terpolymer of an olefin having 2 to 8 carbon atoms, acrylic acid and an unsaturated monomer of the acrylate ester class having a modulus in a range of about 1,000 to about 30,000 psi; and

at least one interior layer disposed between said core and said outer layer, said interior layer comprising a silicone material.

23. A multi-layer golf ball comprising:

a spherical core;

an inner cover layer disposed about said spherical core to form a spherical intermediate ball, said inner cover layer comprising an ionomeric resin including about 17% to about 25% by weight of an alpha, beta-unsaturated carboxylic acid and having a modulus of from about 15,000 to about 70,000 psi;

an outer cover layer molded over said spherical intermediate ball to form a multi-layer golf ball, the outer layer comprising a non-ionomeric thermoplastic selected from the group consisting of polyester elastomer, polyester polyurethane and polyester amide, said outer cover layer having a modulus in a range of about 1,000 to about 30,000 psi; and

at least one interior layer disposed between said core and said outer cover layer, said interior layer comprising a silicone material.

24. A golf ball comprising:

a core comprising a silicone material;

an inner layer disposed about said core, the inner cover layer comprising a high acid ionomer including at least 16% by weight of an alpha, beta-unsaturated carboxylic acid;

an outer cover layer molded on said inner cover layer, said outer cover layer comprising a relatively soft polymeric material selected from the group consisting of a low flexural modulus ionomer resins and non-ionomeric thermoplastic elastomers; and

at least one interior layer disposed between said core and said outer cover layer, said interior layer comprising a silicone material.

25. A golf ball according to claim 24 wherein the inner cover layer comprises a high acid ionomer resin comprising a copolymer of about 17% to about 25% by weight of an alpha, beta-unsaturated carboxylic acid.

26. A golf ball according to claim 24 wherein the inner cover layer comprises a high acid ionomer resin comprising a copolymer of about 18.5% to about 21.5% by weight of an alpha, beta-unsaturated carboxylic acid.

27. A golf ball according to claim 24, wherein the inner cover layer has a thickness of about 0.100 to about 0.010 inches and the outer cover layer has a thickness of about 0.010 to about 0.05 inches, the golf ball having an overall diameter of 1.680 inches or more.

28. A golf ball according to claim 24 wherein the outer cover layer comprises a low flexural modulus ionomer resin which includes a blend of a hard high modulus ionomer with a soft low modulus ionomer, the high modulus ionomer being a sodium, zinc, magnesium or lithium salt of a copolymer having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, the low modulus ionomer being a sodium or zinc salt of a terpolymer of an olefin having 2 to 8 carbon atoms, acrylic acid and an unsaturated monomer of the acrylate ester class having from 1 to 21 carbon atoms.

29. A golf ball according to claim 28 wherein the outer cover layer composition includes 90 to 10 percent by weight of the hard high modulus ionomer resin and about 10 to 90 percent by weight of the soft low modulus ionomer resin.

30. A golf ball according to claim 28 wherein the outer cover layer composition includes 75 to 25 percent by weight of the hard high modulus ionomer resin and about 25 to 75 percent by weight of the soft low modulus ionomer resin.

31. A golf ball according to claim 24 wherein the non-ionomeric thermoplastic elastomer is a polyester polyurethane.

32. A golf ball according to claim 24 wherein the non-ionomeric thermoplastic elastomer is a polyester elastomer.

33. A golf ball according to claim 24 wherein the non-ionomeric thermoplastic elastomer is a polyester amide.

34. A golf ball according to claim 24 wherein said silicone material, upon curing, has a Shore 00 hardness of from about 55 to about 100.

35. A golf ball according to claim 24 wherein said silicone material, upon curing, has a tensile strength of from about 300 psi to about 600 psi.

36. A golf ball according to claim 24 wherein said silicone material, upon curing, exhibits an elongation of from about 350% to about 650%.

37. A multi-layer golf ball comprising:

a spherical core comprising a silicone material;

an inner cover layer disposed about said spherical core, said inner cover layer comprising an ionomeric resin including at least 16% by weight of an alpha, beta-unsaturated carboxylic acid and having a modulus of from about 15,000 to about 70,000 psi;

an outer cover layer molded over said spherical intermediate ball to form a multi-layer golf ball, the outer layer comprising a blend of i) a sodium or zinc salt of a copolymer having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, and ii) a sodium or zinc salt of a terpolymer of an olefin having 2 to 8 carbon atoms, acrylic acid and an unsaturated monomer of the acrylate ester class having from 1 to 21 carbon atoms, said outer cover layer having a modulus in a range of about 1,000 to about 30,000 psi; and

at least one interior layer disposed between said core and said outer cover layer, said interior layer comprising a silicone material.