Method of disposing of waste in a coking process

• US 6,204,421 B1
• Filed: 11/03/1998
• Issued: 03/20/2001
• Est. Priority Date: 11/03/1998
• Status: Expired due to Term

• Current Assignee: U.S. Filter/Scaltech, Inc.
• Original Assignee: Scaltech, Inc. (Siemens AG)
• Inventors: Ruth, Raymond R., Genssler, Klaus
• Primary Examiner(s): Griffin, Walter D.
• Assistant Examiner(s): Dang, Thuan D.
• Application Number:
  US09/185,394
• Time in Patent Office: 868 Days
• Field of Search: 208/50, 208/131, 208/187, 208/13, 201/2.5, 201/25, 585/240
• US Class Current: 585/240
• CPC Class Codes: C10B 55/00 Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material cracking oils C10G
• CPC Class Codes: C10G 9/005 Coking (in order to produce liquid products mainly)

Abstract

A method for recycling a waste stream containing water and solids comprises (a) removing water from the waste stream to produce a second stream containing less than 60% by weight water, (b) drying the second stream to produce a waste feed charge containing less than 15% by weight water, and (c) injecting the waste feed charge into a coker during the coking cycle. The water removal can be carried out in one or more steps, and can be carried out in a vertical disk centrifuge if it is also desired to reduce the particle size of the solids fraction. The waste feed charge can be injected into a delayed coker, flexicoker, or fluid coker, and allows the recycle of solid waste into the coke.

Claims

1. A method for recycling a waste stream containing water and solids, comprising:

(a) removing water from the waste stream to produce a second stream containing less than 60% by weight water;

(b) drying the second stream to produce a waste feed charge containing less than 15% by weight water and at least 30% by weight solids; and

(c) injecting the waste feed charge into a coker during the coking cycle.

2. The method of claim 1 wherein the second stream is further dried to produce a waste feed charge containing less than 3% by weight water.

3. The method of claim 1, further including mixing sufficient oil into the waste feed charge to render the waste feed charge pumpable.

4. The method of claim 1 wherein the solids and oil are in approximately equal proportions in the waste feed charge.

5. The method of claim 1, further including emulsifying the second stream.

6. The method of claim 1, further including reducing the average particle size of the solids to less than 250 microns prior to step (c).

7. A method for recycling solid components of a waste stream, comprising:

(a) separating the solids from the waste stream to produce a solids charge;

(b) adding oil to the solids charge in an amount 0.5 and 1.5 times the weight of the solids;

(c) reducing the water content of the solids to less than 15 percent by weight of the total solids charge to produce a pumpable waste feed charge containing at least 30% by weight solids; and

(d) injecting the pumpable waste feed charge into a coker.

8. The method of claim 7, wherein step (d) takes place during the coking cycle.

9. The method of claim 7 wherein the pumpable feed charge is fed into the top of a coker during the coking cycle.

10. The method of claim 7 wherein the water content of the pumpable waste feed charge is less than 3 percent by weight.

11. The method of claim 7, further including the step of mixing the waste feed charge with fresh coker feedstock and injecting the mixture into a coker during coking.

12. The method of claim 7 wherein the oil added in step (b) comes from the waste stream.

32. The method of claim 7, further including the step of mixing emulsifying the pumpable waste feed charge.

13. A method for recycling components of a waste stream containing a liquid organic component, water and solids comprising:

(a) separating said waste stream into a liquid organic fraction, a water fraction, and a solids fraction containing less than about 60% by weight water in a first dewatering step;

(b) admixing oil with said solids fraction to produce a feed charge;

(c) heating said feed charge so as to evaporate water and produce a pumpable waste feed charge comprising less than about 15% by weight water, greater than about 30% by weight solids, and from about 30 to about 70% by weight oil; and

(d) injecting said waste feed charge as a feed stream into a coker during a coking operation.

14. The method of claim 13 wherein said waste feed charge comprises less than about 5% by weight water.

15. The method of claim 13 wherein said waste feed charge comprises less than about 3% by weight water.

16. The method of claim 13, further including a second de-watering step between steps (a) and (b).

17. The method of claim 13 wherein said waste feed charge comprises at least about 50% by weight solids.

18. The method of claim 13 wherein said waste feed charge comprises approximately 70% by weight solids.

19. The method of claim 13 wherein said waste feed charge comprises about 3 percent by weight water, about 50 percent by weight solids and about 47 percent by weight oil.

20. The method of claim 13 wherein said solids and said oil components are present in said waste feed charge in approximately equal proportions.

21. The method of claim 13 wherein step (a) is carried out using a vertical disk centrifuge.

22. The method of claim 13 wherein step (a) is carried out using a decanter.

23. The method of claim 13 wherein the coker in step (d) is a delayed coker.

24. The method of claim 13 wherein the coker in step (d) is a flexicoker.

25. The method of claim 13 wherein the coker in step (d) is a fluid coker.

26. The method of claim 13 wherein step (d) comprises adding said waste feed charge to the top of a coker.

27. The method of claim 13, further including the step of mixing the waste feed charge with fresh coker feed and injecting the mixture into a coker.

28. The method of claim 13 wherein said solids have a mean particle size less than 250 microns.

29. The method of claim 13 wherein said solids have a mean particle size less than 75 microns.

30. The method of claim 13 wherein the oil added in step (b) comes from the waste stream.

31. The method of claim 13 further including reducing the size of the particulates making up the solids.

33. The method of claim 13, further including the step of mixing emulsifying the pumpable waste feed charge.