Toner particles of controlled morphology

• US 6,207,338 B1
• Filed: 03/10/1999
• Issued: 03/27/2001
• Est. Priority Date: 03/10/1999
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Ezenyilimba, Matthew C., Regan, Michael T.
• Primary Examiner(s): Dote, Janis L.
• Application Number:
  US09/265,750
• Time in Patent Office: 748 Days
• Field of Search: 430/137, 430/109, 430/110, 430/111, 524/780, 524/786, 524/714, 523/333, 523/339
• US Class Current: 430/108.2
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium

Abstract

A method for the preparation of electrostatographic toner comprising the steps of:

a) dissolving a polymer material in an organic solvent to form an organic phase;

b) dispersing the organic phase in an aqueous phase comprising a salt selected from aluminum salt and gallium salt and a particulate stabilizer to form a dispersion and homogenizing the resultant dispersion;

c) evaporating the organic solvent and recovering a resultant product; and

d) washing and drying the resultant product.

Claims

1. A method for the preparation of electrostatographic toner comprising the steps of:

a) dissolving a polymer material in an organic solvent to form an organic phase;

b) dispersing the organic phase in an aqueous phase comprising a salt selected from the group consisting of aluminum salt and gallium salt and a particulate stabilizer to form a dispersion and homogenizing the resultant dispersion;

c) evaporating the organic solvent and recovering a resultant product; and

d) washing and drying the resultant product.

2. The method of claim 1 wherein a charge control agent is added in step a).

3. The method of claim 1 wherein a pigment is added in step a).

4. The method of claim 3 wherein the pigment to salt ratio by weight ranges from 1.0:

0.5 to 1.0;

0.06.

5. The method of claim 1 wherein a promoter is added in the dispersing step in b).

6. The method of claim 1 wherein the solvent is selected from the group consisting of chloromethane, dichloromethane, ethyl acetate, n-propyl acetate, iso-propyl acetate, vinyl chloride, methyl ethyl ketone, trichloromethane, carbon tetrachloride, ethylene chloride, trichloroethane, toluene, xylene, cyclohexanone and 2-nitropropane.

7. The method of claim 1 wherein the amount of particulate stabilizer is between 1 to 15 parts, by weight, based on 100 parts of total solids in the toner.

8. The method of claim 1 wherein the ratio of the aqueous phase to the organic phase, by volume, ranges from 1:

1 to 9;

1.

9. The method of claim 1 wherein the organic phase contains lubricants.

10. The method of claim 1 wherein the organic phase contains waxes.

11. The method of claim 1 wherein the polymer material is a homopolymer or copolymer.

12. The method of claim 11 wherein the homopolymer or copolymer is selected from the group consisting of polyethylene, polypropylene, polyisobutylene, polyisopentylene, polytrifluoroolefins, polyamides, acrylic resins, ethylene-methylacrylate copolymers, ethylene-ethyl acrylate copolymers, ethylene-ethyl methacrylate copolymers, polystyrene and copolymers of styrene with unsaturated monomers, polyesters, polyvinyl resins and ethylene-allyl alcohol copolymers.

13. The method of claim 11 wherein the homopolymer or copolymer is selected from the group consisting of polytetrafluoroethylene, polytrifluorochloroethylene, polyhexamethylene adipamide, polyhexamethylene sebacamide, polycaprolactam, polymethylmethacrylate, polymethylacrylate, polyethylmethacrylate and styrene-methylmethacrylate.

14. The method of claim 1 wherein the polymer material is polyester.

15. The method of claim 1 wherein the polymer material is butyl acrylate-styrene copolymer.