Melt-blown nonwoven fabric, process for producing same and the uses thereof

• US 6,207,601 B1
• Filed: 05/18/1998
• Issued: 03/27/2001
• Est. Priority Date: 03/08/1996
• Status: Expired due to Fees

• Current Assignee: Rhodia Acetow AG
• Original Assignee: Rhodia Acetow AG
• Inventors: Maurer, Gunter, Rustemeyer, Paul, Teufel, Eberhard
• Primary Examiner(s): Copenheaver, Blaine
• Assistant Examiner(s): Guarriello, John J.
• Application Number:
  US09/077,044
• Time in Patent Office: 1,044 Days
• Field of Search: 442/322, 442/389, 442/400, 442/327, 442/373, 281/12, 156/167, 131/341, 428/401
• US Class Current: 442/333
• CPC Class Codes: A24D 3/068 Biodegradable or disintegrable
• CPC Class Codes: A24D 3/10 of cellulose or cellulose derivatives
• CPC Class Codes: D04H 1/425 Cellulose series
• CPC Class Codes: D04H 3/013 Regenerated cellulose series
• CPC Class Codes: D04H 3/077 Stick, rod or solid cylinder shaped
• CPC Class Codes: D04H 3/16 with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
• CPC Class Codes: Y10T 428/298 Physical dimension
• CPC Class Codes: Y10T 442/60 Nonwoven fabric [i.e., nonwoven strand or fiber material]
• CPC Class Codes: Y10T 442/607 Strand or fiber material is synthetic polymer
• CPC Class Codes: Y10T 442/668 Separate nonwoven fabric layers comprise chemically different strand or fiber material
• CPC Class Codes: Y10T 442/68 Melt-blown nonwoven fabric

Abstract

The disclosure relates to a melt-blown non-woven fabric based on cellulose esters, with fibers of mean diameter less than about 10 microns. The fabric contains 0-10 wt. % extractable softener, has a reflection factor determined according to DIN 53 145 Part I (1992) of more than 60% and the cellulose ester has a degree of substitution DS of about 1.5-3.0. The softener is preferably water-extractable. A melt-blown non-woven fabric is produced with the cellulose ester as follows: a cellulose ester, cellulose acetate, with a DS of about 1.5-3.0, in particular 1.7-2.7, is mixed with softener in a weight ratio of about 2:1 to 1:4 and simultaneously heated and melted. The mixture of softener and cellulose ester has a melting index MFI (210/2.16) according to DIN 53 735 of about 400 to 5 g/10 min., in particular 300 to 50 g/10 min. The melt is worked in a melt-blown spinning device into a melt-blown non-woven fabric and the softener is then extracted with a softener solvent to leave a proportion of 0-10 wt. %. The melt-blown non-woven fabric is especially suitable as a filter material.

Claims

1. A melt-blown formed fabric based on cellulose acetate having a degree of polymerization between about 150 to 400, said formed fabric having fibers with a mean fiber diameter in the range of about 2 to 8 μ

m, a retained softening agent following extraction of nearly 0 to 10% of the weight of formed fabric, a reflection factor (R∞

), determined according to DIN 53 145 Part I (1992), of more than approximately 60%, and a degree of substitution of approximately 1.7 to 2.7.

2. The fabric according to claim 1 wherein the said softening agent is extractable with water.

3. The fabric according to claim 1 wherein said softening agent is a member selected from the group consisting of triacetin, ethylene and propylene carbonate, triethyl citrate, triethylene glycol diacetate, polyethylene glycol with weight of 200-1400 and tetrahydrothiophene 1,1-dioxide.

4. The fabric according to claim 1 wherein the degree of substitution DS is about 2.2 to 2.6.

5. The fabric according to claim 1 wherein said cellulose acetate has a degree of polymerization DP of approximately 180 to 350.

6. The fabric according to claim 1 wherein the content of said softening agent is 2 to 8 weight percent.

7. The fabric according to claim 1 wherein the reflection factor (Roo) is greater than about 70%.

8. The fabric according to claim 1 wherein the cellulose acetate is a polymer blend with a member selected from the group consisting of aliphatic polyesters, acetylated starches and mixtures thereof.

9. The method of preparing a filter material which consists of preparing a melt-blown formed fabric according to claim 1.

10. The method according to claim 9 wherein said filter material is applied in tobacco smoke filters.

11. The method according to claim 10 wherein said filter material is applied in double filters for ultralight cigarettes.

12. The method according to claim 9 wherein said fabric is applied as a filter of bases or liquids.

13. The method according to claim 12 wherein said fabric is applied as a filtering material for blood.

14. A process for the production of a melt-blown formed fabric as claimed in claim 1 wherein the cellulose acetate has a degree of substitution DS of approximately 1.7 to 2.7 and a degree of polymerization between about 150 to 400, the process comprises the steps of:

a) mixing said cellulose acetate with a softening agent at a ratio by weight of approximately 2;

1 to 1;

4 of said cellulose acetate to said softening agent while being heated and converted into a melt, wherein the mixture of softening agent and cellulose acetate has a melt index MFI (210/2.16) according to DIN 53 735 of approximately 400 to 5 g/10 min;

b) processing the melt in a melt-blown spinning device to form a melt-blown formed fabric; and

c) extracting the softening agent with a solvent in which the softening agent is soluble, to leave a fraction thereof of approximately 0 to 10% of the weight of the formed fabric.

15. The process according to claim 14 wherein step b) is carried out in the presence of air at a temperature of 255°

-265°

C. and a pressure of 60 m³/h-70 m³/h.

16. The process according to claim 14 wherein the ratio by weight of said softening agent to said cellulose acetate is adjusted to approximately 3:

2 to 2;

3.

17. The process according to claim 14 wherein the temperature in step a) is adjusted to approximately 140 to 180°

C.

18. The process according to claim 14 wherein the spinning device has a spinning head and a spinneret and the temperature at the spinning head and the spinneret is adjusted in step b) to approximately 180 to 240°

C.

19. The process according to claim 14 wherein the mixing of said cellulose acetate and softening agent in step a) takes place in a parallel twin-screw extruder.

20. The process according to claim 14 wherein in step c) the softening agent is extracted with water.

21. The process according to claim 20 wherein the melt-blown formed fabric after step b) is transferred to a water bath for the extraction of the softening agent.

22. The process according to claim 21 wherein the formed fabric leaving the melt-blown spinning device after step b) is transported to a stacking arrangement, pressed to adjust the desired thickness and is subsequently in step c) subjected to extraction.

23. The process according to claim 22 wherein the melt-blown formed fabric is deposited on a stacking arrangement which is a screen, a traveling screen or a revolving screen.

24. The process according to claim 14 wherein in the formation of the melt-blown formed fabric, filaments of cellulose acetate are added in step a).

25. The process according to claim 14 wherein the melt-blown formed fabric after step b) leaving the spinning device is deposited on a base for the formation of a compound structure.

26. The process according to claim 25 wherein the base is a formed fabric of a cellulose acetate filter tow, a flat filter tow or paper.

27. The process according to claim 25 wherein said compound structure is subjected to at least one pressure and structuring for the purpose of regulating its thickness.