Method for forming encapsulated lithium electrodes having glass protective layers

• US 6,214,061 B1
• Filed: 08/25/1998
• Issued: 04/10/2001
• Est. Priority Date: 05/01/1998
• Status: Expired due to Term

• Current Assignee: PolyPlus Battery Company
• Original Assignee: PolyPlus Battery Company
• Inventors: Visco, Steven J., Tsang, Floris Y.
• Primary Examiner(s): CHANEY, CAROL DIANE
• Application Number:
  US09/139,601
• Time in Patent Office: 959 Days
• Field of Search: 296/235, 429/236, 429/218.1, 429/231.1, 429/231.95, 429/232
• US Class Current: 29/623.5
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0565 Polymeric materials, e.g. gel-type or solid-type
• CPC Class Codes: H01M 2300/0085 Immobilising or gelification of electrolyte
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/0402 Methods of deposition of the material
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/0407 by coating on an electrolyte layer
• CPC Class Codes: H01M 4/0423 Physical vapour deposition
• CPC Class Codes: H01M 4/0428 Chemical vapour deposition
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/139 Processes of manufacture
• CPC Class Codes: H01M 6/185 with oxides, hydroxides or oxysalts as solid electrolytes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

A method for fabricating an active metal electrode involves depositing lithium or other active metal electrode on a protective layer. The protective layer is a glassy or amorphous material that conducts ions of the active metal. It may be deposited on a releasable web carrier or other substrate such as polymer electrolyte layer. Lithium is then deposited on the protective layer. Finally, a current collector is attached to the lithium.

Claims

1. A method of fabricating a stand-alone active metal negative electrode that is not affixed to a positive electrode, the method comprising:

(a) forming a glassy or amorphous protective layer on a substrate, the protective layer forming a substantially impervious layer which is conductive to ions of an active metal;

(b) depositing a first active metal layer on the protective layer; and

(c) providing a current collector on the first active metal layer to form the stand-alone active metal electrode.

2. The method of claim 1, wherein the substrate on which the protective layer is formed is a releasable web carrier.

3. The method of claim 2, wherein the releasable web carrier includes a layer of copper, tin, zinc, aluminum, iron, or combination thereof on which the protective layer is formed.

4. The method of claim 1, wherein the substrate on which the protective layer is formed is an electrolyte.

5. The method of claim 1, wherein the substrate on which the protective layer is formed is a polymeric electrolyte.

6. The method of claim 1, wherein the protective layer is formed on the substrate by a physical deposition process or a chemical vapor deposition process.

7. The method of claim 1, wherein the active metal is lithium.

8. The method of claim 1, wherein the active metal is deposited by evaporation.

9. The method of claim 1, further comprising forming a second layer of the active metal on the current collector prior to providing the current collector on the first active metal layer of the protective layer.

10. The method of claim 9, wherein providing the current collector on the first active metal layer comprises bonding the second active metal layer to the first active metal layer.

11. The method of claim 1, wherein the protective layer has a thickness of between about 50 angstroms and 5 micrometers.

12. The method of claim 1, wherein the protective layer has a conductivity of between about 10⁻

8 and about 10<sup>−

2</sup> (ohm-cm)<sup>−

1</sup>.