Membrane module with layered hollow-fiber membranes

• US 6,214,232 B1
• Filed: 06/25/1999
• Issued: 04/10/2001
• Est. Priority Date: 12/21/1996
• Status: Expired due to Term

• Current Assignee: Akzo Nobel N.V. (Nouryon BV)
• Original Assignee: Akzo Nobel N.V. (Nouryon BV)
• Inventors: Wollbeck, Rudolf, Baurmeister, Ulrich
• Primary Examiner(s): Drodge, Joseph W.
• Assistant Examiner(s): SORKIN, DAVID L
• Application Number:
  US09/308,535
• Time in Patent Office: 655 Days
• Field of Search: 210/198.2, 210/321.74, 210/321.75, 210/321.76, 210/321.79, 210/321.8, 210/321.83, 210/321.84, 210/321.85, 210/321.89, 210/500.23, 210/651, 210/656, 210/805, 436/531, 436/532, 436/535, 530/810, 530/812, 530/815, 530/816, 530/817
• US Class Current: 210/651
• CPC Class Codes: B01D 61/00 Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor separation of gases or vapours by diffusion B01D53/22
• CPC Class Codes: B01D 63/024 with a single potted end
• CPC Class Codes: B01D 63/026 Wafer type modules or flat-surface type modules
• CPC Class Codes: B01D 63/04 comprising multiple hollow fibre assemblies
• CPC Class Codes: B01J 20/321 consisting of a polymer obtained by reactions involving only carbon to carbon unsaturated bonds
• CPC Class Codes: B01J 20/3212 consisting of a polymer obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds
• CPC Class Codes: B01J 20/3219 involving a particular spacer or linking group, e.g. for attaching an active group
• CPC Class Codes: B01J 20/3236 containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
• CPC Class Codes: B01J 20/3248 the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
• CPC Class Codes: B01J 20/3251 comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulphur
• CPC Class Codes: B01J 20/3257 the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
• CPC Class Codes: B01J 20/3259 comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulfur with at least one silicon atom
• CPC Class Codes: B01J 20/3261 comprising a cyclic structure not containing any of the heteroatoms nitrogen, oxygen or sulfur, e.g. aromatic structures
• CPC Class Codes: B01J 20/3274 Proteins, nucleic acids, polysaccharides, antibodies or antigens
• CPC Class Codes: B01J 20/3285 Coating or impregnation layers comprising different type of functional groups or interactions, e.g. different ligands in various parts of the sorbent, mixed mode, dual zone, bimodal, multimodal, ionic or hydrophobic, cationic or anionic, hydrophilic or hydrophobic
• CPC Class Codes: B01J 35/58 Fabrics or filaments

Abstract

An apparatus and process for substance-specific treatment of fluids, whereby the apparatus comprises a housing with a distribution space and a collection space, between which is arranged a structure of adjacent flat first and second layers containing first and second hollow-fiber membranes, respectively, and a matrix on which groups acting in a substance-specific manner for fluid treatment are immobilized, whereby the filling ratio ε of the housing determined by the hollow-fiber membranes and the matrix is greater than 0.55. The first hollow-fiber membranes are open in the direction of the distribution space and closed in the direction of the collection space, and the second hollow-fiber membranes are open in the direction of the collection space and closed in the direction of the distribution space, and the hollow fiber membranes are embedded at least at their open end in the sealing compounds. The layers contained in the apparatus are substantially of equal thickness, and each first layer is, on at least one of its sides, adjacent to a second layer and each second layer is, on at least one of its sides, adjacent to a first layer.

Claims

1. An apparatus for substance-specific treatment of a fluid comprising:

a) a housing,

b) an inlet arrangement, connected to a distribution space, for introducing the fluid to be treated into the housing,

c) an outlet arrangement, connected to a collection space, for removing the treated fluid from the housing,

d) an arrangement of first hollow-fiber membranes, and second hollow-fiber membranes,

whereby the first and second hollow-fiber membranes in the arrangement are substantially parallel to each other and each of the hollow-fiber membranes respectively have an end facing the distribution space and an end facing the collection space, whereby the first hollow-fiber membranes have cavities formed by their walls, open in the direction of the distribution space and closed in the direction of the collection space, and at least at the respective end facing the distribution space are embedded in a sealing compound that is joined in a fluid-tight manner with a wall of the housing, and whereby the second hollow-fiber membranes have cavities formed by their walls, open in the direction of the collection space and closed in the direction of the distribution space, and at least at the respective end facing the collection space are embedded in a sealing compound that is joined in a fluid-tight manner to the wall of the housing,

wherein the first hollow-fiber membranes are arranged in at least one flat first layer of adjacent first hollow-fiber membranes and the second hollow-fiber membranes are arranged in at least one flat second layer (19) of adjacent second hollow-fiber membranes, wherein each first layer is adjacent on at least one of its sides, over substantially the entire extent of its surface, to a second layer, and each second layer is adjacent on at least one of its sides, over substantially the entire extent of its surface, to a first layer, wherein the first and second layers have substantially the same thickness, wherein the housing contains a matrix on and/or in which substance-specific groups acting in a substance-specific manner are immobilized, and the filling ratio ε

of the housing is greater than 0.55.

2. The apparatus according to claim 1, wherein the hollow-fiber membranes in the layers lie next to each other in a plane.

3. The apparatus according to claim 1, wherein it contains at least three layers.

4. The apparatus according to claim 1, wherein the first and second hollow-fiber membranes are incorporated into at least one hollow fiber mat respectively.

5. The apparatus according to claim 4, wherein the hollow-fiber membranes are incorporated into the respective hollow-fiber mat using textile threads.

6. The apparatus to claim 4, wherein the at least one hollow-fiber mat is a woven mat.

7. The apparatus according to claim 4, wherein the at least one hollow-fiber mat is a knitted mat.

8. The apparatus according to claim 4, wherein the hollow-fiber membranes are incorporated into the respective hollow-fiber mat using strip-form connecting elements.

9. The apparatus according to claim 4, wherein the hollow-fiber mats have a transverse elongation less than one per cent when the mat is subjected to a transverse stress of 12 cN per cm of mat width.

10. The apparatus according to claim 1, wherein the arrangement consists of flat first layers and flat second layers that are superimposed to form a stack.

11. The apparatus according to claim 1, wherein the arrangement consists of superimposed hollow-fiber mats that each contain first or second hollow-fiber membranes, and the hollow-fiber mats are folded jointly in a zigzag manner to form a stack.

12. The apparatus according to claim 1, wherein the arrangement consists of first and second layers that are wound spirally around a winding axis substantially parallel to the hollow-fiber membranes.

13. The apparatus according to claim 1, wherein the arrangement has an alternating sequence of first and second layers.

14. The apparatus according to claim 1, wherein the arrangement is made from a sequence of equal groups, each containing three superimposed layers, whereby each group is symmetrical with respect to the first and second layers within said group.

15. The apparatus according to claim 1, wherein the first and/or second hollow-fiber membranes serve as a matrix for the groups acting in a substance-specific manner.

16. The apparatus according to claim 1, wherein fluid-permeable carrier materials are inserted between the first and second layers and serve as a matrix for the groups acting in a substance-specific manner.

17. The apparatus according to claim 16, wherein the carrier materials are semi-permeable porous flat membranes.

18. The apparatus according to claim 16, wherein the carrier materials are particles.

19. The apparatus according to claim 16, wherein the first and second hollow-fiber membranes and the carrier materials serve as the matrix for the groups acting in a substance-specific manner.

20. The apparatus according to claim 19, wherein the matrix has different groups acting in a substance-specific manner.

21. The apparatus according to claim 1, wherein the hollow-fiber membranes have a ratio V_w/V_m of the volume of their walls V_w to the volume V_m comprising the volume of their walls V_w and the volume V_c of their cavity between 0.4 and 0.9, where V_w, V_c, and V_m refer to the wall, cavity and total volumes, respectively, of an individual hollow-fiber membrane.

22. The apparatus according to claim 1, wherein the filling ratio ε

is greater than 0.7.

23. The apparatus according to claim 1, wherein the membranes contained in the housing have a mean pore diameter between 0.01 μ

m and 10 μ

m.

24. The apparatus according to claim 23, wherein the membranes have a mean pore diameter between 0.1 μ

m and 3 μ

m.

25. The apparatus according to claim 1, wherein the membranes contained in the housing have a mean porosity between 50% and 90% by volume.

26. The apparatus according to claim 1, wherein the membranes contained in the housing have a BET surface area between 2 and 300 m² per cm³ of membrane volume.

27. The apparatus according to claim 26, wherein the membranes have a BET surface area between 4 and 30 m² per cm³ of membrane volume.

28. The apparatus according to claim 1, wherein the membranes contained in the housing have a substantially isotropic structure.

29. The apparatus according to claim 20, wherein the first and second membranes and the carrier materials contained in the housing are made from cellulose, polyamide, polytetrafluoroethylene, or polyvinylidene fluoride, or modifications, blends, mixtures, or copolymers thereof.

30. The apparatus according to claim 1, wherein the groups acting in a substance-specific manner are ligands for affinity separation of ligates from a liquid to be treated.

31. The apparatus according to claim 30, wherein the ligands are coupled to the matrix via molecules of long-chain linear polymers, whereby the molecules of the long-chain linear polymers carry a plurality of ligands.

32. The apparatus according to claim 1, wherein the groups acting in a substance-specific manner are catalysts.

33. A process for substance-specific treatment of a fluid, using an apparatus according to claim 1, the process comprising at least the following steps:

a) introducing the fluid to be treated via the inlet arrangement into the distribution space in the housing, the distribution space connected to the inlet arrangement,

b) passing of the fluid from there into the cavities of the first hollow-fiber membranes and through the walls of the first hollow-fiber membranes,

c) passing of the fluid out of the walls of the first hollow-fiber membranes,

d) passing of the fluid into and through the walls of second hollow-fiber membranes,

e) passing of the fluid out of the walls of the second hollow-fiber membranes into their cavities,

f) passing of the fluid into the collection space, and,

g) removing the fluid from the housing via the outlet arrangement,

whereby the fluid on the way from the distribution space to the collection space flows through the matrix on and/or in which groups acting in a substance-specific manner are immobilized, and whereby at least one substance-specific treatment of the fluid takes place as it passes through the matrix.

34. The process according to claim 33, wherein the fluid to be treated in flowing through the matrix is successively subjected to at least two different substance-specific treatments.

35. The process according to claim 33, in that wherein the fluid to be treated is recirculated.

36. The process according to claim 33 conducted for cleaning/separation of ligates from a ligate-containing liquid by affinity, wherein the matrix is used on and/or in which ligands for the ligates are immobilized.

37. The process according to claim 33 conducted for catalytic treatment of fluids, characterized in that the matrix is used on and/or in which catalysts are immobilized.