Integral sensors for monitoring a fuel cell membrane and methods of monitoring

• US 6,214,487 B1
• Filed: 02/01/1999
• Issued: 04/10/2001
• Est. Priority Date: 02/01/1999
• Status: Expired due to Term

• Current Assignee: Google Technology Holdings LLC (Alphabet Inc.)
• Original Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Inventors: Kelley, Ronald J., Mulligan, Robert J., Pratt, Steven D., Muthuswamy, Sivakumar, Landreth, Bobby Dean, Pennisi, Robert W.
• Primary Examiner(s): Chaney, Carol
• Assistant Examiner(s): TSANG FOSTER, SUSY N
• Application Number:
  US09/241,190
• Time in Patent Office: 799 Days
• Field of Search: 429/12, 429/13, 429/18, 429/22-25, 429/27, 429/40-42, 429/61-62, 429/90-93, 429/101
• US Class Current: 429/430
• CPC Class Codes: H01M 10/4257 Smart batteries, e.g. electronic circuits inside the housing of the cells or batteries
• CPC Class Codes: H01M 10/4264 with capacitors
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 6/181 with polymeric electrolytes
• CPC Class Codes: H01M 8/02 Details electrodes H01M4/86 - H01M4/98
• CPC Class Codes: H01M 8/04 Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
• CPC Class Codes: H01M 8/1018 Polymeric electrolyte materials
• CPC Class Codes: H01M 8/1065 characterised by the form, e.g. perforated or wave-shaped
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A membrane electrode assembly consists of a polymer electrolyte membrane (100) with an electrode on each side. The polymer electrolyte membrane has an integral sensor (115) disposed on the surface. The sensor monitors the physical, thermal, chemical or electrical state of the membrane electrode assembly. Information obtained from the sensor is used to identify a defective membrane electrode assembly, and the operation of the fuel cell is altered based on the identified defective membrane electrode assembly.

Claims

1. A membrane electrode assembly having an integral sensor, comprising:

a polymer electrolyte membrane having two major surfaces and an electrode on each of the two major surfaces; and

a sensor for monitoring one or more parameters of the membrane electrode assembly, said parameters selected from the group consisting of temperature, hydration, ionic conductivity, AC impedance, resistivity, capacitance, dielectric constant, complex dielectric constant, bulk dielectric constant, and response of the membrane electrode assembly, wherein the sensor is on one of the two major surfaces, and wherein the sensor is an integral part of the membrane electrode assembly.

2. The membrane electrode assembly as described in claim 1, wherein the sensor comprises the same material as the electrode.

3. The membrane electrode assembly as described in claim 1, wherein the sensor is a resistive element, a capacitive element or a piezoelectric element.

4. The membrane electrode assembly as described in claim 1, wherein a plurality of sensors are on the polymer electrolyte membrane.

5. The membrane electrode assembly as described in claim 1, further comprising an electrical connection, a first portion attached to the sensor and a second portion extending to a perimeter of the membrane electrode assembly.

6. The membrane electrode assembly as described in claim 1, wherein the sensor is on both sides of the polymer electrolyte membrane.

7. The membrane electrode assembly as described in claim 1, wherein the sensor monitors the state of the membrane electrode assembly by measuring the impedance of the membrane electrode assembly.

8. The membrane electrode assembly as described in claim 1, wherein the sensor is electrically isolated from the electrode.

9. A method of operating a fuel cell assembly having membrane electrode assemblies with sensors, comprising the steps of;

monitoring one or more parameters of the membrane electrode assemblies via one or more sensors that are integrally on each of the membrane electrode assemblies, said parameters selected from the group consisting of temperature, hydration, ionic conductivity, AC impedance, resistivity, capacitance, dielectric constant, complex dielectric constant, bulk dielectric constant, and response; and

optimizing the operation of the fuel cell assembly in response to the monitored parameters.

10. The method as described in claim 9, wherein the steps of monitoring and optimizing are repeated to provide closed-loop feedback.

11. A membrane electrode assembly having an integral sensor, comprising a polymer electrolyte membrane having an electrode and a sensor on one major surface of the polymer electrolyte membrane to monitor one or more parameters of the membrane electrode assembly, said parameters selected from the group consisting of temperature, hydration, ionic conductivity, AC impedance, resistivity, capacitance, dielectric constant, complex dielectric constant, bulk dielectric constant, and response of the membrane electrode assembly.

12. The membrane electrode assembly as described in claim 11, wherein the sensor is a resistive element or a capacitive element.

13. A method of operating a fuel cell assembly having membrane electrode assemblies with sensors, each membrane electrode assembly comprising a polymer electrolyte membrane, the method comprising the steps of:

monitoring one or more parameters of one or more of the membrane electrode assemblies via one or more sensors integrally on the polymer electrolyte membranes in the membrane electrode assemblies, said parameters selected from the group consisting of temperature, hydration, ionic conductivity, AC impedance, resistivity, capacitance, dielectric constant, complex dielectric constant, bulk dielectric constant, and response of one or more of the membrane electrode assemblies;

identifying a membrane electrode assembly that is operating sub-optimally by using the monitored parameters; and

altering the operation of the fuel cell assembly based on the identified sub-optimal membrane electrode assembly.

14. The method as described in claim 13, wherein the step of monitoring comprises measuring the AC impedance of the membrane electrode assembly.

15. The method as described in claim 13, wherein the step of monitoring comprises pulsing the membrane electrode assembly with an AC signal and measuring the response of the membrane electrode assembly.

16. The method as described in claim 13, wherein the steps of monitoring, identifying and altering are performed while the fuel cell assembly is operating.

17. The method as described in claim 13, wherein the step of monitoring comprises measuring the complex dielectric constant of the membrane electrode assembly.

18. The method as described in claim 17, wherein the degree of hydration of the membrane electrode assembly is calculated using the measured value of the complex dielectric constant.

19. The method as described in claim 13, wherein the step of altering comprises adjusting the input of fuel or oxidant to the fuel cell assembly.

20. The method as described in claim 13, wherein the step of altering comprises reducing the fuel or oxidant to the identified membrane electrode assembly.

21. The method as described in claim 13, wherein the step of altering comprises reducing the electrical output of the fuel cell assembly.

22. The method as described in claim 13, wherein the steps of monitoring, identifying and altering are repeated to form a closed-loop feedback.

23. The method as described in claim 13, wherein the steps of monitoring, identifying and altering are per formed by a microcontroller.

24. A method of operating a fuel cell assembly having membrane electrode assemblies with sensors, comprising the steps of;

measuring the AC impedance of the membrane electrode assemblies via one or more sensors integrally on each of the membrane electrode assemblies;

identifying a membrane electrode assembly that is operating sub-optimally by using the measured AC impedance; and

altering the operation of the fuel cell assembly based on the identified sub-optimal membrane electrode assembly.

25. A method for monitoring the individual fuel cells in a fuel cell stack and altering the stack'"'"'s operation in response to said monitoring, comprising the steps of:

a. measuring one or more parameters of a membrane electrode assembly in each of said individual fuel cells via a sensor integrally on said membrane electrode assembly, said parameters selected from the group consisting of temperature, hydration, ionic conductivity, AC impedance, resistivity, capacitance, dielectric constant, complex dielectric constant, bulk dielectric constant, and response;

b. comparing the measured parameters to predetermined standards; and

c. altering the operation of the fuel cell stack when the comparison performed in step (b) indicates that the measured parameters do not meet the predetermined standards.