Compositions and process for treating metal substrates

• US 6,217,674 B1
• Filed: 05/11/1999
• Issued: 04/17/2001
• Est. Priority Date: 05/11/1999
• Status: Expired due to Fees

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Valko, Joseph T., Gray, Ralph C., Hauser, Brian T.
• Primary Examiner(s): Sheehan, John
• Assistant Examiner(s): Oltmans, Andrew L.
• Application Number:
  US09/309,849
• Time in Patent Office: 707 Days
• Field of Search: 148/247, 148/251, 148/274, 427/410, 427/419.5, 427/333, 106/14.15, 106/14.37
• US Class Current: 148/247
• CPC Class Codes: C23C 22/34 containing fluorides or complex fluorides
• CPC Class Codes: C23C 22/83 Chemical after-treatment

Abstract

A composition for passivating a metal substrate is provided. The composition is prepared by mixing together:

a) Group IIIB or IVB metal compound; and

b) a reaction product of an epoxy group-containing polymer or oligomer, a hydroxy functional acid and a dialkanolamine. The compositions, which are substantially free of chrome, are used to treat metal substrates prior to the application of a protective or decorative coating.

Claims

1. A composition for passivating metal substrates, which is substantially free of chromium and which comprises:

a) a Group IIIB or IVB metal or metal compound; and

b) from 100 to 5000 ppm of a reaction product of an epoxy group-containing polymer or oligomer with a mixture of a hydroxy functional acid and a dialkanolamine.

2. The composition of claim 1 wherein the Group IIIB or IVB metal compound is a zirconium compound.

3. The composition of claim 2 wherein the zirconium compound is hexafluorozirconic acid.

4. The composition of claim 1 wherein the epoxy group-containing polymer or oligomer is a polyglycidyl ether of a polyhydric phenol.

5. The composition of claim 4 wherein the epoxy group-containing polymer or oligomer is the diglycidyl ether of Bisphenol A.

6. The composition of claim 1 in which the dialkanolamine is diethanolamine.

7. The composition of claim 1 in which the hydroxy functional acid is dimethylolpropionic acid.

8. The composition of claim 1 wherein the epoxy group-containing polymer or oligomer, hydroxy functional acid, and dialkanolamine are reacted in a 0.6 to 5.0:

0.05 to 5.5;

1 mole ratio.

9. The composition of claim 1 wherein (a) and the reaction product are mixed together in an aqueous carrier medium.

10. The composition of claim 1 wherein component (a) constitutes from 10 to 5000 ppm metal.

13. A process for passivating a metal substrate comprising contacting the substrate with the composition of claim 1.

14. The process of claim 13 in which the metal substrate is untreated.

15. The process of claim 13 in which the metal substrate is phosphated.

16. The process of claim 13 wherein the Group IIIB or IVB metal or metal compound and the reaction product are mixed together in an aqueous carrier medium.

17. The process of claim 16 wherein the metal substrate is contacted with the composition at a temperature of from 60 to 150°

F. (15 to 65°

C.).

18. The process of claim 16 wherein the metal substrate is contacted with the composition by immersion.

19. The process of claim 13 wherein the Group IIIB or IVB metal compound is a zirconium compound.

20. The process of claim 19 wherein the zirconium compound is hexafluorozirconic acid.

21. The process of claim 16 wherein the component (a) constitutes from 10 to 5000 ppm metal.

22. The process of claim 16 wherein component (b) constitutes from 100 to 5000 ppm.

23. The process of claim 13 wherein the metal substrate is selected from cold rolled steel, steel coated or plated with zinc metal, zinc compounds or zinc alloys, aluminum, aluminum alloys and a multimetal substrate containing two or more metals selected from the group consisting of cold rolled steel, steel coated or plated with zinc metal, zinc compounds or zinc alloys and aluminum.

24. The process of claim 13 in which the metal substrate comprises more than one metal.

25. The process of claim 13 in which the metal substrate comprises a multimetal substrate containing two or more metals selected from the group consisting of cold rolled steel, steel coated or plated with zinc metal and aluminum.

26. The process of claim 13 further comprising the step of:

a) after contacting the metal substrate with the composition, electrodepositing a coating on the substrate.

27. The process of claim 13 further comprising the step of:

a) after contacting the metal substrate with the composition, applying by non-electrophoretic means a primer coating to the substrate.

28. The process of claim 27 in which the primer coating is a zinc-rich primer coating.

29. The process of claim 13 further comprising the step of:

a) after contacting the metal substrate with the composition, applying a powder coating composition to the substrate.

11. A composition for passivating metal substrates, which is substantially free of chromium and which is prepared by mixing together:

a) a zirconium compound; and

b) a reaction product of a polyglycidyl ether of a polyhydric phenol, dimethylolpropionic acid and a dialkanolamine.

12. The composition of claim 11 in which the polyglycidyl ether of a polyhydric phenol, dimethylolpropionic acid and dialkanolamine are reacted in a 0.6 to 5.0:

0.05 to 5.5;

1 mole ratio.