Method of making straight fuel cell tubes

• US 6,217,822 B1
• Filed: 02/09/1998
• Issued: 04/17/2001
• Est. Priority Date: 02/09/1998
• Status: Expired due to Term

• Current Assignee: Siemens Energy Incorporated (Siemens AG)
• Original Assignee: Siemens Westinghouse Power Corporation
• Inventors: Borglum, Brian P.
• Primary Examiner(s): Fiorilla, Christopher A.
• Application Number:
  US09/021,054
• Time in Patent Office: 1,163 Days
• Field of Search: 264/671, 264/234, 264/632, 264/634, 264/232
• US Class Current: 264/632
• CPC Class Codes: B28B 11/243 Setting, e.g. drying, dehydrating or firing ceramic articles B28B11/242 takes precedence
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 2300/0074 Ion conductive at high temperature
• CPC Class Codes: H01M 4/8885 Sintering or firing
• CPC Class Codes: H01M 4/9033 Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
• CPC Class Codes: H01M 8/1231 with both reactants being gaseous or vaporised
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A method and an apparatus for making straight fuel cell tubes are disclosed. Extruded tubes comprising powders of fuel cell material and a solvent are dried by rotating the extruded tubes. The rotation process provides uniform circumferential drying which results in uniform linear shrinkage of the tubes. The resultant dried tubes are very straight, thereby eliminating subsequent straightening steps required with conventional processes. The method is particularly useful for forming inner air electrode tubes of solid oxide fuel cells.

Claims

1. A method of drying a fuel cell tube consisting essentially of:

forming a tube from a mixture comprising ceramic fuel cell powder and solvent; and

rotating the formed tube substantially about an axis of the tube to at least partially remove the solvent from the formed tube to thereby produce a dried unsintered fuel cell tube.

2. The method of claim 1, wherein the tube is formed by extruding the mixture.

3. The method of claim 1, wherein the formed tube includes an open end and a closed end.

4. The method of claim 1, wherein the ceramic fuel cell powder comprises La_1-X(M1)_XMn_1-Y(M2)_YO₃ where M1 is calcium, strontium, yttrium, cerium, other appropriate dopants or combinations thereof, M2 is nickel, chromium, zinc, colbalt, other appropriate dopants or combinations thereof, X is from 0 to about 0.5, and Y is from 0 to about 0.5.

5. The method of claim 1, wherein the solvent comprises water, propanol, butyl acetate, butoxyethanol or a combination thereof.

6. The method of claim 1, wherein the solvent comprises water.

7. The method of claim 6, wherein substantially all of the water is removed from the formed tube.

8. The method on claim 1, wherein the mixture further comprises at least one organic binder selected from the group consisting of methylcellulose, hydroxyproply methylcellulose, polyvinyl alcohol, polyvinyl butyral resin or acrylic polymer.

9. The method on claim 1, wherein the mixture further comprises at least one plasticizer selected from the group consisting of polyethylene glycol, butylbenzl phthalate or polymeric fatty acids.

10. The method of claim 1, further comprising rotating the formed tube about a substantially horizontal axis.

11. The method of claim 1, further comprising rotating the formed tube continuously.

12. The method of claim 11, further comprising rotating the formed tube at a speed of from about 0.1 to about 20 rpm.

13. The method of claim 1, further comprising rotating the formed tube on two opposing rollers.

14. The method of claim 1, wherein each opposing roller has a diameter of from about 25 to about 200 percent of an outer diameter of the formed tube.

15. The method of claim 1, further comprising rotating the formed tube in ambient air.

16. The method of claim 1, further comprising directing gas against the rotating formed tube to accelerate the drying thereof.

17. The method of claim 16, wherein the gas is air.

18. The method of claim 17, wherein the air is dehumidified.

19. The method of claim 1, wherein the dried fuel cell tube is substantially straight.

20. The method of claim 19, wherein the dried fuel cell tube has an axial bow of less than about 0.15 mm per meter.

21. The method of claim 1, further comprising sintering the dried fuel cell tube.

22. The method of claim 21, further comprising rotating the formed tube about a substantially horizontal axis and sintering the dried fuel cell tube about the substantially horizontal axis.

23. The method of claim 1, where the fuel cell tube is an air electrode of a solid oxide fuel cell.

24. The method of claim 1, wherein the step of rotating the formed tube is performed on rollers, and further comprising the step of removing the dried unsintered fuel cell tube from the rollers.

25. The method of claim 1, wherein the formed tube has a maximum outer diameter of 2.45 cm.

26. The method of claim 1, wherein the formed tube has a maximum thickness of about 0.5 cm.