Dioxole coated membrane module for ultrafiltration or microfiltration of aqueous suspensions

• US 6,221,247 B1
• Filed: 06/03/1999
• Issued: 04/24/2001
• Est. Priority Date: 06/03/1999
• Status: Expired due to Fees

• Current Assignee: Cms Technologies Holdings, Inc.
• Original Assignee: Cms Technologies Holdings, Inc.
• Inventors: Cragg, George Alfred, Nemser, Stuart Marshall
• Primary Examiner(s): Fortuna, Ana
• Assistant Examiner(s): Ward, Richard W.
• Application Number:
  US09/324,897
• Time in Patent Office: 691 Days
• Field of Search: 210/500.27, 210/500.28, 210/500.36, 210/506, 210/650, 210/651, 210/490, 210/321.6, 555/24
• US Class Current: 210/321.6
• CPC Class Codes: B01D 61/14 Ultrafiltration; Microfiltration
• CPC Class Codes: B01D 61/145 Ultrafiltration
• CPC Class Codes: B01D 61/147 Microfiltration
• CPC Class Codes: B01D 61/18 Apparatus therefor
• CPC Class Codes: B01D 63/061 Manufacturing thereof
• CPC Class Codes: B01D 67/0088 Physical treatment with compounds, e.g. swelling, coating or impregnation
• CPC Class Codes: B01D 69/02 characterised by their properties
• CPC Class Codes: B01D 71/32 containing fluorine atoms
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration

Abstract

A filter useful for the ultrafiltration and microfiltration of aqueous suspensions includes a microporous membrane structure that has pores of size effective to reject particles in the range of about 0.01-10 μm. At least a portion of the membrane structure in contact with the suspension has a surface energy less than that of polytetrafluoroethylene. Low surface energy can be achieved by coating a microporous substrate with a substance such as fluorine substituted dioxole polymer. The filter has superior resistance to fouling by species suspended in the aqueous suspension and can continuously filter flow of such suspension in excess of 100 L/(m²−h) for more than 150 hours. The new filter is useful in many traditionally fouling prone ultrafiltration and microfiltration membrane applications such as the filtering of shipboard generated graywater waste.

Claims

1. A membrane module comprising a two-sided microporous membrane structure having passageways through the structure of a size effective to reject species suspended in an aqueous medium which species are of size in the range of about 0.01-10 μ

m, said structure capable of passing a simulated graywater from a boiled mixture of a composition consisting of 435 mg detergent, 2 g laundry starch, 750 mg gelatin, 50 ml of 5% ammonium chloride solution, 15 ml of 1 M sodium chloride solution, 2.5 ml 1 M trisodium phosphate solution, 10 g canned dog food, 350 mg food shortening, 350 mg cooking oil per 5 L of tap water at a rate of at least 100 L/(m²−

h) continuously for longer than 150 hours when operated in a cross flow mode,

in which said membrane structure comprises a microporous substrate having its microporous surfaces coated with a substance comprising a polymerized perfluoro-dioxole monomer having the following formula

in which Y is either F or the perfluoroalkoxylic moiety —

OR_F of 1-5 carbon atoms and X₁ and X₂ are both CF₃ when Y is F, and X₁ and X₂ are each independently selected from the group consisting of F and CF₃ when Y is —

OR_F, and

in which the substance has a surface energy less than that of tetrafluoroethylene homopolymer.

2. The membrane module of claim 1 in which the substance comprises a copolymer comprising copolymerized 2,2,4-trifluoro-5-trifluoromethoxy-1,3-dioxole.

3. The membrane module of claim 1 in which the substance consists essentially of copolymerized perfluoro-2,2-dimethyl-1,3-dioxole, tetrafluoroethylene and maleic anhydride.

4. The membrane module of claim 1 in which the species comprise biological matter.

5. The membrane module of claim 4 in which the aqueous medium is drinking water and the species include microorganisms.

6. The membrane module of claim 1 in which the surface energy is at most 16 dynes/cm.