Oil quality sensor

• US 6,223,589 B1
• Filed: 04/26/1999
• Issued: 05/01/2001
• Est. Priority Date: 10/26/1996
• Status: Expired due to Fees

• Current Assignee: Volkswagen AG
• Original Assignee: Volkswagen AG
• Inventors: Forth, Peter, Lieberzeit, Peter, Marquardt, Klaus Dieter, Dickert, Franz, Voigt, Gunter
• Primary Examiner(s): Williams, Hezron
• Assistant Examiner(s): CYGAN, MICHAEL T
• Application Number:
  US09/299,126
• Time in Patent Office: 736 Days
• Field of Search: 73/61.45, 73/581, 73/579, 73/53.01, 73/61.43, 73/61.44, 73/61.49, 73/61.41, 73/61.62, 73/54.41, 310/312, 310/313
• US Class Current: 73/61.45
• CPC Class Codes: G01N 11/16 by measuring damping effect upon oscillatory body
• CPC Class Codes: G01N 2291/0258 Structural degradation, e.g. fatigue of composites, ageing of oils
• CPC Class Codes: G01N 2291/02818 Density, viscosity
• CPC Class Codes: G01N 2291/0427 Flexural waves, plate waves, e.g. Lamb waves, tuning fork, cantilever
• CPC Class Codes: G01N 29/036 by measuring frequency or resonance of acoustic waves
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

The chemical and/or physico-chemical determination of the ageing of a motor oil is very expensive and requires measuring methods which cannot be carried out on board a motor vehicle. The determination of only one oil condition parameter, for example the viscosity, only enables conditional statements to be made with respect to oil quality since conflicting effects may exist to varying degrees in this case. According to the invention, oil quality can be determined by a quartz base coated with a sensitive layer. The sensitive layer has a surface or volume which is adapted to an oil component and is suitable for the repeated incorporation and release of the oil component according to the concentration thereof. When the oil component is present, it is incorporated in the sensitive layer causing the resonant frequency of the layer to decrease via a mass effect or causing an effective increase of the component thickness or mass. As the oil ages, the proportion of the component incorporated in the sensitive layer decreases, so that the resonant frequency increases. A non-sensitive layer is used as a reference by which the viscosity effect of the oil on the oscillation of the quartz and the variation in viscosity of the motor oil are determined as a second important oil quality parameter.

Claims

1. A process for determining the content of an analyte which is a selected motor oil constituent in a motor oil comprising:

providing a sensor having a sensitive layer with at least one of a surface especially adapted to releasably absorb or adsorb at least one specific analyte which is a motor oil constituent and a layer volume especially adapted to releasably absorb or adsorb at least one specific analyte which is a motor oil constituent, which surface or layer volume is arranged for repeated analyte-specific incorporation or release of the analyte;

bringing a motor oil containing the analyte into contact with the sensitive layer; and

determining a weight change of the sensitive layer according to an existing affinity of the analyte to the layer, wherein the sensor is arranged for determining ageing of a motor oil.

2. A process according to claim 1 wherein the sensitive layer is a polymer.

7. A process according to one of claims 6 and 2 wherein the polymer is selected from the group consisting of a cross-linked polyurethane and a derivatized polyurethane.

8. A process according to claim 6 or 2 wherein the polymer contains basic groups.

9. A process according to claim 6 or 2 wherein the polymer contains amino groups.

10. A process according to claim 6 or 2 wherein the polymer is formed in the presence of used motor oil or is imprinted with used motor oil.

3. A process for determining the content of an analyte which is a selected motor oil constituent in a liquid phase comprising providing a molecular-imprinted material and determining the content of an analyte corresponding to the molecular imprint in the motor oil by determining a weight change of the material wherein the content of the analyte is used to determine ageing of a motor oil.

4. A process according to claim 3 wherein the molecular-imprinted material is contained in a sensor.

5. A process according to claim 3 wherein the molecular-imprinted material has at least one of a surface adapted to at least one analyte and a layer volume adapted to at least one analyte, and the surface or layer volume is arranged, according to an existing affinity of the analyte to the molecular-imprinted layer, for repeated analyte-specific incorporation and release of the analyte.

6. A process according to claim 3 wherein the molecular imprinted material is a polymer.

11. A process for determining the content of an analyte which is a selected motor oil constituent in a motor oil comprising providing a sensor having a sensitive layer with at least one of a surface adapted to releasably absorb or adsorb at least one specific analyte and a layer volume adapted to releasably absorb or adsorb at least one specific analyte which is a motor oil constituent, and in which the surface or volume is arranged, according to an existing affinity of the analyte to the layer, for repeated analyte-specific incorporation or release of the analyte, and bringing the sensitive layer into contact with an analyte, wherein the sensor is arranged for determining ageing of a motor oil.

12. A process according to claim 11 wherein the analyte is a constituent of a motor oil for a combustion engine.

13. A process according to claim 12 wherein the analyte is a constituent of a motor oil group consisting of a fresh motor oil and a used motor oil.