Preblended carrier starches for corrugating adhesives

• US 6,228,158 B1
• Filed: 04/16/1999
• Issued: 05/08/2001
• Est. Priority Date: 04/16/1999
• Status: Active Grant

• Current Assignee: Corn Products International Incorporated (Ingredion Incorporated)
• Original Assignee: Corn Products International Incorporated (Ingredion Incorporated)
• Inventors: Skuratowicz, Roman
• Primary Examiner(s): BRUNSMAN, DAVID M
• Application Number:
  US09/293,610
• Time in Patent Office: 753 Days
• Field of Search: 106/617, 106/208.1, 106/208.3, 106/210.1, 106/217.3, 156/291, 156/336, 428/182
• US Class Current: 106/208.1
• CPC Class Codes: B32B 3/28 characterised by a layer comprising a deformed thin sheet , i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled B32B29/08 takes precedence
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C09J 103/02 Starch; Degradation products thereof, e.g. dextrin
• CPC Class Codes: C09J 103/10 Oxidised starch
• CPC Class Codes: Y10T 428/24694 Parallel corrugations

Abstract

A dry preblended carrier starch for corrugating adhesive compositions comprising modified starch and a dry alkali, the modified starch being preferably oxidized starch and the dry alkali being sodium metasilicate or trisodium phosphate. The dry preblended carrier starch for corrugating adhesives has improved viscosity stability over time and temperature fluctuations, eliminates the need for added caustic at end use or at the corrugator and does not require additional silicate compounds in the corrugating adhesive.

Claims

1. A dry preblended carrier starch for corrugating adhesives comprising an admixture of from about 70% to 90% by dry weight of oxidized starch and from about 30% to 10% by dry weight of dry alkali selected from the group consisting of sodium metasilicate and trisodium phosphate wherein said dry preblended carrier starch, when dissolved in water, forms a carrier phase for a corrugating adhesive which does not require the addition of caustic compounds or silicates.

2. The dry preblended carrier starch of claim 1 wherein said oxidized starch is hypochlorite-oxidized starch.

3. The dry preblended carrier starch of claim 1 further comprising mineral oil.

4. The dry preblended carrier starch of claim 1 further comprising fillers and bulking agents.

5. A corrugating adhesive comprising the carrier starch of claim 1.

6. A corrugated board comprising the carrier starch of claim 1.

7. A method of making a dry preblended carrier starch comprising dry mixing from about 70% dry weight to about 90% dry weight oxidized starch with about 30% dry weight to about 10% dry weight dry alkali selected from the group consisting of sodium metasilicate and trisodium phosphate.

8. The method of claim 7 wherein said oxidized starch is hypochlorite-oxidized starch.

9. The method of claim 7 comprising the additional step of adding mineral oil when mixing said modified starch and dry alkali.

10. The method of claim 7 comprising the additional step of adding fillers and bulking agents when mixing said modified starch and dry alkali.

11. A method for making a corrugating adhesive comprising:

a) preparing a carrier phase by heating water under agitation to a temperature from about 120°

F. to about 180°

F. and then admixing under continuous agitation a dry preblended carrier starch comprising from about 70% dry weight to about 90% dry weight oxidized starch and from about 30% dry weight to about 10% dry weight dry alkali selected from the group consisting of sodium metasilicate and trisodium phosphate with said heated water, the amount of dry preblended carrier starch being such that the mixture comprises around 1% to around 8% dry alkali based on total weight of said carrier phase;

b) preparing a suspended phase by admixing water, starch and borax; and

c) admixing said carrier phase and said slurry phase, wherein said corrugating adhesive is prepared without any caustic or additional silicate compounds.

12. The method of claim 11 wherein said oxidized starch hypochlorite-oxidized starch.

13. The method of claim 11 comprising the additional step of adding cooling water to said carrier phase after said carrier phase is prepared.

14. The method of claim 11 wherein said carrier phase is prepared by heating water under agitation to a temperature of at least about 135°

F.

15. A corrugating adhesive which does not require the addition of caustic compounds or silicates which in an aqueous emulsion comprises

from about 2% to about 10% by weight of the adhesive of an admixture of from about 70% to about 90% by dry weight of oxidized starch and from about 30% to about 10% by dry weight of dry alkali selected from the group consisting of sodium metasilicate and trisodium phosphate;

and

from about 98% to about 90% by weight of the adhesive of water, starch and borax wherein the starch comprises about 10 to about 30% by weight of the adhesive and borax comprises about 0.3 to about 1.0% by weight of the adhesive.

16. A method for making a corrugated board comprising joining a corrugated medium to at least one liner using a corrugating adhesive prepared with a dry preblended carrier starch comprising from about 70% dry weight to about 90% dry weight oxidized starch and from about 30% dry weight to about 10% dry weight dry alkali selected from the group consisting of sodium metasilicate and trisodium phosphate wherein said dry preblended carrier starch is admixed with heated water to form a carrier phase in which said dry alkali is present in said carrier phase in an amount of from about 1% to 8% based on total weight of carrier starch and heated water in the carrier phase, wherein said corrugating adhesive is prepared without any caustic or additional silicate compounds.