Vehicle occupant protection device and solid solution gas generating composition therefor

• US 6,231,701 B1
• Filed: 02/17/1999
• Issued: 05/15/2001
• Est. Priority Date: 03/31/1998
• Status: Expired due to Fees

• Current Assignee: TRW Inc. (Northrop Grumman Corporation)
• Original Assignee: TRW Inc. (Northrop Grumman Corporation)
• Inventors: Blomquist, Harold R.
• Primary Examiner(s): Nelson, Peter A.
• Application Number:
  US09/250,851
• Time in Patent Office: 818 Days
• Field of Search: 149/45, 149/18, 149/46
• US Class Current: 149/18
• CPC Class Codes: C06B 31/00 Compositions containing an inorganic nitrogen-oxygen salt
• CPC Class Codes: C06B 47/00 Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
• CPC Class Codes: C06D 5/00 Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets explosive compositions containing an oxidizer, fuels for rocket engines intended for reaction with an oxidant other than air C06B
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

An apparatus (12) for inflating an inflatable vehicle occupant protection device (20) comprises a gas generating material (16) which when ignited produces gas to inflate the inflatable vehicle occupant protection device (20). The gas generating material (16) comprises a solid solution of a water soluble liquid oxidizer, a cross-linked hydrophilic gelling agent, and water. The cross-linked hydrophilic gelling agent comprises an effective amount of carbon atoms to provide a combustible mixture with the liquid oxidizer. The cross-linked hydrophilic gelling agent forms a reticulated structure in which the liquid oxidizer and water are immobilized.

Claims

1. An apparatus for inflating an inflatable vehicle occupant protection device comprising a gas generating material, said gas generating material comprising a solid solution of a water soluble liquid oxidizer, a cross-linked hydrophilic polymeric gelling agent, and water;

wherein said gelling agent comprises an effective amount of carbon atoms to provide a combustible mixture with said liquid oxidizer; and

wherein said cross-linked hydrophilic gelling agent forms a reticulated structure in which the liquid oxidizer and water are immobilized.

2. The apparatus of claim 1 wherein said liquid oxidizer is hydroxyl ammonium nitrate or a derivative thereof.

3. The apparatus of claim 1 wherein said cross-linked hydrophilic gelling agent is cross-linked polyvinyl alcohol.

4. The apparatus of claim 1 wherein said the amount of water soluble liquid oxidizer in gas generating material is that amount effective to oxidize the carbon atoms in cross-linked hydrophilic polymeric gelling agent to carbon dioxide.

5. The apparatus of claim 4 wherein the amount of water soluble liquid oxidizer in the gas generating material is about 50% to about 90% by weight of the gas generating material.

6. The apparatus of claim 1 wherein the amount of cross-linked polymeric hydrophilic gelling agent in the gas generating material is about 5% to about 25% by weight of the gas generating material.

7. The apparatus of claim 1 wherein the amount of water in the gas generating material is about 1% to about 5% by weight of the gas generating material.

8. The apparatus of claim 1 wherein said gas generating material further comprises up to about 5% by weight of ammonium nitrate by weight of the gas generating material.

9. The apparatus of claim 1 wherein the gas generating material further comprises a stabilizer.

10. The apparatus of claim 1 wherein the gas generating material further comprises a burn rate catalyst.

11. The apparatus of claim 1 further comprising a non-combustible preform embedded in the gas generating material.

12. An apparatus for inflating an inflatable vehicle occupant protection device comprising a gas generating material, said gas generating material comprising a solid solution of a hydroxyl ammonium nitrate, cross-linked polyvinyl alcohol, and water;

wherein said cross-linked polyvinyl alcohol comprises an effective amount of carbon atoms to provide a combustible mixture with said hydroxyl ammonium nitrate; and

wherein said cross-linked polyvinyl alcohol forms a reticulated structure in which the hydroxyl ammonium nitrate and water are immobilized.

13. The apparatus of claim 12 wherein the amount of hydroxyl ammonium nitrate in gas generating material is that amount effective to oxidize the carbon atoms in cross-linked polyvinyl alcohol to carbon dioxide.

14. The apparatus of claim 12 wherein the amount of hydroxyl ammonium nitrate in the gas generating material is about 50% to about 90% by weight of the gas generating material.

15. The apparatus of claim 12 wherein the amount of cross-linked polyvinyl alcohol in the gas generating material is about 5% to about 25% by weight of the gas generating material.

16. The apparatus of claim 12 wherein the amount of water in the gas generating material is about 1% to about 5% by weight of the gas generating material.

17. A gas generating material comprising a solid solution of a water soluble liquid oxidizer, a hydrophilic gelling agent, a cross-linking agent, and water;

said hydrophilic gelling agent comprising an effective amount of carbon atoms to provide a combustible mixture with said liquid oxidizer;

said cross-linking agent cross-linking said hydrophilic gelling agent and forming a reticulated structure in which said liquid oxidizer and water are immobilized.

18. The gas generating material of claim 17 wherein said cross-linking agent comprises an organo-metallic complex.

19. The gas generating material of claim 18 wherein said organo-metallic complex is selected from group consisting of water soluble organic titanates and water soluble organic zirconates.