Method for injection molding for epoxy resin moldings and an injection moldable epoxy resin composition

• US 6,231,800 B1
• Filed: 07/06/1999
• Issued: 05/15/2001
• Est. Priority Date: 05/29/1996
• Status: Expired due to Term

• Current Assignee: Mitsui Chemicals
• Original Assignee: Mitsui Chemicals
• Inventors: Togashi, Eiki, Sakuraba, Tsukasa
• Primary Examiner(s): Tentoni, Leo B.
• Application Number:
  US09/348,073
• Time in Patent Office: 679 Days
• Field of Search: 264/328.2, 264/328.8, 264/328.16, 264/328.18, 264/331.12, 264/331.22
• US Class Current: 264/328.2
• CPC Class Codes: B29C 45/2756 Cold runner channels
• CPC Class Codes: B29C 45/73 of the mould B29C45/2642 and B29C45/2737 take precedence
• CPC Class Codes: B29K 2063/00 Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2101/10 Thermosetting resins
• CPC Class Codes: C08G 59/686 containing nitrogen
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Abstract

Disclosed is a method of injection-molding for epoxy resin moldings wherein an epoxy resin composition is used as starting material, a molding cycle is shortened, a continuous molding operation is possible and a waste portion after curing can be minimized as well as an injection-moldable epoxy resin composition excellent in thermal stability possessing latent-type curing characteristics capable of rapidly promoting curing reaction in a metal mold without being cured in an injection molding machine.

The aforesaid method is carried out by charging an epoxy resin composition possessing the latent-type curing characteristics into a mini-sprue metal mold which is composed of a manifold part, a mini-sprue part and an ejector-plate part and wherein a metal mold temperature at the manifold part is so maintained that the epoxy resin composition is molten but curing of the composition is not promoted, and injection-molding the composition.

Claims

1. A method of injection molding for epoxy resin moldings, comprising,

charging a curable epoxy resin composition into a mini-sprue metal mold comprising a manifold part, a mini-sprue part, a product part, and an ejector-plate part,

wherein the curable epoxy resin composition comprises epoxy resin, curing agent, curing accelerator, and inorganic filler, wherein the epoxy resin is at least one of the following types of epoxy resins:

o-cresol type epoxy resin, biphenyl type epoxy resin, naphthalene type epoxy resin, and hydroquinone type epoxy resin, and further wherein, the curable epoxy resin composition has the following latent curing properties;

(1) a gel time at 80°

C. of at least 1,500 seconds,

(2) a gel time at 100°

C. of at least 1,000 seconds, and

(3) an activating energy for the curing reaction of at least 12,000 cal/mol;

maintaining the temperature of the manifold part of said mini-sprue metal mold at a temperature at which the curable epoxy resin composition is in the molten state but less than the temperature at which the composition will cure; and

injection molding the curable epoxy resin composition in the product part of the mini-sprue metal mold.

2. The method of claim 1, further comprising maintaining the temperature of the manifold part at from 90°

C. to 130°

C. lower than the temperatures of the mini-sprue part and the product part.

3. The method of claim 1, further comprising maintaining the temperatures of the mini-sprue part and the product part of the mini-sprue metal mold in the range of from 160°

C. to 200°

C.

4. The method as claimed in claim 1, wherein the curing agent is incorporated into the epoxy resin composition in an amount of 20-70 parts by weight per 100 parts by weight of the epoxy resin.

5. The method as claimed in claim 1, wherein the curing accelerator is incorporated into the epoxy resin composition in an amount of 3-20 parts by weight per 100 parts by weight of the epoxy resin.

6. The method according to claim 1 wherein the curing agent is a phenol novolac resin.

7. The method according to claim 1 wherein the curing accelerator is an alkylurea compound selected from the group consisting of

wherein X₁ and X₂, may be the same or different and represent hydrogen atom, halogen atom, alkyl group, alkoxy group, or nitro group;

Y and Z may be the same or different and each represents a hydrogen atom, a halogen atom or an alkyl group;

each of the R'"'"'s may be the same or different and represent alkyl of from 1 to 10 carbon atoms; and

p represents an integer of 0 to 5.

8. The method according to claim 7 wherein the curing accelerator is selected from the group consisting of 3-phenyl-1,1-dimethyl urea, 3-(chlorophenyl)-1,1-dimethylurea, 3-(3,4-dichlorophenyl)-1,1-dimethylurea, 3-(o-methylphenyl)-1,1-dimethylurea, 3-(p-methylphenyl)-1,1-dimethylruea, 3-(methoxyphenyl)-1,1-dimethylurea, 3-(nitrophenyl)-1,1-dimethylurea, 1,1′

-phenylene-bis-(3,3-dimethylurea), and 1,1′

-(4-methyl-m-phenylene)-bis-(3,3-dimethylurea).

9. The method according to claim 7 wherein the curing accelerator is a dimethylamine adduct of 2,4-tolylene diisocyanate of formula (f).