Heat temperable transparent coated glass article

• US 6,231,999 B1
• Filed: 02/13/1997
• Issued: 05/15/2001
• Est. Priority Date: 06/21/1996
• Status: Expired due to Term

• Current Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Original Assignee: Cardinal IG Company (Cardinal Glass Industries Incorporated)
• Inventors: Krisko, Annette J.
• Primary Examiner(s): TURNER, ARCHENE A
• Application Number:
  US08/798,742
• Time in Patent Office: 1,552 Days
• Field of Search: 428/621, 428/622, 428/627, 428/632, 428/698, 428/701, 428/702, 428/216, 428/336, 428/469, 428/472, 428/432, 428/433, 428/434, 219/391, 359/359, 359/360, 359/585, 427/164, 427/165
• US Class Current: 428/627
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3615 Coatings of the type glass/metal/other inorganic layers, at least one layer being non-metallic
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 17/3686 the multilayer coating being used for ovens
• CPC Class Codes: C03C 2218/365 Coating different sides of a glass substrate
• CPC Class Codes: Y10T 428/12535 with additional, spatially distinct nonmetal component
• CPC Class Codes: Y10T 428/12542 More than one such component
• CPC Class Codes: Y10T 428/12576 Boride, carbide or nitride component
• CPC Class Codes: Y10T 428/1259 Oxide
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

A heat-resistant transparent glass article is formed with a film stack deposited on a glass substrate, the film stack comprising one or more infrared reflective films each bearing on its surface facing away from the substrate a protective film of niobium metal having a thickness of up to 25 Å and preferably in the range of about 7 Å to 20 Å. A protective film of niobium metal or metal oxide may be formed on the other surface (facing the substrate) of each infrared reflective film. Metal nitride films such as silicon nitride may be employed between neighboring infrared reflective films, and as an outer protective film.

Claims

1. A heat-resistant, temperable glass article comprising a glass substrate and a transparent film stack deposited upon the substrate, said film stack comprising, from the glass substrate outwardly, a first niobium metal barrier film, an infrared reflective metallic film and a second niobium metal barrier film deposited directly on the infrared reflective film at a thickness up to 25 Å

such that a thin protective film of niobium remains after heat-tempering of the glass article.

2. The article of claim 1 including a transparent nitride dielectric film further from the glass substrate than said second niobium barrier film.

3. The glass article of claim 1 wherein said infrared reflective metallic film is silver.

4. The glass article of claim 1 including a metal oxide barrier film between the first barrier film and the glass substrate and contiguous to the first barrier film.

5. A heat-resistant, temperable glass article comprising a glass substrate and a film stack deposited upon the substrate, said film stack comprising, from the glass substrate outwardly, a metal oxide barrier film, a first niobium metal barrier film, an infrared reflective silver-containing metallic film, and a second niobium metal barrier film, the first and second niobium barrier films being contiguous to the infrared reflective silver film, and the second niobium barrier film having a thickness in the range of 7 to 20 Å

.

6. The article of claim 5 including a transparent nitride film positioned further from said glass substrate than said second niobium barrier film.

7. The article of claim 5 including a transparent nitride film positioned nearer the said glass substrate than the metal oxide barrier film.

8. The article of claim 5 including a first film of a nitride positioned nearer the glass substrate than the metal oxide barrier film and a second film of a nitride positioned further from said glass substrate than the second niobium barrier film.

9. The article of claim 8 wherein at least one of said nitride films is silicon nitride.

10. A transparent heat-resistant glass article comprising a glass substrate and a transparent film stack deposited upon the substrate, said film stack comprising a plurality of transparent nitride films, an infrared reflective film positioned between neighboring transparent nitride films, and a film of niobium metal 7-20 Å

in thickness positioned between each transparent nitride film and each infrared reflective film.

11. The transparent heat-resistant glass article of claim 10 wherein said nitride films are silicon nitride.

12. A transparent heat-resistant glass article comprising a glass substrate and a transparent film stack deposited upon the substrate, said film stack comprising, from the glass substrate outwardly, a first Si₃N₄ film 100-400 Å

in thickness, a second Si₃N₄ film 100-800 Å

in thickness, and a third Si₃N₄ film 50-300 Å

in thickness, an infrared reflective silver film between the first and second Si₃N₄ films and between the second and third Si₃N₄ films, and a film of niobium metal 7-20 Å

in thickness positioned on each surface of each infrared reflective film.

13. A transparent heat-resistant glass article comprising a glass substrate and a transparent film stack deposited upon the substrate, said film stack comprising, from the glass substrate outwardly, a transparent silicon nitride film having a thickness of from 125 Å

to 500 Å

, a first protective film of niobium metal 7 to 20 Å

in thickness, a transparent infrared reflective silver film, a second protective film of niobium metal 7 to 20 Å

in thickness, and a transparent silicon nitride film having a thickness of from 350 Å

to 600 Å

.

14. A transparent heat-resistant glass article comprising a glass substrate and a transparent film stack deposited upon the substrate, said film stack comprising a film of silver contiguous to and sandwiched between protective niobium metal films that are 7 Å

to 20 Å

in thickness, and, on each side of said sandwich structure, a transparent film capable of liberating nitrogen upon being heated to glass tempering temperatures.

15. Method for manufacturing a transparent glass article comprising depositing on a surface of a glass substrate a transparent film stack comprising, from the glass surface outwardly, a first niobium metal barrier film, a transparent infrared reflective metallic film, a second niobium metal barrier film 7 Å

to 20 Å

in thickness, and a transparent nitride film, and heat tempering said article to at least partially convert said barrier film to niobium nitride.

16. The method of claim 15 including the step of depositing between the second niobium metal barrier film and the transparent nitride film a metal oxide film.

17. A self-cleaning oven having a window comprising a glass sheet bearing a transparent film stack, said film stack comprising, from the glass substrate outwardly, a first niobium metal barrier film, a transparent infrared reflective metallic film, and a second barrier film of niobium metal.

18. A glass article comprising a sheet of glass having deposited on a surface thereof a transparent film stack comprising, from said glass surface outwardly, a first niobium metal barrier film, an infrared reflective metallic film and a second barrier film of niobium metal deposited directly on the infrared reflective film at a thickness up to 25 Å

.

19. The article of claim 18 including a transparent nitride dielectric film further from the glass surface than said second niobium barrier film.

20. The glass article of claim 18 wherein said infrared reflective metallic film is silver.

21. A transparent glass article comprising a glass surface and a transparent film stack deposited upon a surface thereof, said film stack comprising, from the glass surface outwardly, a transparent silicon nitride film having a thickness of from 125 Å

to 500 Å

, a first protective film of niobium metal 7 to 20 Å

in thickness, a transparent infrared reflective silver film, a second protective film of niobium metal 7 to 20 Å

in thickness, and a transparent silicon nitride film having a thickness of from 350 Å

to 600 Å

.

22. A transparent glass article comprising a glass sheet having deposited on a surface thereof a transparent film stack comprising a film of silver contiguous to and sandwiched between protective niobium metal films that are 7 Å

to 20 Å

in thickness.