Trinuclear molybdenum multifunctional additive for lubricating oils

• US 6,232,276 B1
• Filed: 04/18/1997
• Issued: 05/15/2001
• Est. Priority Date: 12/13/1996
• Status: Expired due to Term

• Current Assignee: Infineum USA LP (Infineum)
• Original Assignee: Infineum USA LP (Infineum)
• Inventors: Francisco, Manuel A., Coyle, Catherine Louise, Guzi, Peter John, Pictroski, Charles F., McConnachie, Jonathan M., Stiefel, Edward Ira, Leta, Daniel Paul
• Primary Examiner(s): Johnson, Jerry D.
• Application Number:
  US08/844,019
• Time in Patent Office: 1,488 Days
• Field of Search: 508/363, 508/364, 508/370, 508/379, 508/445, 556/38, 556/57
• US Class Current: 508/363
• CPC Class Codes: C07F 11/005 compounds without a metal-carbon linkage
• CPC Class Codes: C10M 135/18 thiocarbamic type, e.g. containing the groups
• CPC Class Codes: C10M 137/10 Thio derivatives
• CPC Class Codes: C10M 159/18 Complexes with metals
• CPC Class Codes: C10M 2219/068 Thiocarbamate metal salts
• CPC Class Codes: C10M 2223/045 Metal containing thio derivatives
• CPC Class Codes: C10M 2227/09 Complexes with metals
• CPC Class Codes: C10N 2010/12 Groups 6 or 16
• CPC Class Codes: C10N 2040/25 Internal-combustion engines
• CPC Class Codes: C10N 2040/251 Alcohol fueled engines
• CPC Class Codes: C10N 2040/255 Gasoline engines
• CPC Class Codes: C10N 2040/28 Rotary engines

Abstract

A lubricating oil composition is provided comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one trinuclear molybdenum compound. Preferably, the trinuclear molybdenum compound is selected from those compounds having the formula Mo₃S_kL₄Q_z and mixtures thereof in which L is a ligand having organo groups with a sufficient number of carbon atoms to render the compound soluble in the oil, k varies from 4 through 7, Q is selected from the group of compounds having lone pair electrons including water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5. In general, the organo groups of the mono-anionic ligands will be the same although they may be different, and they preferably are selected from alkyl, aryl, substituted aryl, and ether groups. For example, when L is a dialkyldithiocarbamate or a dialkyldithiophosphate, the alkyl groups will have from about 1 to 30 carbon atoms.

Claims

1. A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one trinuclear molybdenum compound sufficient to provide said lubricating oil composition with at least 1 ppm of molybdenum.

2. The lubricating composition of claim 1, wherein the trinuclear molybdenum compound has a sulfur-containing core.

3. The lubricating composition of claim 1, wherein the trinuclear molybdenum compound is selected from compounds having the formula Mo₃S_kL_nQ_z, and mixtures thereof, wherein L represents independently selected ligands, n is 1 to 4, k is 4 through 7, Q is an electron donating compound, and z is 0 to 5.

4. The lubricating composition of claim 3 wherein the neutral electron donating compound is selected from the group of water, amines, alcohols, phosphines, and ethers.

5. The lubricating composition of claim 3 wherein the ligands, L, are represented by one or more of the structures having the formula

wherein X, X₁, X₂, and Y are oxygen or sulfur and wherein R₁, R₂, and R are independently selected from the group of hydrogen and organo groups.

6. The lubricating composition of claim 5 wherein the organo groups are independently selected from alkyl, aryl, substituted aryl, and ether groups.

7. The lubricating composition of claim 6 wherein the organo groups are alkyl groups and the number of carbon atoms in each alkyl group ranges from about 1 to 100.

8. The lubricating composition of claim 7 wherein the number of carbon atoms in each alkyl group ranges from about 4 to about 20.

9. The lubricating composition of claim 8 wherein the ligands are independently selected from the group of dialkyldithiophosphate, thioxanthates, dialkylphosphate, dialkyldithiocarbamate, dialkylthiophosphate, and xanthates.

10. The composition of claim 5 wherein the trinuclear molybdenum compound ligand'"'"'s organo groups have a sufficient number of carbon atoms to render the trinuclear molybdenum compound soluble or dispersible in oil.

11. The lubricating composition of claim 5 wherein the trinuclear molybdenum compounds have a total of at least 21 carbon atoms among all the ligands'"'"' organo groups.

12. The lubricating composition of claim 1 wherein the weight of the molybdenum from the trinuclear molybdenum compound ranges from 1 to 1000 ppm based on the weight of the lubricating composition.

13. The lubricating composition of claim 1 wherein the molybdenum in the trinuclear molybdenum compound is in the +4 oxidation state.

14. The composition of claim 1 wherein the trinuclear molybdenum compound is oil soluble.

15. The composition of claim 1 wherein the trinuclear molybdenum compound is dispersible in oil.

16. The lubricating composition of claim 2 wherein the trinuclear molybdenum compound contains sulfur and wherein the lubricating composition further comprises added sulfur containing compounds.

17. The lubricating composition of claim 1 wherein the trinuclear molybdenum compound contains sulfur and wherein the lubricating composition is substantially free of added sulfur containing compounds.

18. The lubricating composition of claim 1 wherein the trinuclear molybdenum compound contains phosphorus and wherein the lubricating composition further comprises added phosphorus containing compounds.

19. The lubricating composition of claim 1 wherein the trinuclear molybdenum compound contains phosphorus and wherein the lubricating composition is substantially free of added phosphorus containing compounds.

20. The lubricating composition of claim 1 wherein the oil is substantially free of sulfur.

21. An additive concentrate for blending with lubricating oils comprising an oleagenous carrier and from about 1 to about 200,000 ppm by weight of the molybdenum of a trinuclear molybdenum compound based on the weight of the concentrate.

22. A method for preparing an oil soluble trinuclear thiomolybdenum compound comprising combining a liquid containing a molybdenum source, a ligand source, and a sulfur source other than the molybdenum source in order to form an oil soluble trinuclear thiomolybdenum compound.

23. The method of claim 22 wherein the molybdenum source is selected from the group of Mo₃S₁₃²⁻

and trinuclear thiomolybdenum halides.

24. The method of claim 22 wherein the liquid is water.

25. The method of claim 22 wherein the liquid is an organic liquid.

26. The product of claim 22.

27. A method for preparing a lubricating oil composition comprising combining an oil of lubricating viscosity and an amount of a trinuclear molybdenum compound sufficient to provide said lubricating oil composition with at least about 1 ppm of molybdenum.

28. The product of claim 27.

29. A compound having the formula Mo₃S_kL_nQ_z wherein the L are independently selected ligands, n varies from 1 to 4, k varies from 4 through 7, Q is selected from the group of neutral electron donating compounds, and z ranges from 0 to 5, wherein the compound has a core selected from the group of cores having the structures

and ligands selected from the group of ligands having the formulas

wherein X, X₁, X₂, and Y oxygen or sulfur and wherein R₁, R₂, and R are independently selected the group of hydrogen and organo groups, wherein at least 21 carbon atoms are present among all the ligands'"'"' organo groups.

30. A lubricating composition comprising a major amount of an oil of lubricating viscosity and a minor amount of a compound having the formula Mo₃S_kL_nQ_z wherein the L are independently selected ligands, n varies from 1 to 4, k varies from 4 through 7, Q is selected from the group of neutral electron donating compounds, and z ranges from 0 to 5, wherein the compound has a core selected from the group of cores having the structures

and ligands selected from the group of ligands having the formulas

wherein X, X₁, X₂, and Y oxygen or sulfur and wherein R₁, R₂, and R are independently selected the group of hydrogen and organo groups.

31. A method for lubricating an internal combustion engine, comprising:

adding to an oil of lubricating viscosity a compound containing at least one trinuclear molybdenum core in an amount sufficient to provide said oil with at least 1 ppm of molybdenum, and treating moving parts of the internal combustion engine with said oil.