Ink jet recording ink

• US 6,232,370 B1
• Filed: 02/21/1997
• Issued: 05/15/2001
• Est. Priority Date: 02/22/1996
• Status: Expired due to Term

• Current Assignee: Seiko Epson Corporation (Seiko Group)
• Original Assignee: Seiko Epson Corporation (Seiko Group)
• Inventors: Takemoto, Kiyohiko, Miyabayashi, Toshiyuki, Watanabe, Kazuaki, Kubota, Kazuhide
• Primary Examiner(s): Michl, Paul R.
• Application Number:
  US08/816,748
• Time in Patent Office: 1,544 Days
• Field of Search: 523/161
• US Class Current: 523/161
• CPC Class Codes: B41J 2/2107 characterised by the ink properties supplying ink in a solid state B41J2/17593
• CPC Class Codes: B41M 3/00 Printing processes to produce particular kinds of printed work, e.g. patterns printing apparatus or machines of special type or for particular purposes B41F17/00; special designs or pictures per se B44F; manufacturing printed circuits using printing techniques H05K3/12 ; manufacturing organic semiconductor devices using printing techniques H10K71/13
• CPC Class Codes: B41M 3/001 using chemical colour-formers or chemical reactions, e.g. leuco dyes or acids
• CPC Class Codes: C09D 11/30 Inkjet printing inks
• CPC Class Codes: C09D 11/322 Pigment inks
• CPC Class Codes: C09D 11/54 Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/3188 Next to cellulosic
• CPC Class Codes: Y10T 428/31895 Paper or wood

Abstract

A pigment-based ink composition for ink jet recording is provided which can offer prints having excellent scratch resistance and free from uneven printing. Ink jet recording is carried out using an ink composition comprising a pigment and an inorganic oxide colloid in combination. Further, the use of a recording head equipped with a nozzle plate (101), which has been treated to form a fluoropolymer-containing plating layer (104) thereon for rendering the nozzle plate (101) water-repellent, can realize printing free from the ejection of ink droplets with trajectories non-perpendicular to the print head.

Claims

1. An ink composition for ink jet recording having components comprising at least a colorant selected from the group consisting of carbon black and an organic pigment, an inorganic colloid, a resin emulsion and an aqueous solvent, said components being present in respective amounts sufficient to allow the ink composition to be ejected from a recording head and deposited on a recording medium to form a print with the colorant evenly distributed in the print.

2. The ink composition according to claim 1, wherein the inorganic oxide colloid is colloidal silica.

3. The ink composition according to claim 1, further comprising a saccharide.

4. The ink composition according to claim 1, wherein the resin emulsion is an epoxy-containing resin emulsion or the ink composition further comprises an epoxy containing compound having a functional group reactive with an epoxy group.

5. The ink composition according to claim 4, wherein the resin emulsion is an epoxy-containing resin emulsion.

6. The ink composition according to claim 5, wherein the epoxy-containing resin emulsion comprises a copolymer comprising recurring units represented by the following formulae (I) and (II):

wherein R¹ and R³ independently represent H or CH₃, R² represents a group containing at least one member selected from alkyl, hydroxyl, carboxyl, and sulfonic groups.

7. The ink composition according to any one of claims 1-3 or 4-6, which is usable for ink jet recording with a recording head equipped with a nozzle plate having a fluoropolymer-containing plating layer.

8. The ink composition according to claim 7, wherein the fluoropolymer-containing plating layer is obtainable by an eutectoid plating method.

9. A ink jet recording method comprising the steps of:

ejecting droplets of an ink composition with an ink jet recording head, and depositing the droplet onto a recording medium to perform printing,

wherein the ink composition is the ink composition according to any one of claims 1-3 or 4-7.

10. The ink composition according to claim 1, wherein the ink composition consists essentially of said colorant, said inorganic oxide colloid, said resin emulsion and said aqueous solvent, said colorant being present in the ink composition in an amount of between 0.5 to 25% by weight, said inorganic oxide colloid being present in the ink composition in an amount of between 0.1 to 15% by weight, and said resin emulsion being present in the ink composition in an amount of 0.1 to 40% by weight.

11. The in jet recording method according to claim 9, wherein the fluoropolymer-containing plating layer is obtainable by an eutectoid plating method.

12. A combination comprising the ink composition of claim 10 and ink jet recording head means, including an ink jet recording head, for ejecting droplets of the ink composition onto a recording medium.

13. The ink composition according to claim 4, wherein the resin emulsion does not contain an epoxy group, wherein the ink composition consists essentially of said colorant, said inorganic oxide colloid, said resin emulsion, said epoxy-containing compound, and said aqueous solvent, said colorant being present in the ink composition in an amount of between 0.5 to 25% by weight, said inorganic oxide colloid being present in the ink composition in an amount of between 0.1 to 15% by weight, said resin emulsion being present in the ink composition in an amount of 0.1 to 40% by weight and said epoxy-containing compound being present in the ink composition in an amount of 1 to 10% by weight.

14. The ink composition according to claim 1, wherein the ink composition consists essentially of said colorant, said saccharide, said inorganic oxide colloid, said resin emulsion and said aqueous solvent, said colorant being present in the ink composition in an amount of between 0.5 to 25% by weight, said inorganic oxide colloid being present in the ink composition in an amount of between 0.1 to 15% by weight, said resin emulsion being present in the ink composition in an amount of 0.1 to 40% by weight, and said saccharide being present in the ink composition in an amount of 0.5 to 30% by weight.

15. The combination of claim 10, wherein the ink jet recording head has a nozzle plate having a fluoropolymer-containing plating layer.

16. An ink composition according to claim 4 further comprising a dispersant which is a styrene/acrylic acid copolymer, said composition consisting essentially of:

carbon black 5% by weight

styrene/acrylic acid copolymer 1% by weight

colloidal silica 5% by weight

epoxy-containing acrylic resin emulsion 3% by weight

glycerin 10% by weight

2-pyrrolidone 2% by weight

water balance.

17. An ink composition according to claim 1, wherein the components are present in respective amounts such that the ink composition is ejectable from an ink jet recording head to form a print wherein the difference between a maximum optical density value of the print and a minimum optical density of the print is less than 0.4.