Room temperature lamination of Li-ion polymer electrodes

• US 6,235,065 B1
• Filed: 10/27/1998
• Issued: 05/22/2001
• Est. Priority Date: 10/27/1998
• Status: Expired due to Fees

• Current Assignee: Alcatel SA (Nokia Corporation)
• Original Assignee: Alcatel SA (Nokia Corporation)
• Inventors: Pasquier, Eric
• Primary Examiner(s): Kalafut, Stephen
• Assistant Examiner(s): ALEJANDRO, RAYMOND
• Application Number:
  US09/179,414
• Time in Patent Office: 938 Days
• Field of Search: 296/235, 296/231, 296/232, 296/234, 429/247, 429/249, 429/137, 429/145, 419/65
• US Class Current: 29/623.4
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/0585 of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 50/46 Separators, membranes or diaphragms characterised by their combination with electrodes
• CPC Class Codes: H01M 6/188 Processes of manufacture
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/49112 including laminating of indefinite length material
• CPC Class Codes: Y10T 29/49114 including adhesively bonding
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

According to an exemplary embodiment a polyvinylidene diflouride homopolymer and solvent, such as acetone, are mixed together to form a solution. The solution is coated on a porous electrode. The coated electrode is immersed in a bath, such as denatured Ethanol, thereby creating a porous membrane on the electrode. The membrane coated electrode is then dried. After drying membrane coated electrode is placed opposite another porous electrode with the membrane positioned substantially between the first and second electrodes. The membrane is compressed between the electrodes dry bonding the membrane with the other electrode thereby forming a good physical bound. Alternatively the membrane may be formed on both electrodes and the membranes are then compressed between the electrodes thereby dry bonding the first and second electrodes together. In yet another embodiment the membrane may be formed separately then compressed between the electrodes thereby dry bonding the membrane with the two electrodes.

Claims

1. A method of manufacturing an electrolytic cell comprising the steps of:

placing a porous membrane between a first electrode and second electrode;

compressing the membrane between the electrodes at a room temperature thereby dry bonding the membrane to the electrodes.

2. The method of claim 1 wherein said step of compressing further comprises calendering said membrane and first electrode with said second electrode.

3. The method of claim 1, wherein the first electrode as a porosity substantially between 25-40% and said second electrode as a porosity substantially between 25 to 40%.

4. The method of claim 1, wherein said step of compressing further comprises compressing said membrane to at least 20% of an original thickness of said membrane.

5. The method of claim 1, wherein said membrane initially has a porosity of at least 50%.

6. The method of claim 5, wherein said membrane is formed of a polyvinylidene diflouride homopolymer.

7. The method of claim 1, wherein said dry bond has an adhesion force greater than 10 N/cm².

8. A method of manufacturing an electrolytic cell comprising the steps of:

mixing a polyvinylidene diflouride homopolymer and solvent to form a solution;

coating said solution on said first electrode;

coating said solution on said second electrode;

immersing said first and second coated electrodes in a liquid filled bath thereby creating a porous membrane on said first and second electrodes;

drying the first and second coated electrodes;

placing the first electrode opposite said second electrode with the respective membranes positioned substantially between said first and second electrodes;

compressing the membranes between the first and second electrodes thereby dry bonding said first and second electrodes together.

9. The method of claim 8 wherein said step of compressing further comprises compressing said membrane at least 25% of an original thickness of said membrane.

10. The method of claim 8, wherein said step of creating said porous membranes on said first and second electrodes further comprises creating said membranes having a porosity of at least 60%.

11. The method of claim 10, wherein said step of creating said porous membranes on said first and second electrodes further comprises creating said membrane on said first electrode having a thickness of 50 μ

m to 120 μ

m and said membrane on said second electrode having a thickness of 25 μ

m to 100 μ

m.

12. An electrolytic cell made according to the method of claim 11.

13. A method of manufacturing a lithium secondary cell including a microporous ployvinylidene difluoride homopolymer (PVdF) membrane comprising the steps of:

providing a lithium based electrode;

placing the PVdF membrane on said electrode; and

compressing said electrode and membrane at a room temperature, wherein said electrode and the PVdF membrane are dry bonded with an adhesion force of at least 10 N/cm².

14. The method of claim 13, wherein the step of compression compresses said membrane to at least 70 percent of its original thickness.

15. A Lithium ion cell manufactured according to the method of claim 14.