Apparatus for producing electrolytic water

• US 6,235,186 B1
• Filed: 05/21/1999
• Issued: 05/22/2001
• Est. Priority Date: 05/26/1998
• Status: Expired due to Fees

• Current Assignee: Chlorine Engineers Corp., Ltd.
• Original Assignee: Permelec Electrode, Ltd.
• Inventors: Hayamizu, Naoya, Tanaka, Masashi, Nishiki, Yoshinori, Sakurai, Naoaki
• Primary Examiner(s): Gorgos, Kathryn
• Assistant Examiner(s): Parsons, Thomas H
• Application Number:
  US09/315,945
• Time in Patent Office: 732 Days
• Field of Search: 205/464, 205/758, 205/521, 204/253, 204/282, 204/630
• US Class Current: 205/521
• CPC Class Codes: C02F 1/42 by ion-exchange ion-exchange in general B01J
• CPC Class Codes: C02F 1/46109 Electrodes
• CPC Class Codes: C02F 1/4618 for producing "ionised" acidic or basic water
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 2001/46142 Catalytic coating
• CPC Class Codes: C02F 2001/46161 Porous electrodes
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C02F 2201/46195 Cells containing solid electrolyte
• CPC Class Codes: C02F 2209/04 Oxidation reduction potential [ORP]
• CPC Class Codes: C02F 9/00 Multistage treatment of water, waste water or sewage

Abstract

An apparatus for producing electrolytic water in which the yielded electrolytic water does not suffer quality deterioration caused by chemical species, e.g., hydrogen ions, moving to the counter-electrode chamber. A diaphragm 4 of a two-chamber type electrolytic cell comprises two or more ion-exchange membranes 3, and a noble-metal layer 2 or another layer may be formed in the diaphragm. Use of the ion-exchange membranes produces an enhanced physical screening effect, while formation of the noble-metal layer produces catalytic effect to decompose chemical species. Both the ion-exchange membranes and the anode-metal layer are effective in diminishing the movement of chemical species to the counter-electrode chamber.

Claims

1. An apparatus for producing electrolytic water comprising a two-chamber electrolytic cell partitioned by a diaphragm into an anode chamber having a gas- and liquid-permeable anode and a cathode chamber having a gas- and liquid-permeable cathode, said diaphragm comprising at least two ion-exchange membranes in intimate contact with each other or comprising at least two ion-exchange membranes and a metal foil intimately sandwiched between two of the ion-exchange membranes, and wherein the anode and the cathode are disposed on opposing sides of said diaphragm.

2. The apparatus for producing electrolytic water of claim 1, wherein at least one of the ion-exchange membranes has a noble-metal layer, which noble-metal layer is disposed so as to be in contact with neither the anode nor the cathode.

3. The apparatus for producing electrolytic water of claim 1, wherein the diaphragm comprises at least one foil of a hydrogen occlusion metal or alloy interposed between two of the ion-exchange membranes.

4. The apparatus for producing electrolytic water of claim 3, wherein the hydrogen occlusion metal or alloy is selected from the group consisting of Pd, Pd—

Au, Pd—

Ag and La—

Ni.

5. The apparatus for producing electrolytic water of claim 1, wherein at least one of the ion-exchange membranes comprises a fibrous resin support or the diaphragm has at least one fibrous resin support interposed between two of the ion-exchange membranes.

6. The apparatus for producing electrolytic water of claim 5, wherein the fibrous resin support has a thickness of 0.01 to 5 mm.

7. The apparatus for producing electrolytic water of claim 5, wherein the fibrous resin support comprises fibers and each fiber has a thickness of 0.001 to 1 mm.

8. The apparatus for producing electrolytic water of claim 5, wherein the fibrous resin support has a porosity of 20 to 95%.

9. The apparatus for producing electrolytic water of claim 5, wherein the fibrous resin support comprises a material selected from the group consisting of hydrocarbon resins.

10. The apparatus for producing electrolytic water of claim 9, wherein the fibrous resin support is selected from the group consisting of polypropylene, polyethylene, polyvinylidene fluoride, polytetrafluoroethylene and fluorinated ethylene propylene.

11. The apparatus for producing electrolytic water of claim 1, wherein the ion-exchange membranes are perfluorocarbon ion-exchange membranes.

12. The apparatus for producing electrolytic water of claim 1, wherein the anode comprises a base and a catalyst deposited on the surface of the base.

13. The apparatus for producing electrolytic water of claim 12, wherein the base comprises noble metals, titanium, tantalum, carbon or conductive ceramics.

14. The apparatus for producing electrolytic water of claim 12, wherein the catalyst is selected from the group consisting of platinum, ruthenium, iridium, conductive ceramics and diamond.

15. The apparatus for producing electrolytic water of claim 12, wherein the catalyst is a conductive diamond.

16. The apparatus for producing electrolytic water of claim 1, wherein the cathode comprises a base and a catalyst deposited on the surface of the base.

17. The apparatus for producing electrolytic water of claim 16, wherein the base comprises noble metals, titanium, zirconium, tantalum, carbon or conductive ceramics.

18. The apparatus for producing electrolytic water of claim 16, wherein the catalyst is selected from the group consisting of platinum, ruthenium, iridium, conductive ceramics and diamond.

19. The apparatus for producing electrolytic water of claim 16, wherein the catalyst is a conductive diamond.

20. The apparatus for producing electrolytic water of claim 1, wherein said diaphragm comprises at least two ion-exchange membranes in intimate contact with each other.

21. A method for producing electrolytic water which comprises:

providing a two-chamber electrolytic cell partitioned by a diaphragm into an anode chamber having a gas- and liquid-permeable anode and a cathode chamber having a gas- and liquid-permeable cathode, said diaphragm comprising at least two ion-exchange membranes in intimate contact with each other or comprising at least two ion-exchange membranes and a metal foil intimately sandwiched between two of the ion-exchange membranes, and wherein the anode and the cathode are disposed on opposing sides of said diaphragm,

supplying pure water to the anode and cathode chambers,

passing an electric current through the electrolytic cell to produce by electrolysis anode water in the anode chamber and cathode water in the cathode chamber, said electrolysis generating hydrogen ion in the cathode chamber and hydroxyl ion in the anode chamber, and said diaphragm preventing hydroxyl ion generated in the anode chamber from entering the cathode chamber and preventing hydrogen ion generated in the cathode chamber from entering the anode chamber, and

recovering anode water and cathode water from the electrolytic cell.

22. The method for producing electrolytic water of claim 21, which comprises supplying hydrochloric acid and pure water to the anode chamber.

23. The method for producing electrolytic water of claim 21, which comprises supplying ammonium hydroxide and pure water to the cathode chamber of the electrolytic cell.