Ink jet recording medium for a pigment ink

• US 6,238,047 B1
• Filed: 08/30/1996
• Issued: 05/29/2001
• Est. Priority Date: 09/01/1995
• Status: Expired due to Term

• Current Assignee: Mitsubishi Paper Mills Limited
• Original Assignee: AGC Flat Glass Company Limited (AGC, Inc.)
• Inventors: Saito, Masaaki, Suzuki, Shinichi, Kijimuta, Hitoshi, Terayama, Sumito
• Primary Examiner(s): Barlow, John
• Assistant Examiner(s): SHAH, MANISH S
• Application Number:
  US08/705,849
• Time in Patent Office: 1,733 Days
• Field of Search: 347/105, 347/101, 347/100, 347/102
• US Class Current: 347/105
• CPC Class Codes: B41M 5/506 Intermediate layers
• CPC Class Codes: B41M 5/508 Supports
• CPC Class Codes: B41M 5/52 Macromolecular coatings
• CPC Class Codes: B41M 5/5218 characterised by inorganic additives, e.g. pigments, clays

Abstract

An ink jet recording medium for a pigment ink, which including a substrate, a porous layer of alumina hydrate having a thickness of from 1 to 200 μm, formed on the substrate, and a water-soluble resin layer having a thickness of from 0.01 to 50 μm, formed as an upper layer thereon.

Claims

1. An ink jet recording method, comprising the step of ink-jetting a pigment ink dispersed in water to a water-soluble resin layer of a recording medium which comprises a substrate, a porous layer of alumina hydrate having a thickness of from 1 to 200 μ

m formed on the substrate, and said water-soluble resin layer formed as an upper layer thereon,

wherein said water-soluble resin layer is a porous layer having a thickness of 0.01-50 μ

m, a pore radius of 1-30 nm and a pore volume per unit weight of 0.3-2.0 cc/g.

2. The ink jet recording method according to claim 1, wherein the pigment ink dispersed in water, contains a pigment in an amount of from 0.5 to 20 wt % based on the entire pigment ink.

3. The ink jet recording method according to claim 1, wherein the pigment ink dispersed in water contains carbon black as the pigment.

4. The ink jet recording method according to claim 1, wherein the water soluble resin layer comprises a water-soluble polymer having a solubility parameter of 8-23 cal/cm³ at 25°

C.

5. The ink jet recording method according to claim 1, wherein the water soluble resin layer comprises a water soluble polymer material that, when present in a 1 wt % aqueous solution, has a viscosity of 0.01-10,000 cp at 25°

C.

6. The ink jet recording method according to claim 1, wherein the water soluble resin layer comprises silica or alumina particles in an amount of 5-50%, based on the water soluble resin.

7. The ink jet recording method according to claim 1, wherein the water soluble resin layer is a non-porous film.

8. The ink jet recording method according to claim 1, wherein the water soluble resin layer comprises particles having an average particle diameter of 0.02-100 μ

m in an amount of 0.001-5 wt % based on the water soluble resin.

9. The ink jet recording method according to claim 1, wherein the water soluble resin layer comprises a water-soluble polymer selected from the group consisting of starch, oxidized starch, modified starch, grafted starch, etherified starch, esterified starch, cellulose derivative, methylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose, modified cellulose, grafted cellulose, protein, agarose, gelatin, casein, soybean protein, partially saponified polyvinyl alcohol, completely saponified polyvinyl alcohol, modified polyvinyl alcohol, carboxylated polyvinyl alcohol, olefin-modified polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl acetal, sodium polyarginate, hydrophilic urethane resin, polyacrylic acid, polyacryloamide, polyvinylmethylether imide, polyethylene imide, acrylic acid and vinyl alcohol copolymer and mixtures thereof.

10. The ink jet recording method according to claim 1, wherein the substrate comprises a material selected from the group consisting of plastic, polyester resin, polyethylene terephthalate, polycarbonate resin, fluorine resin, polytetrafluoroethylene (PTFE), paper, cloth, glass and metal.

11. The ink jet recording method according to claim 1, wherein the substrate is a transparent plastic film.

12. The ink jet recording method according to claim 1, wherein the substrate is a paper or an opaque plastic film.

13. The ink jet recording method according to claim 1, wherein the porous alumina hydrate layer comprises a binder selected from the group consisting of starch, modified starch, polyvinyl alcohol, modified polyvinyl alcohol, SBR latex, NBR latex, carboxymethylcellulose, hydroxymethylcellulose and polyvinyl pyrrolidone.

14. The ink jet recording method according to claim 1, wherein the porous alumina hydrate layer comprises a binder in an amount of 5-50 wt %, based on the alumina hydrate.

15. The ink jet recording method according to claim 1, wherein the porous alumina hydrate layer comprises pores having a pore radius of 1-30 nm in a volume per unit weight of 0.3-2.0 cc/g.

16. The ink jet recording method according to claim 1, wherein the pigment ink comprises pigment particles having a primary particle size of 15-40 nm.