Process for preparing pellets of saponified ethylene/vinyl acetate copolymer

• US 6,238,606 B1
• Filed: 05/06/1999
• Issued: 05/29/2001
• Est. Priority Date: 09/08/1997
• Status: Expired due to Term

• Current Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
• Original Assignee: Nippon Gohsei Kagaku Kogyo
• Inventors: Izumi, Koji, Ninomiya, Kenji, Kunieda, Makoto
• Primary Examiner(s): Silbaugh, Jan H.
• Assistant Examiner(s): Eashoo, Mark
• Application Number:
  US09/297,688
• Time in Patent Office: 754 Days
• Field of Search: 525/58, 264/143, 264/148, 264/178 R, 264/203, 264/183, 264/331.18
• US Class Current: 264/143
• CPC Class Codes: B29B 9/06 in the form of filamentary material, e.g. combined with extrusion
• CPC Class Codes: B29B 9/12 characterised by structure or composition
• CPC Class Codes: B29B 9/16 Auxiliary treatment of granules
• CPC Class Codes: B29K 2023/06 PE, i.e. polyethylene
• CPC Class Codes: B29K 2023/086 EVOH, i.e. ethylene vinyl alcohol copolymer
• CPC Class Codes: B29K 2105/0085 Copolymers
• CPC Class Codes: C08J 2329/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
• CPC Class Codes: C08J 3/12 Powdering or granulating

Abstract

In the method of continuously producing pellets by continuously extruding a saponified ethylene-vinyl acetate (EVOH) solution in a strand form into a coagulation liquid and then cutting the resulting strand, the ratio between the weight X of the coagulation liquid and the weight Y of the strand of the saponified ethylene-vinyl acetate copolymer, namely the ratio X/Y, is set at 50 to 10,000. The coagulation liquid preferably contains 1 to 10,000 ppm of a carboxylic acid, 1 to 50,000 ppm of a carboxylic acid ester, or 1 to 15,000 ppm of a carboxylic acid salt. It is preferred as well that the water content of the continuously produced EVOH pellets be adjusted to 20 to 80% by weight and then brought into contact with an aqueous solution, having at least one boron compound, an acetic acid salt and a phosphoric acid compound.

Claims

1. A method of continuously producing saponified ethylene-vinyl acetate copolymer pellets by continuously extruding a solution of a saponified ethylene-vinyl acetate copolymer in the form of a strand into a coagulation liquid and then cutting the resulting strand, characterized in that the ratio between the weight X of the coagulation liquid and the weight Y of the strand, prior to coagulation of the extruded solution, of the saponified ethylene-vinyl acetate copolymer, namely the ratio X/Y is set at 100 to 10,000.

2. A method of producing saponified ethylene-vinyl acetate copolymer pellets as claimed in claim 1, wherein the coagulation liquid contains 1 to 10,000 ppm of a carboxylic acid, 1 to 50,000 ppm of a carboxylic acid ester, or 1 to 15,000 ppm of a carboxylic acid salt.

3. A method of producing saponified ethylene-vinyl acetate copolymer pellets as claimed in claim 1, wherein the coagulation liquid is water or a water-methanol mixed solvent.

4. A method of producing saponified ethylene-vinyl acetate copolymer pellets as claimed in claim 3, wherein the water content of the saponified ethylene-vinyl acetate copolymer pellets continuously produced is adjusted to 20 to 80% by weight and then brought into contact with an aqueous solution of at least one compound selected from the group consisting of a boron compound (B), an acetic acid salt (C) and a phosphoric acid compound (D), and wherein, when said solution is an aqueous solution of a boron compound (B), the content of said boron compound (B) in the aqueous boron compound (B) solution is adjusted to 0.001 to 0.5 part by weight per 100 parts by weight of the total sum of the water contained in the saponified ethylene-vinyl acetate copolymer pellets and the water contained in the aqueous boron compound (B) solution, when said solution is an aqueous solution of an acetic acid salt (C), the content of said acetic acid salt (C) in the aqueous acetic acid salt (C) solution is adjusted to 0.001 to 0.5 part by weight per 100 parts by weight of the total sum of the water contained in the saponified ethylene-vinyl acetate copolymer pellets and the water contained in the aqueous acetic acid salt (C) solution, and/or

when said solution is an aqueous solution of a phosphoric acid compound (D), the content of said phosphoric acid compound (D) in the aqueous phosphoric acid compound (D) solution is adjusted to 0.0001 to 0.5 part by weight per 100 parts by weight of the total sum of the water contained in the saponified ethylene-vinyl acetate copolymer pellets and the water contained in the aqueous phosphoric acid compound (D) solution.

5. A method of producing saponified ethylene-vinyl acetate copolymer pellets which comprises subjecting the saponified ethylene-vinyl acetate copolymer pellets obtained by a production method defined in claim 1 further to drying treatment by a combination of stationary drying and fluidized drying.

6. A method of producing saponified ethylene-vinyl acetate copolymer pellets as claimed in claim 5, wherein fluidized drying is followed by stationary drying, wherein the water content of the saponified ethylene-vinyl acetate copolymer pellets before fluidized drying is 20 to 80% by weight and that after fluidized drying is 5 to 60% by weight and wherein the difference between the water content of the saponified ethylene-vinyl acetate copolymer pellets before fluidized drying and that after fluidized drying is not less than 5% by weight.