Powder coating involving compression of the coating during curing

• US 6,238,750 B1
• Filed: 10/12/1999
• Issued: 05/29/2001
• Est. Priority Date: 10/12/1999
• Status: Expired due to Fees

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Horinka, Paul R., Muthiah, Jeno, Daly, Andrew T., Correll, Glenn D.
• Primary Examiner(s): PARKER, FREDERICK JOHN
• Application Number:
  US09/415,727
• Time in Patent Office: 595 Days
• Field of Search: 264/293, 427/180, 427/194, 427/195, 427/202, 427/270, 427/277, 427/355, 427/356, 427/358, 427/359, 427/369, 427/320, 427/371, 427/508, 427/521, 427/522
• US Class Current: 427/521
• CPC Class Codes: B05D 3/0254 After-treatment
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: B05D 3/12 by mechanical means
• CPC Class Codes: B05D 7/06 to wood

Abstract

A process of forming coatings on substrates by applying a layer of curable materials in dry powder form and then melting and curing the material is improved by compressing the layer using a flexible confining membrane. Less material is required to provide equivalent barrier protection and surface finish. The process is particularly applicable to applying dry powder coatings on temperature sensitive substrates, such as medium density fiberboard, in press apparatus, such as a membrane press, which have not commercially used dry powder coating materials previously.

Claims

1. A process of forming a coating on a solid substrate, comprising:

providing a dry, free-flowing powder of a curable material, depositing said curable material on a surface of said substrate to form a layer, heating said layer sufficiently to cause said powder to melt, compressing said layer by pressing it against said substrate by use of a flexible membrane which confines said powder until it has melted and achieved a viscosity sufficient to resist migration on the substrate surface, and fully curing said layer to form said coating on said substrate.

2. The process of claim 1, wherein said substrate includes a material which degrades when maintained at a temperature of 350°

F.

3. The process of claim 1, wherein said substrate comprises lignocellulosic material.

4. The process of claim 1, wherein said curable material melts at a temperature of 180°

F. or less.

5. The process of claim 1, wherein said curable material comprises a heat activated curing agent.

6. The process of claim 5, wherein said curing agent is capable of being activated by being heated to a temperature below 350°

F.

7. The process of claim 1, wherein said curable material comprises an initiator capable of being activated by exposure to radiation.

8. The process of claim 7, wherein said curable material also comprises a component which is capable of absorbing said radiation.

9. The process of claim 1, wherein said curable material comprises a mold release agent.

10. The process of claim 1, wherein a second layer comprising a dry free-flowing powder of a second curable material is established over said first layer.

11. The process of claim 1, wherein said substrate is preheated to a temperature in excess of 150°

F. prior to establishing said layer on its surface.

12. The process of claim 1, wherein said layer is compressed before being fully cured.

13. The process of claim 1, wherein said layer is compressed while at a temperature exceeding its glass transition temperature.

14. The process of claim 1, wherein said layer is compressed by applying a pressing means against its surface at a pressure greater than 5 psi.

15. A process of forming a coating on a solid substrate, comprising:

providing a dry powder of a curable material, depositing said curable material on said solid substrate to form a layer, heating said layer sufficiently to cause said powder to melt, partially curing said layer to cause its viscosity to increase, compressing said layer by pressing it against said substrate by use of a flexible membrane which confines said powder until it has melted and achieved a viscosity sufficient to resist migration on the substrate surface, fully curing said layer to form said coating on said substrate.

16. The process of claim 15, wherein said substrate includes a material which degrades when maintained at a temperature of 350°

F.

17. The process of claim 15, wherein said substrate comprises lignocellulosic material.

18. The process of claim 15, wherein said curable material melts at a temperature of 180°

F. or less.

19. The process of claim 15, wherein said curable material comprises a heat activated curing agent.

20. The process of claim 19, wherein said curing agent is capable of being activated by being heated to a temperature below 350°

F.

21. The process of claim 15, wherein said curable material comprises an initiator capable of being activated by exposure to radiation.

22. The process of claim 21, wherein said curable material also comprises a component which is capable of absorbing said radiation.

23. The process of claim 22, wherein said step of partially curing is initiated by exposing said layer to radiation.

24. The process of claim 15, wherein a second layer comprising a dry free-flowing powder of a second curable material is established over said layer.

25. The process of claim 24, wherein said layer and said second layer are both compressed simultaneously.

26. The process of claim 24, wherein said second curable material forms a second layer which is a different color than said layer.

27. The process of claim 15, wherein said layer is compressed by applying a pressing means against its surface at a pressure greater than 5 psi.

28. The process of claim 15, wherein said substrate is preheated to a temperature in excess of 150°

F. prior to depositing said layer on its surface.

29. The process of claim 15, wherein said partial cure is initiated by exposing said layer to radiation.

30. The process of claim 15, wherein said curable material comprises a mold release agent.

31. The process of claim 15, wherein said step of partially curing said layer is initiated by heating said layer to a temperature between about 180°

and 260°

F.

32. The process of claim 15, wherein said step of partially curing said layer is initiated by exposing said layer to radiation.

33. The process of claim 32, wherein said step of fully curing said layer includes heating said layer to a temperature up to 350°

F.

34. The process of claim 15, wherein said compression of said layer occurs after said partial curing of said layer has increased the viscosity of said layer sufficiently that the layer does not drip or otherwise migrate during the compression step.

35. A process of forming a coating on a solid substrate, comprising:

providing a dry powder of a curable material, depositing said curable material on said substrate, heating said layer sufficiently to cause said powder to melt, partially curing said layer to cause its viscosity to increase, pressing a flexible membrane against the surface of said layer on said substrate, and fully curing said layer to form said coating on said substrate.

36. The process of claim 35, wherein said flexible membrane is pressed against said layer at a pressure in excess of 5 psi.

37. The process of claim 35, wherein said substrate includes a material which degrades when maintained at a temperature of 350°

F.

38. The process of claim 35, wherein said substrate comprises lignocellulosic material.

39. The process of claim 35, wherein said curable material melts at a temperature of 180°

F. or less.

40. The process of claim 35, wherein said curable material comprises a heat activated curing agent.

41. The process of claim 35, wherein said curing agent is capable of being activated by being heated to a temperature below 350°

F.

42. The process of claim 35, wherein said curable material comprises an initiator capable of being activated by exposure to radiation.

43. The process of claim 42, wherein said curable material also comprises a component which is capable of absorbing said radiation.

44. The process of claim 35, wherein said curable material comprises a mold release agent.

45. The process of claim 35, wherein a second layer comprising a dry free-flowing powder of a second curable material is established over the layer of said curable material.

46. The process of claim 45, wherein said layer and said second layer are pressed by said flexible membrane simultaneously.

47. The process of claim 45, wherein said second curable material is a different color than said curable material.

48. The process of claim 35, wherein said substrate is preheated to a temperature in excess of 150°

F. prior to establishing said layer on its surface.

49. The process of claim 35, further comprising:

confining said layer until it has melted and partially cured to a viscosity sufficient to resist migration on the substrate surface.

50. The process of claim 35, wherein said step of partially curing said molten layer is initiated by heating said layer to a temperature between about 180°

F. and 260°

F.

51. The process of claim 35, wherein said step of partially curing said layer is initiated by exposing said layer to radiation.

52. The process of claim 51, wherein said step of fully curing said layer includes heating said layer to a temperature up to 350°

F.

53. The process of claim 35, wherein said pressing of said layer occurs after said partial curing of said layer has increased the viscosity of said layer sufficiently that the layer does not drip or otherwise migrate during said pressing.

54. The process of claim 35, wherein said flexible membrane is part of an inflatable structure, and said membrane is pressed against said layer by the pressure of a fluid supplied to the interior of said structure.

55. The process of claim 54, wherein said layer is heated by heat transferred through said membrane from said fluid.

56. The process of claim 54, wherein said membrane is pressed against said layer by supplying said fluid to the interior of said inflatable structure at a pressure in excess of 5 psi.

57. The process of claim 56, wherein fluid is initially supplied to the interior of said structure at a positive pressure less than 5 psi to confine said layer until it has melted and achieved a viscosity sufficient to resist migration on the substrate surface.

58. The process of claim 54, wherein said membrane is pressed against said layer by supplying said fluid to the interior of said inflatable structure at a pressure between 10 and 1400 psi.