Transparent substrate with antireflection coating

• US 6,238,781 B1
• Filed: 09/21/1998
• Issued: 05/29/2001
• Est. Priority Date: 02/23/1995
• Status: Expired due to Term

• Current Assignee: Saint-Gobain Vitrage
• Original Assignee: Saint-Gobain Vitrage
• Inventors: Macquart, Philippe, Anderson, Charles-Edward
• Primary Examiner(s): TURNER, ARCHENE A
• Application Number:
  US09/157,516
• Time in Patent Office: 981 Days
• Field of Search: 428/216, 428/212, 428/426, 428/428, 428/432, 428/697, 428/698, 428/701, 428/702, 428/699, 428/336, 359/359, 359/580, 359/586, 359/589
• US Class Current: 428/216
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10201 Dielectric coatings
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/734 comprising an alternation of high and low refractive indexes
• CPC Class Codes: C03C 2218/365 Coating different sides of a glass substrate
• CPC Class Codes: C03C 27/10 with the aid of adhesive specially adapted for that purpose
• CPC Class Codes: Y10T 428/12792 Zn-base component
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/31616 Next to polyester [e.g., alkyd]

Abstract

The invention relates to a glass substrate having on at least one of its faces an antireflection coating formed by a stack of thin dielectric material layers having alternately high and low refractive indices. To prevent the modification of the optical properties of the coating in the case where the substrate is subject to a heat treatment such as tempering, bending or annealing, the layer or layers of the stack which are liable to deteriorate on contact with alkali ions such as sodium ions are separated form the substrate by at least one layer forming part of the antireflection coating and forming a “shield” with respect to the diffusion of alkali.

Claims

1. A coated transparent substrate, comprising:

a transparent substrate including alkali metal ions; and

an antireflection coating on at least one surface of said substrate, wherein

said coating is a stack of dielectric material layers having alternating high and low refractive indices,

at least one of said layers is a shield layer which prevents diffusion of said alkali metal ions from said substrate through said shield layer, and

said shield layer is a high refractive index dielectric material layer selected from the group consisting of silicon nitride and aluminum nitride, and

said coated transparent substrate has a light reflection R_L of at most 2% and a blue or blue-green color in reflection, with a variation of R_L of at most 0.3% and variations of a* and b* in reflection of at most 2.0 after heating.

2. The coated transparent substrate of claim 1, wherein said low refractive index dielectric material layer has a refractive index between 1.35 and 1.70 and said high refractive index dielectric material layer has a refractive index of at least 1.80.

3. The coated transparent substrate of claim 2, wherein said low refractive index dielectric material layer has a refractive index between 1.38 and 1.65 and said high refractive index dielectric material layer has a refractive index between 1.80 and 2.60.

4. The coated transparent substrate of claim 3, wherein said high refractive index dielectric material has a refractive index between 2.10 and 2.35.

5. The coated transparent substrate of claim 1, wherein said high refractive index dielectric material layer comprises an oxide selected from the group consisting of niobium oxide, tungsten oxide, bismuth oxide and cerium oxide.

6. The coated transparent substrate of claim 1, wherein said shield layer is a low refractive index dielectric material layer selected from the group consisting of SiO₂, Al₂O₃:

F and a mixture thereof.

7. The coated transparent substrate of claim 1, wherein said shield layer has an optical thickness of 25 to 60 nm.

8. The coated transparent substrate of claim 1, wherein said antireflection coating comprise two successive sequences of high and low refractive index layers, a first sequence including said shield layer and a second sequence including a layer of niobium oxide, bismuth oxide or tungsten oxide, said first sequence and said second sequence also including a low refractive index layer of silicon dioxide or a mixture of silicon and aluminum oxides.

9. The coated transparent substrate of claim 8, wherein said shield layer and said layer of niobium oxide, bismuth oxide or tungsten oxide has an optical thickness of 245-290 nm and said low refractive index layer has an optical thickness of 120-150 nm.

10. The coated transparent substrate of claim 9, said coating having the structure SnO₂/SiO₂/Nb₂O₅/SiO₂, SnO₂/SiO₂/Bi₂O₃/SiO₂ or SnO₂/SiO₂/WO₃/SiO₂.

11. The coated transparent substrate of claim 8, wherein said second sequence comprises a plurality of high refractive index layers, wherein at least one of said plurality of layers comprises niobium oxide, bismuth oxide or tungsten oxide.

12. The coated transparent substrate of claim 11, said coating having the structure SnO₂/SiO₂/Bi₂O₃/SnO₂/Bi₂O₃/SiO₂ or SnO₂/SiO₂/Nb₂O₅/SnO₂/Nb₂O₅/SiO₂.

13. The coated transparent substrate of claim 1, wherein said shield layer has a refractive index between 1.7-1.8 and an optical thickness of 80-120 nm.

14. The coated transparent substrate of claim 1, wherein at least one of said low refractive index dielectric material layers is a mixture of silicon oxide and aluminum oxide.

15. The coated transparent substrate of claim 14, wherein said at least one low refractive index layer containing said mixture is in contact with said substrate.

16. The coated transparent substrate of claim 1, having said coating on a plurality of surfaces.

17. The coated transparent substrate of claim 1, wherein R_L is at most 1%, the variation of R_L is at most 0.1% and variations of a* and b* in reflection are at most 1.5.

18. A monolithic glazing, laminated glazing or multiple glazing with interposed gas layer, comprising the coated transparent substrate of claim 1.

19. The glazing of claim 18, further comprising sun-shielding, sun-absorbing, anti-ultraviolet, anti-static, low emissive, heating, anti-soiling, security, burglar proof, sound proofing, fire protection, anti-mist, water-repellant or mirror means.

20. The glazing of claim 18, wherein said substrate is frosted, printed or screen process printed.

21. The glazing of claim 18, wherein said substrate is tinted, tempered, reinforced, bent, folded or ultraviolet filtering.

22. The glazing of claim 21, wherein said glazing is a car windshield.

23. The glazing of claim 18, having a laminated structure comprising two glass substrates and a polyvinylbutyral layer interposed therebetween, at least one outer face of said glass substrates contacting said coating.

24. The glazing of claim 23, having the structure:

antireflection coating/glass/polyvinylbutyral/glass/antireflection coating.

25. The coated transparent substrate of claim 1, wherein said shield layer is in contact with the substrate.

26. The coated transparent substrate of claim 1, wherein said stack comprises an intermediate refractive index layer in contact with said substrate and a sequence of layers of high and low refractive indices on said intermediate refractive index layer.

27. The coated transparent substrate of claim 1, wherein said coating is a stack of four layers having alternating high and low refractive indices or a stack of six layers having alternating high and low refractive indices.

28. The coated transparent substrate of claim 1, wherein one of said high refractive index layers is a superposition of two or three different layers.

29. The coated transparent substrate of claim 1, wherein said substrate comprises bent glass or tempered glass.

30. A process for producing a coated transparent substrate, the process comprising

depositing a first dielectric material layer on a glass substrate by pyrolysis of dielectric material precursors;

forming a second dielectric material layer on said first material layer by cathodic sputtering; and

forming the coated transparent substrate of claim 1.

31. The coated transparent substrate of claim 1, wherein said shield layer prevents diffusion of alkali metal ions from said substrate to a layer comprising metallic oxides having multiple valencies.