Metal complexes for use as gas generants

• US 6,241,281 B1
• Filed: 11/05/1999
• Issued: 06/05/2001
• Est. Priority Date: 07/25/1996
• Status: Expired due to Term

• Current Assignee: Northrop Grumman Innovation Systems, Inc. (Northrop Grumman Corporation)
• Original Assignee: Cordant Technologies, Inc. (Howmet Aerospace, Inc.)
• Inventors: Hinshaw, Jerald C., Doll, Daniel W., Lund, Gary K., Blau, Reed J.
• Primary Examiner(s): Carone, Michael J.
• Assistant Examiner(s): FELTON, AILEEN BAKER
• Application Number:
  US09/434,274
• Time in Patent Office: 578 Days
• Field of Search: 149/19.1, 149/45, 149/75, 149/109.6, 280/741, 602/19
• US Class Current: 280/741
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, sufficient oxidizing anion to balance the charge of the complex, and at least one cool burning organic nitrogen-containing compound. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas generating compositions and to permit efficient combustion of the binder. Such gas generating compositions are adaptable for use in gas generating devices such as automobile air bags.

Claims

1. A method of inflating an air bag comprising combusting a gas generating composition containing a complex of a transition metal cation or alkaline earth metal cation, at least one neutral ligand containing hydrogen and nitrogen, and sufficient oxidizing anion to balance the charge of the metal cation, such that when the gas generating composition combusts, a mixture of gases containing nitrogen gas and water vapor is produced, wherein the composition further contains at least one cool burning organic nitrogen-containing compound.

2. A method of inflating an air bag as defined in claim 1, wherein the combustion of the metal complex is initiated by heat.

3. A method of inflating an air bag as defined in claim 1, wherein the complex is selected from the group consisting of metal nitrite ammines, metal nitrate ammines, metal perchlorate ammines, metal nitrite hydrazines, metal nitrate hydrazines, metal perchlorate hydrazines, and mixtures thereof.

4. A method of inflating an air bag as defined in claim 1, wherein the complex is a metal nitrite ammine.

5. A method of inflating an air bag as defined in claim 1, wherein the complex is a metal nitrate ammine.

6. A method of inflating an air bag as defined in claim 1, wherein the complex is a metal perchlorate ammine.

7. A method of inflating an air bag as defined in claim 1, wherein the complex is a metal nitrite hydrazine.

8. A method of inflating an air bag as defined in claim 1, wherein the complex is a metal nitrate hydrazine.

9. A method of inflating an air bag as defined in claim 1, wherein the complex is a metal perchlorate hydrazine.

10. A method of inflating an air bag as defined in claim 1, wherein the transition metal cation is cobalt.

11. A method of inflating an air bag as defined in claim 1, wherein the transition metal cation or alkaline earth metal cation is selected from the group consisting of magnesium, manganese, nickel, titanium, copper, chromium, and zinc.

12. A method of inflating an air bag as defined in claim 1, wherein the transition metal cation is selected from the group consisting of rhodium, iridium, ruthenium, palladium, and platinum.

13. A method of inflating an air bag as defined in claim 1, wherein the oxidizing anion is coordinated with the metal cation.

14. A method of inflating an air bag as defined in claim 1, wherein the oxidizing anion is selected from the group consisting of nitrate, nitrite, chlorate, perchlorate, peroxide, superoxide, and mixtures thereof.

15. A method of inflating an air bag as defined in claim 1, wherein the inorganic oxidizing anion and the inorganic neutral ligand are free of carbon.

16. A method of inflating an air bag as defined in claim 1, wherein the complex includes at least one other common ligand, in addition to the neutral ligand.

17. A method of inflating an air bag as defined in claim 1, wherein the common ligand is selected from the group consisting of aquo (H₂O), hydroxo (OH), perhydroxo (O₂H), peroxo (O₂), carbonato (CO₃), carbonyl (CO), oxalato (C₂O₄), nitrosyl (NO), cyano (CN), isocyanato (NC), isothiocyanato (NCS), thiocyanato (SCN), amido (NH2), imdo (NH), sulfato (So₄), chloro (Cl), fluoro (F), phosphato (PO₄), and ethylenediaminetetraacetic acid (EDTA) ligands.

18. A method of inflating an air bag as defined in claim 1, wherein the complex includes a common counter ion in addition to the oxidizing anion.

19. A method of inflating an air bag as defined in claim 18, wherein the common counter ion is selected from the group consisting of hydroxide (OH⁻

), chloride (Cl⁻

), fluoride (F⁻

), cyanide (CN⁻

), thiocyanate (SCN⁻

), carbonate (CO₃<sup>−

2</sup>), sulfate (So₄<sup>−

2</sup>), phosphate (PO₄<sup>−

3</sup>), oxalate (C₂O₄<sup>−

2</sup>), borate (BO₄<sup>−

5</sup>), and ammonium (NH₄⁺) counter ions.

20. A method of inflating an air bag as defined in claim 1, wherein the complex and oxidizing anion combined have a concentration in the gas generating composition from 50% to 80% by weight, wherein the gas generating composition further comprises a binder and a co-oxidizer such that the binder has a concentration in the gas generating composition from 0.5% to 10% by weight and the co-oxidizer has a concentration in the gas generating composition from 5% to 50% by weight.

21. A method of inflating an air bag as defined in claim 1, wherein the gas generating composition which is combusted further comprising a co-oxidizer.

22. A method of inflating an air bag as defined in claim 21, wherein the co-oxidizer is selected from alkali, alkaline earth, or ammonium perchlorates, chlorates, peroxides, and nitrates.

23. A method of inflating an air bag as defined in claim 21, wherein the co-oxidizer is selected from metal oxides, metal hydroxides, metal peroxides, metal oxide hydrates, metal oxide hydroxides, metal hydrous oxides, basic metal carbonates, basic metal nitrates, and mixtures thereof.

24. A method of inflating an air bag as defined in claim 21, wherein the co-oxidizer is selected from oxides of copper, cobalt, manganese, tungsten, bismuth, molybdenum, and iron.

25. A method of inflating an air bag as defined in claim 21, wherein the co-oxidizer is a metal oxide selected from CuO, Co₂O₃,Co₃O₄, CoFe₂O₄, Fe₂O₃, MoO₃, Bi₂MoO₆, and Bi₂O₃ .

26. A method of inflating an air bag as defined in claim 21, wherein the co-oxidizer is a metal hydroxide selected from Fe(OH)₃, Co(OH)₃, Co(OH)₂, Ni(OH)₂, Cu(OH)₂, and Zn(OH)₂ .

27. A method of inflating an air bag as defined in claim 21, wherein the co-oxidizer is a metal oxide hydrate or metal hydrous oxide selected from Fe₂O₃.xH₂O, SnO₂.xH₂O, and MoO₃.H₂O.

28. A method of inflating an air bag as defined in claim 21, wherein the co-oxidizer is a metal oxide hydroxide selected from CoO(OH)₂, FeO(OH)₂, MnO(OH)₂, and MnO(OH)₃.

29. A method of inflating an air bag as defined in claim 21, wherein the co-oxidizer is a basic metal carbonate selected from CuCO₃.Cu(OH)₂ (malachite), 2Co(CO₃).3Co(OH)₂.H₂O, Co_0.69Fe_0.34(CO₃)_0.2(OH)₂, Na₃[Co(CO₃)₃].3H₂O, Zn₂(CO₃) (OH)₂, Bi₂Mg(CO₃)₂(OH)₄, Fe(CO₃)_0.12(OH)_2.76, Cu_1.54Zn_0.46(CO₃) (OH)₂, Co_0.49Cu_0.51(CO₃)_0.43(OH)_1.1, Ti₃Bi₄(CO₃)₂(OH)₂O₉(H₂O)₂, and (BiO)₂CO₃.

30. A method of inflating an air bag as defined in claim 21, wherein the co-oxidizer is a basic metal nitrate selected from Cu₂(OH)₃NO₃, Co₂(OH)₃NO₃, CuCo(OH)₃NO₃, Zn₂(OH)₃NO₃, Mn(OH)₂NO₃, Fe₄(OH)₁₁NO₃.2H₂O, Mo(NO₃)₂O₂, BiONO₃.H₂O, and Ce(OH) (NO₃)₃.3H₂O.

31. A method of inflating an air bag as defined in claim 1, wherein the gas generating composition which is combusted further comprising a binder.

32. A method of inflating an air bag as defined in claim 31, wherein the binder is water soluble.

33. A method of inflating an air bag as defined in claim 32, wherein the binder is selected from naturally occurring gums, polyacrylic acids, and polyacrylamides.

34. A method of inflating an air bag as defined in claim 31, wherein the binder is not water soluble.

35. A method of inflating an air bag as defined in claim 34, wherein the binder is selected from nitrocellulose, VAAR, and nylon.

36. A method of inflating an air bag as defined in claim 1, wherein the complex is hexaamminecobalt(III) nitrate, ([(NH₃)₆Co](NO₃)₃) and the co-oxidizer is copper(II) trihydroxy nitrate (Cu₂(OH)₃NO₃).

37. A method of inflating an air bag as defined in claim 1, further comprising carbon powder present from 0.1% to 6% by weight of the gas generating composition, wherein the composition exhibits improved crush strength compared to the composition without carbon powder.

38. A method of inflating an air bag as defined in claim 1, further comprising carbon powder present from 0.3% to 3% by weight of the gas generating composition.