Electrochemical display and timing mechanism with migrating electrolyte

• US 6,243,192 B1
• Filed: 07/26/1999
• Issued: 06/05/2001
• Est. Priority Date: 04/28/1997
• Status: Expired due to Fees

• Current Assignee: Wisconsin Label Corporation (Multi-Color Corporation)
• Original Assignee: Timer Technologies, LLC
• Inventors: Parker, Robert, Mitchell, Chauncey T. Jr., Verschuur, Gerrit L., Shadle, Mark A., Good, David M.
• Primary Examiner(s): Epps, Georgia
• Assistant Examiner(s): Lester, Evelyn A.
• Application Number:
  US09/360,670
• Time in Patent Office: 680 Days
• Field of Search: 359/265, 359/270, 359/272, 359/274, 429/93, 429/116, 429/8, 429/90, 324/435, 324/426, 324/437, 324/104, 296/231
• US Class Current: 359/270
• CPC Class Codes: G02F 1/0018 Electro-optical materials
• CPC Class Codes: G02F 1/1506 caused by electrodeposition, e.g. electrolytic deposition of an inorganic material on or close to an electrode
• CPC Class Codes: G02F 1/1508 using a solid electrolyte
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G04F 1/00 Apparatus which can be set and started to measure-off predetermined or adjustably-fixed time intervals without driving mechanisms, e.g. egg timers
• CPC Class Codes: G09F 7/00 Signs, name or number plates, letters, numerals, or symbols vehicle registration number plates B60R13/10; Panels or boards show-cards G09F1/00; indicating arrangements for variable information G09F9/00, G09F11/00; illuminated signs G09F13/00; boards for notices or posters G09F15/00
• CPC Class Codes: G09F 9/00 Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the variable information is permanently attached to a movable support G09F11/00; abacus G06C1/00; slide-rules G06G1/00
• CPC Class Codes: H01M 6/38 by mechanical means
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries
• CPC Class Codes: H01M 6/5044 Cells or batteries structurally combined with cell condition indicating means

Abstract

Printed electrochemical display cells are arranged in layer form with two electrode layers and an electrolyte layer occupying distinct areas of a substrate. When activated, an electrochemical reaction progressively increases the area occupied by the electrolyte layer and progressively decreases the area occupied by the thin-film electrode layer. The thin-film electrode layer recedes at a boundary in common with the electrolyte layer and provides an irreversible indication of change at a rate governed by the electrochemical reaction.

Claims

1. An irreversible electrochemical display comprising:

first and second electrodes interconnected by an electronically conductive pathway;

an image obscured by the second electrode;

electrolyte confined within an area out of contact with the second electrode; and

a guided pathway through which the electrolyte can be moved into contact with a limited portion of the second electrode for completing an ionically conductive pathway between the first and second electrodes, in which

the second electrode is progressively erodable along a common boundary with the electrolyte for revealing the image obscured by the second electrode.

2. The display of claim 1 in which the electrolyte is also confined within the area out of contact with the first electrode.

3. The display of claim 2 in which the guided pathway directs the electrolyte into contact with both the first and second electrodes.

4. The display of claim 1 in which the electrolyte is confined within the area in contact with the first electrode.

5. The display of claim 1 in which the electronically conductive pathway is formed by contact between the first and second electrodes.

6. The display of claim 1 in which the first and second electrodes overlap.

7. The display of claim 6 in which the overlap between electrodes completes a conductive pathway between the electrodes.

8. The display of claim 7 in which the first electrode overlaps the second electrode within an overlap area that extends beyond the common moving boundary with the electrolyte.

9. The display of claim 8 in which the overlap area extends in a direction approximately parallel to a direction of movement of the common boundary with the electrolyte to preserve the conductive pathway between the electrodes despite the progressive erosion of the second electrode.

10. The display of claim 1 in which the first and second electrodes extend in a common direction approximately parallel to a direction of movement of the common boundary with the electrolyte.

11. The display of claim 1 further comprising a barrier layer that separates the electrolyte from the second electrode.

12. The display of claim 11 in which the electrolyte layer overlaps the second electrode layer within the confined area that is out of contact with the second electrode.

13. The display of claim 1 in which the guided pathway penetrates the barrier layer to move the electrolyte into contact with the limited portion of the second electrode.

14. The display of claim 1 in which the electrolyte is a gelatinous material that is flowable through the guided pathway.

15. The display of claim 1 in which the first electrode is a cathode having a first electrode potential and the second electrode is an anode having a second different electrode potential.

16. The display of claim 15 in which the anode has a thickness less than one micron.

17. An irreversible electrochemical display comprising:

first and second electrodes interconnectable by both ionically and electronically conductive pathways for supporting an electrochemical reaction that consumes the second electrode;

the ionically conductive pathway including a flowable electrolyte that is initially maintained out of operative contact with an elongated portion of the second electrode;

the elongated portion of the second electrode defining a path of migration for the flowable electrolyte;

the first electrode also extending along the path of migration; and

one of the conductive pathways being interruptable for controlling the start of the electrochemical reaction that progressively consumes the second electrode at a common boundary with the flowable electrolyte and produces an irreversible indication of change in the display.

18. The display of claim 17 in which the first electrode straddles the path of migration along the second electrode.

19. The display of claim 17 in which the first electrode overlaps the elongated portion of the second electrode in a direction approximately parallel to the path of migration.

20. The display of claim 19 in which substantially all of the second electrode overlaps the first electrode.

21. The display of claim 19 in which the electronically conductive pathway is completed between overlapping portions of the first and second electrodes that extend approximately parallel to the path of migration.

22. The display of claim 17 in which the flowable electrolyte overlaps the elongated portion of the second electrode.

23. The display of claim 22 in which a barrier layer isolates the flowable electrolyte from the elongated portion of the second electrode.

24. The display of claim 17 in which the second electrode has a thickness less than one micron.

25. The display of claim 17 in which the first and second electrodes have different electrode potentials.

26. The display of claim 25 in which completion of the conductive pathways supports a spontaneous electrochemical reaction between the electrodes.

27. The display of claim 17 in which the flowable electrolyte exhibits a surface tension that confines the electrolyte along the common boundary with the second electrode.

28. The display of claim 17 in which the first electrode includes discontinuous portions along the path of migration.

29. The display of claim 28 in which the discontinuous portions of the first electrode are connected by separate electronically conductive pathways to the second electrode.

30. The display of claim 17 in which the flowable electrolyte is temporarily confined within an area out of contact with the second electrode.

31. The display of claim 30 further comprising a guided pathway through which the flowable electrolyte can be moved into contact with a limited portion of the elongated portion of the second electrode.

32. The display of claim 17 further comprising an image obscured by the elongated portion of the second electrode.

33. The display of claim 32 in which the electrochemical reaction progressively reveals the underlying image obscured by the elongated portion of the second electrode along the path of migration.

34. An irreversible electrochemical display comprising:

two electrodes having different electrode potentials and a flowable electrolyte supported between two substrates;

a first of the substrates including a transparent window for viewing a second of the two electrodes;

a guided pathway between the two substrates for directing the flowable electrolyte along a path of migration that includes the second substrate; and

the flowable electrolyte being engageable with the second electrode along a common boundary that progressively advances along the guided pathway for producing a change viewable through the transparent window.

35. The display of claim 34 in which the flowable electrolyte is confined within an area out of contact with at least a portion of the second electrode that extends along the path of migration.

36. The display of claim 35 in which the flowable electrolyte contacts the first electrode within the confined area.

37. The display of claim 35 in which the flowable electrolyte is confined out of contact with both electrodes within the confined area.

38. The display of claim 35 in which a pocket is formed between the two substrates for confining the flowable electrolyte.

39. The display of claim 38 in which the pocket is compressible for moving the flowable electrolyte out of the pocket along the guided pathway.

40. The display of claim 34 in which the guided pathway directs the flowable electrolyte to complete an ionically conductive pathway between the first and second electrodes.

41. The display of claim 40 in which the flowable electrolyte overlaps the second electrode.

42. The display of claim 41 in which a barrier separates the flowable electrolyte from the overlapped portion of the second electrode.

43. The display of claim 34 in which an electronically conductive pathway is formed by overlapping electronic contact between the first and second electrodes.

44. The display of claim 43 in which the first electrode extends along the path of migration for completing the electronically conductive pathway between electrodes beyond the advancing boundary between the flowable electrolyte and the second electrode.

45. The display of claim 44 in which the first electrode straddles the path of migration along the second electrode.

46. The display of claim 44 in which substantially all of the first electrode overlaps the second electrode.

47. The display of claim 34 in which the guided pathway includes two smooth surfaces between which the second electrode is confined.

48. The display of claim 34 in which the flowable electrolyte is transparent.

49. A method of producing an irreversible change in an electrochemical display comprising:

electronically interconnecting first and second electrodes having different electrode potentials;

temporarily confining a flowable electrolyte out of contact with an elongated portion of the second electrode;

initiating an electrochemical reaction that progressively erodes the elongated portion of the second electrode at a common boundary with the flowable electrolyte without correspondingly adding to an area occupied by the first electrode; and

revealing an image behind the advancing common boundary of the flowable electrolyte and the second electrode.

50. The method of claim 49 including a further step of extending the flowable electrolyte from a position out of contact with the second electrode into a position in contact with the second electrode for completing an ionically conductive pathway between the first and second electrodes.

51. The method of claim 49 including a further step of extending the flowable electrolyte from a position in contact with only the first electrode of the first and second electrodes to a position in contact with both the first and second electrodes for completing an ionically conductive pathway between the first and second electrodes.

52. The method of claim 49 including a further step of extending the flowable electrolyte from a position out of contact with both the first and second electrodes into a position in contact with both the first and second electrodes for completing an ionically conductive pathway between the first and second electrodes.

53. The method of claim 50 in which the step of extending includes directing the flowable electrolyte along a guided pathway that includes the elongated portion of the second electrode.

54. The method of claim 49 in which the step of temporarily confining includes confining the flowable electrolyte in a pocket formed between two substrates.

55. The method of claim 54 including a further step of squeezing the flowable electrolyte out of the pocket into contact with the elongated portion of the second electrode.

56. The method of claim 49 in which the step of electronically interconnecting includes overlapping the first and second electrodes along the extended portion of the second electrode.

57. The method of claim 49 including a further step of orienting the first and second electrodes in a common direction along the elongated portion of the second electrode.