Selective adsorption process for resid upgrading (law815)

• US 6,245,223 B1
• Filed: 05/09/2000
• Issued: 06/12/2001
• Est. Priority Date: 12/16/1997
• Status: Expired due to Fees

• Current Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Inventors: Soled, Stuart L., Olmstead, William N., Robbins, Winston K., Miseo, Sabato, Ferrughelli, David T., Gorbaty, Martin L.
• Primary Examiner(s): GRIFFIN, WALTER DEAN
• Application Number:
  US09/568,865
• Time in Patent Office: 399 Days
• Field of Search: 208/251.R, 208/253, 208/299, 208/305, 208/307, 585/820, 585/823, 585/826
• US Class Current: 208/251.00R
• CPC Class Codes: C10G 25/00 Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
• CPC Class Codes: C10G 25/003 Specific sorbent material, not covered by C10G25/02 or C10G25/03

Abstract

The present invention is a process to remove a major portion of metals and coke precursors from a hydrocarbon stream. The steps of the process include contacting the feedstream with a hydrocarbon insoluble adsorbent, recovering the oil which does not adsorb and removing the metals and coke precursors from the adsorbent.

Claims

1. A process to remove a major portion of metal-containing molecules and coke precursor molecules from a hydrocarbon feedstream including an atmospheric residuum, vacuum residuum, or a deasphalted oil from a solvent deasphalter, in the substantial absence of an added aromatic or cyclic non-aromatic solvent, comprising:

(a) contacting said hydrocarbon feedstream with a hydrocarbon insoluble adsorbent characterized by a surface area greater than 100m²/g for a time and temperature sufficient to adsorb a major portion of said metal containing molecules and coke precursor molecules onto said adsorbent,

(b) recovering the oil which does not adsorb and

(c) removing the metal containing molecules and coke precursor molecules from said adsorbent.

2. The process of claim 1 wherein said removing step is carried out by contacting said adsorbent with a solvent capable of dissolving polar hydrocarbons.

3. The process of claim 1 wherein said adsorbent is selected from the group consisting of silica, silica-alumina, acid treated clays and activated carbons.

4. The process of claim 1 wherein the hydrocarbon feedstream is an atmospheric residuum having a boiling point greater than 300°

C.

5. The process of claim 1 wherein said hydrocarbon feedstream is a vacuum residuum having a boiling point of 500°

C. or greater at atmospheric pressure.

6. The process of claim 1 wherein said hydrocarbon feedstream is effluent from a solvent deasphalter which includes a propane solvent.

7. The process of claim 1 wherein said hydrocarbon feedstream is effluent from a solvent deasphalter which includes a butane solvent.

8. The process of claim 1 wherein said hydrocarbon feedstream is effluent from a solvent deasphalter which includes a pentane solvent.

9. The process of claim 1 wherein said removing step is carried out by contacting said adsorbent with heat.

10. The process of claim 1 wherein said feedstream and said adsorbent are present in a ratio between 0.1 and 10 wt/wt.

11. The process of claim 1 wherein said feedstream is fed through a fixed bed of adsorbent.

12. The process of claim 11 further comprising the step of terminating the feeding of the feedstream and regenerating said adsorbent by passing a solvent through said adsorber.

13. The process of claim 1 wherein said feedstream is a residuum and said temperature is greater than 150°

C.

14. The process of claim 1 wherein said feedstream is a residuum and said temperature is between 200 and 225°

C.

15. The process of claim I wherein said feedstream is a deasphalted oil from a solvent deasphalter and said temperature is between 140 and 160°

C.