Antibiotic high-pressure laminates

• US 6,248,342 B1
• Filed: 09/29/1998
• Issued: 06/19/2001
• Est. Priority Date: 09/29/1998
• Status: Expired due to Fees

• Current Assignee: Sciessent, LLC
• Original Assignee: AgION Technologies, LLC
• Inventors: Trogolo, Jeffrey A., Barry, John E.
• Primary Examiner(s): Dodson, Shelley A.
• Application Number:
  US09/163,039
• Time in Patent Office: 994 Days
• Field of Search: 424/79, 424/400, 424/402, 424/404, 424/443, 424/409, 424/489, 424/412, 424/413, 424/421, 424/405, 427/396.2, 428/411.1, 428/457, 428/488, 428/480, 428/481
• US Class Current: 424/404
• CPC Class Codes: B32B 2260/028 Paper layer
• CPC Class Codes: B32B 2307/7145 Rot proof, resistant to bacteria, mildew, mould, fungi
• CPC Class Codes: B32B 2311/08 Silver
• CPC Class Codes: B32B 2607/00 Walls, panels
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 29/06 specially treated, e.g. surfaced, parchmentised
• CPC Class Codes: B44C 5/0476 with abrasion resistant properties
• CPC Class Codes: D21H 21/36 Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
• CPC Class Codes: D21H 27/26 characterised by the overlay sheet or the top layers of the structures decorative panels B44C5/04; wood grain effects B44F9/02
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/3179 Next to cellulosic

Abstract

This invention provides an antimicrobial high-pressure laminate which contains an inorganic antibiotic metal containing composition incorporated in an antimicrobially effective amount in its surface layer, which is preferably formed of melamine. The laminate can be bonded to appropriate substrates to form antimicrobial table tops, cabinets, wall paneling, and counter tops.

Claims

1. An antimicrobial high-pressure laminate, comprising:

(a) multiple layers of paper or cloth saturated with a resin component comprising a melamine resin; and

(b) an inorganic antibiotic metal ion component distributed in a surface of the resin component such that the inorganic antibiotic metal ion is exteriorly available in an antimicrobially effective amount.

2. The antimicrobial high-pressure laminate of claim 1 wherein the inorganic antibiotic metal ion component comprises a silver salt component.

3. The antimicrobial high-pressure laminate of claim 2 wherein the silver salt component comprises a silver salt selected from the group consisting of silver acetate, silver benzoate, silver carbonate, silver iodate, silver iodide, silver lactate, silver laurate, silver nitrate, silver oxide, silver palmitate, and silver sulfadiazine.

4. The antimicrobial high-pressure laminate of claim 2 wherein the silver salt component comprises silver nitrate.

5. The antimicrobial high-pressure laminate of claim 2 wherein the laminate has a thickness of at least 0.01 mm.

6. The antimicrobial high-pressure laminate of claim 1 wherein the melamine resin does not incorporate a chlorohexidine component.

25. A counter top coated with the antimicrobial high-pressure laminate of claim 1.

26. A table having a top surface thereof coated with the antimicrobial high-pressure laminate of claim 1.

27. A cabinet having a surface thereof coated with the antimicrobial high-pressure laminate of claim 1.

28. Wall paneling having a surface thereof coated with with the antimicrobial high-pressure laminate of claim 1.

7. An antimicrobial high-pressure laminate having a thickness of at least 0.1 mm, comprising:

(a) multiple layers of paper or cloth saturated with a resin component; and

(b) inorganic ceramic particles with antibiotic metal cations ion-exchanged thereon, wherein the particles are distributed in a surface of the laminate, such that an ion-exchange reaction in the ceramic particles releases antibiotic metal cations, which can migrate out of the ceramic particles to become exteriorly available in an antimicrobially effective amount.

10. The antimicrobial high-pressure laminate of claim 7 having a thickness of at least 0.8 mm.

11. The antimicrobial high-pressure laminate of claim 7 wherein the particles are evenly distributed.

12. The antimicrobial high-pressure laminate of claim 7 wherein the ceramic particles are bonded to a surface layer of the laminate.

13. The antimicrobial high-pressure laminate of claim 7 wherein the resin comprises a layer of melamine.

14. The antimicrobial high-pressure laminate of claim 7 wherein the resin comprises a layer of polyurethane.

15. The antimicrobial high-pressure laminate of claim 7 wherein the ceramic particles comprises silver ions ion-exchanged thereon as an antibiotic metal cation.

16. The antimicrobial high-pressure laminate of claim 7 wherein the ceramic particles comprise ion-exchanged hydroxyapatite or zirconium phosphate.

17. The antimicrobial high-pressure laminate of claim 7 wherein the ceramic particles comprise ion-exchanged zeolite.

18. The antimicrobial high-pressure laminate of claim 7 wherein the ceramic particles comprise aluminosilicate particles.

19. The antimicrobial high-pressure laminate of claim 18 wherein the aluminosilicate has a formula:

20. The antimicrobial high-pressure laminate of claim 19, wherein M is selected from the group consisting of silver, copper, zinc, mercury, tin, lead, bismuth, cadmium, chromium, and mixtures thereof.

21. The antimicrobial high-pressure laminate of claim 19, wherein M is silver.

22. The antimicrobial high-pressure laminated substrate of claim 7 further comprising a discoloration inhibitor.

23. The antimicrobial high-pressure laminated substrate of claim 22 wherein the discoloration inhibitor is inorganic.

24. The antimicrobial high-pressure laminated substrate of claim 23, wherein the discoloration inhibitor comprises one or more ammonium ions.

8. An antimicrobial high-pressure laminate having a thickness of at least 0.1 mm, comprising:

(a) multiple layers of paper or cloth saturated with a resin; and

(b) inorganic ceramic particles with antibiotic metal cations ion-exchanged thereon, wherein the particles are distributed in a surface of the laminate, such that some or all of the ceramic particles are exteriorly exposed to release antibiotic metal cations in an antimicrobially effective amount.

32. The antimicrobial high-pressure laminate of claim 8 wherein the ceramic particles comprise ion-exchanged hydroxyapatite or zirconium phosphate.

9. An antimicrobial high-pressure laminate:

(a) having a thickness of at least 0.1 mm;

(b) comprising a multiple layers of paper or cloth saturated with one or more resins and pressed together to form the laminate;

(c) comprising inorganic ceramic particles;

(i) with antibiotic metal cations ion-exchanged thereon;

(ii) distributed in or on a surface layer of the high pressure laminate;

(iii) retaining a matrix structure that permits, in the presence of water and cations, an ion exchange reaction to release antibiotic metal cations from the laminate in an antimicrobially effective amount.

33. The antimicrobial high-pressure laminate of claim 9 wherein the ceramic particles comprise ion-exchanged hydroxyapatite or zirconium phosphate.

29. An antimicrobial high-pressure laminate formed by a process comprising:

(a) providing a multi-layered substrate saturated with one or more resins;

(b) applying a solvent to a surface of the laminate to soften the one or more resins; and

(c) pressing inorganic antibiotic particles ceramic particles having silver ion exchanged thereon into the surface such that the silver is available in an antimicrobially effective amount.

30. An antimicrobial high-pressure laminate formed by a process comprising:

(a) predispersing in a water-based slurry inorganic antibiotic ceramic particles having an antibiotic metal ion exchanged thereon;

(b) mixing the water-based slurry into a resin to provide an even distribution of the ceramic particles in the resin; and

(c) applying the mixture of (b) to a substrate to provide a surface such that the metal ion is available in an antimicrobially effective amount.

31. An antimicrobial high-pressure laminate having a thickness of at least 0.1 mm and comprising:

(a) a laminate substrate;

(b) a resin saturating the laminate substrate, and

(c) zeolite particles comprising an antibiotic metal cation ion-exchanged thereon, said particles retaining a matrix structure that permits, in the presence of water and cations, an ion exchange reaction to release antibiotic metal cations from the laminate in an antimicrobially effective amount.