Composite bipolar plate for electrochemical cells

• US 6,248,467 B1
• Filed: 07/23/1999
• Issued: 06/19/2001
• Est. Priority Date: 10/23/1998
• Status: Expired due to Term

• Current Assignee: TRIAD National Security, LLC
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Busick, Deanna N., Wilson, Mahlon S.
• Primary Examiner(s): WEINER, LAURA S
• Application Number:
  US09/359,829
• Time in Patent Office: 697 Days
• Field of Search: 429/34, 429/35, 429/36, 429/40, 429/41, 429/46, 429/210, 429/39, 429/38
• US Class Current: 429/514
• CPC Class Codes: C25B 9/65 Means for supplying current; Electrode connections; Electric inter-cell connections
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 4/665 Composites
• CPC Class Codes: H01M 4/668 Composites of electroconductive material and synthetic resins
• CPC Class Codes: H01M 6/48 with bipolar electrodes
• CPC Class Codes: H01M 8/0213 Gas-impermeable carbon-containing materials
• CPC Class Codes: H01M 8/0221 Organic resins; Organic polymers
• CPC Class Codes: H01M 8/0226 in the form of mixtures
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A bipolar separator plate for fuel cells consists of a molded mixture of a vinyl ester resin and graphite powder. The plate serves as a current collector and may contain fluid flow fields for the distribution of reactant gases. The material is inexpensive, electrically conductive, lightweight, strong, corrosion resistant, easily mass produced, and relatively impermeable to hydrogen gas. The addition of certain fiber reinforcements and other additives can improve the properties of the composite material without significantly increasing its overall cost.

Claims

1. A bipolar plate having flow channels on faces of the plate for use in an electrochemical cell comprising an electrically conductive plate molded from a thermosetting vinyl ester resin matrix having a conductive powder embedded therein in an amount effective to provide a electrical conductivity of at least about 10 S/cm for said bipolar plate and having the flow channels formed in the thermosetting vinyl ester resin matrix.

2. A bipolar plate according to claim 1, wherein said electrically conductive plate further includes short (<

1 mm) reinforcement fibers selected from the group consisting of graphite/carbon, glass, cotton, and polymer.

3. A bipolar plate according to claim 2, wherein said conductive powder is graphite with particle sizes predominantly in the range of 80 to 325 mesh.

4. A bipolar plate according to claim 1, wherein said conductive powder is graphite with particle sizes predominantly in the range of 80 to 325 mesh.

5. A bipolar plate according to claim 1, further including fluorochemical intermediates forming perfluoroalkyl groups on surfaces of said electrically conductive plate.

6. A bipolar plate for use in an electrochemical cell comprising an electrically conductive plate molded from a vinyl ester resin binder having graphite powder and short cotton fibers embedded therein.

7. A bipolar plate according to claims 6, wherein said graphite powder has particle sizes predominantly in the range of 80 to 325 mesh.

8. A bipolar plate according to claim 6, further including fluorochemical intermediates forming perfluoroalkyl groups on surfaces of said electrically conductive plate.

9. A material composition for electrochemical cell bipolar plates comprising:

a vinyl ester resin;

a surface modifying agent of a fluorochemical intermediate effective to provide for mold release and for surface hydrophobicity; and

graphite powder having particle sizes predominantly between 80 and 325 mesh in the range 20 to 95% by weight.

10. A material composition according to claim 9 further including a quantity of carbon black in the range of 0 to 5% by weight.

11. A material composition according to claim 9 where the surface modifying agent is a fluorochemical intermediate selected from the group consisting of fluoroalkylacrylates and fluoroalkylolefins.

12. A material composition according to claim 9 further including cotton fibers having a length less than about 1 mm.

13. A bipolar plate for use in an electrochemical cell consisting essentially of an electrically conductive plate molded from a thermosetting vinyl ester resin matrix;

a conductive powder; and

reinforcement fibers selected from the group consisting of graphite/carbon, glass, cotton, and polymer.

14. A bipolar plate according to claim 13, wherein said conductive powder is graphite with particle sizes predominantly in the range of 80 to 325 mesh.