Golf ball compositions and method of making same

• US 6,255,361 B1
• Filed: 08/10/1998
• Issued: 07/03/2001
• Est. Priority Date: 11/21/1995
• Status: Expired due to Fees

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Rajagopalan, Murali, Harris, Kevin M.
• Primary Examiner(s): Buttner, David J.
• Application Number:
  US09/132,193
• Time in Patent Office: 1,058 Days
• Field of Search: 524/320, 473/354, 473/355, 473/357, 473/365, 473/372, 473/373, 473/374, 473/377, 473/378, 473/385, 521/97
• US Class Current: 521/97
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0039 characterised by the material
• CPC Class Codes: A63B 37/0052 Liquid cores
• CPC Class Codes: A63B 37/0056 Hollow; Gas-filled
• CPC Class Codes: A63B 37/0075 Three piece balls, i.e. cover, intermediate layer and core
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 45/00 Apparatus or methods for manufacturing balls working of plastics or substances in a plastic state B29
• CPC Class Codes: C08F 210/00 Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 210/02 Ethene
• CPC Class Codes: C08F 8/44 Preparation of metal salts or ammonium salts
• CPC Class Codes: C08K 5/09 Carboxylic acids; Metal salts thereof; Anhydrides thereof

Abstract

The present invention is directed to a golf ball and to a process for forming a golf ball having at least one layer, where the layer is formed of a saponified polymer/oxa acid blend, having from about 65 to about 99 parts of at least one saponified polymer and from about 35 to 1 parts of at least one oxa acid, based on 100 parts by weight of the saponified polymer/oxa acid blend. The layer may be foamed or unfoamed, and may form at least a portion of any of the cover, the core, or a mantle layer situated between the cover and the core.

Claims

1. A golf ball having at least one layer formed of a saponified polymer/oxa acid blend comprising from about 65 to about 99 parts of at least one saponified polymer and from about 35 to 1 parts of at least one oxa acid, based on 100 parts by weight of the saponified polymer/oxa acid blend, wherein the at least one layer has a foamed structure.

2. The golf ball according to claim 1, comprising a cover, wherein the layer forms at least a portion of the cover.

3. The golf ball according to claim 1, comprising a core, wherein the layer forms at least a portion of the core.

4. The golf ball according to claim 3, wherein the core is selected from the group consisting of wound cores, solid cores, hollow cores, cores filled with a fluid, and cores filled with a gel.

5. The golf ball according to claim 1, further comprising a cover and a core and a mantle situated between the cover and the core.

6. The golf ball according to claim 5, wherein the core is a wound core.

7. The golf ball according to claim 6, wherein the layer forms at least a portion of the mantle.

8. The golf ball according to claim 1, wherein the oxa acid is a monoacid of the formula:

wherein n is an integer greater than or equal to 1, and R is H or an organic moiety selected from the group consisting of linear and branch chained alkyl, substituted and unsubstituted carbocyclic, and heterocyclic groups.

9. The golf ball according to claim 1, wherein the oxa acid is a diacid of the formula:

wherein n is an integer greater than or equal to 1.

10. The golf ball according to claim 1, wherein the saponified polymer comprises a first olefinic, monomeric component having from 2 to 8 carbon atoms and a second monomeric component comprising an unsaturated carboxylic acid based acrylate class ester having from 4 to 22 carbon atoms and at least one ester group, wherein at least a portion of the ester groups have been saponified with an inorganic metal base.

11. The golf ball according to claim 10, wherein the metal base comprises at least one metallic cation, selected from the group consisting of lithium, sodium, potassium, cesium, magnesium, calcium, barium, manganese, copper, zinc, titanium, tungsten, zirconium, and aluminum, and at least one anion, selected from the group consisting of hydroxide, alkoxide, acetate, carbonate, bicarbonate, oxide, formate, and nitrate.

12. The golf ball according to claim 10, wherein the first monomeric component comprises an α

-olefin monomer having a terminal point of unsaturation.

13. The golf ball according to claim 12, wherein the first monomeric component has the formula:

wherein;

R₁ is hydrogen or an alkyl group; and

R₂ is hydrogen, lower alkyl including C₁-C₅, carbocyclic, aromatic or heterocyclic.

14. The golf ball according to claim 13, wherein the first monomeric component is ethylene.

15. The golf ball according to claim 10, wherein the first monomeric component comprises from about 1 to about 99 percent by weight of the total polymer weight.

16. The golf ball according to claim 10, wherein the first monomeric component comprises from about 10 to about 95 percent by weight of the total polymer weight.

17. The golf ball according to claim 10, wherein the first monomeric component comprises from about 10 to about 70 percent by weight of the total polymer weight.

18. The golf ball according to claim 9, wherein the second monomeric component is an unsaturated acrylate class ester having the formula:

wherein;

R₃ is hydrogen or an alkyl group;

R₄ is hydrogen, lower alkyl including C₁-C₅, carbocyclic, aromatic or heterocyclic;

R₅ is selected from the group consisting of C_nH_2n+1, for n=1 to 18 and phenyl, in which from 0 to 5 H within R₄ can be replaced by substituents selected from the group consisting of COOH, SO₃H, NH₂, succinic anhydride and their salts, F, Cl, Br, I, OH, SH, epoxy, silicone, lower alkyl esters, lower alkyl ethers, and aromatic or heterocyclic rings with the proviso that R₄ and R₅ can be combined to form a bicyclic ring.

19. The golf ball according to claim 18, wherein the second monomeric component comprises from about 99 to about 1 percent by weight of the total polymer weight.

20. The golf ball according to claim 18, wherein the second monomeric component comprises from about 90 to about 5 percent by weight of the total polymer weight.

21. The golf ball according to claim 18, wherein the second monomeric component comprises from about 90 to about 30 percent by weight of the total polymer weight.

22. The golf ball according to claim 9, further comprising a third monomeric component selected from the group consisting of carbon monoxide, sulfur dioxide, an anhydride monomer, an unsaturated monocarboxylic acid, an olefin having from 2 to 8 carbon atoms and a vinyl ester or a vinyl ether of an alkyl acid having from 4 to 21 carbon atoms.

23. The golf ball according to claim 22, wherein the third monomeric component is at least one of the monomers selected from the group consisting of:

wherein;

R₆ is hydrogen, lower alkyl including C₁-C₅, carbocyclic, aromatic or heterocyclic;

R₇ is hydrogen, lower alkyl including C₁-C₅, carbocyclic, aromatic or heterocyclic;

R₈ is hydrogen, lower alkyl including C₁-C₅, carbocyclic, aromatic or heterocyclic;

R₉ is hydrogen or lower alkyl including C₁-C₅;

R₁₀ is hydrogen, or is selected from the group consisting of C_nH_2n+1, for n=1 to 18 and phenyl, in which from 0 to 5 H within R₁₀ can be replaced by substituents selected from the group consisting of COOH, SO₃H, NH₂ and their salts, F, Cl, Br, I, OH, SH, silicon, lower alkyl esters, lower alkyl ethers and aromatic or heterocyclic rings with the proviso that R₉ and R₁₀ can be combined to form a bicyclic ring;

R₁₁ is hydrogen, lower alkyl including C₁-C₅, carbocyclic, aromatic or heterocyclic;

R₁₂ is hydrogen or lower alkyl including C₁-C₅,

R₁₃ is hydrogen, or is selected from the group consisting of C_nH_2n+1, for n=1 to 18 and phenyl, in which from 0 to 5 H within R₁₃ can be replaced by substituents selected from the group consisting of COOH, SO₃H, NH₂ and their salts, F, Cl, Br, I, OH, SH, silicon, lower alkyl esters, lower alkyl ethers and aromatic or heterocyclic rings with the proviso that R₁₂ and R₁₃ can be combined to form a bicyclic ring.

24. The golf ball according to claim 22, wherein the third monomeric component comprises up to about 49 percent by weight of the total polymer weight.

25. The golf ball according to claim 10, wherein the monomeric components of the polymer are present in a random, alternating, block or graft arrangement.

26. The golf ball according to claim 10, wherein the polymer is of a form selected from the group consisting of isotactic, syndiotactic, and atactic polymers and combinations thereof.

27. The golf ball according to claim 1, wherein a grafting agent has been added to the saponified polymer to form a grafted polymer.

28. The golf ball according to claim 27, wherein the grafting agent comprises an anhydride having the formula:

wherein;

R₁₄ and R₁₅ are the same or different and are selected from the group consisting of hydrogen, linear or branched chain alkyl and substituted or unsubstituted carboxylic groups.

29. The golf ball according to claim 27, wherein the grafting agent is added in an amount of between about 1-50 percent by weight of the polymer.

30. The golf ball according to claim 27, wherein the grafting agent is added in an amount of between about 1-25 percent by weight of the polymer.

31. The golf ball according to claim 27, wherein the grafting agent is added in an amount of between about 1-15 percent by weight of the polymer.

32. A golf ball comprising a cover and a core and a mantle situated between the cover and the core, wherein at least one of the core and the mantle comprises at least one layer formed of a saponified polymer/oxa acid blend comprising from about 65 to about 99 parts of at least one saponified polymer and from about 35 to 1 parts of at least one oxa acid, based on 100 parts of the saponified polymer/oxa acid blend.

33. The golf ball according to claim 32, wherein the core is selected from the group consisting of wound cores, solid cores, hollow cores, cores filled with a fluid, and cores filled with a gel.

34. The golf ball according to claim 33, wherein the saponified polymer comprises a first olefinic, monomeric component having from 2 to 8 carbon atoms and a second monomeric component comprising an unsaturated carboxylic acid based acrylate class ester having from 4 to 22 carbon atoms and at least one ester group, wherein at least a portion of the ester groups have been saponified with an inorganic metal base.

35. The golf ball according to claim 32, wherein the oxa acids is a monoacid of the formula:

wherein n is an integer greater than or equal to 1, and R is H or an organic moiety selected from the group consisting of linear and branch chained alkyl, substituted and unsubstituted carbocyclic, and heterocyclic groups.

36. The golf ball according to claim 32, wherein the oxa acid is a diacid of the formula:

wherein n is an integer greater than or equal to 1.

37. The golf ball according to claim 32, wherein each layer further comprises at least one polymeric composition selected from the group consisting of grafted metallocene catalyzed polymers, grafted metallocene catalyzed polymer blends, non-grafted metallocene catalyzed polymers, non-grafted metallocene catalyzed polymer blends, balata, and ionomers.

39. The process according to claim 37, further comprising:

forming a polymer comprising a first olefinic monomeric component having from 2 to 8 carbon atoms and a second monomeric component comprising an unsaturated carboxylic acid based acrylate class ester having from 4 to 22 carbon atoms;

applying a sufficient amount of heat to the polymer to convert the polymer to a substantially molten state;

forming a mixture by adding an inorganic metal base to the molten polymer; and

saponifying the mixture to form a saponified polymer,

wherein a sufficient amount of the inorganic metal base is added to the molten polymer in forming the mixture to obtain a degree of saponification of the polymer ranging between about 1 and 50 percent.

41. The process according to claim 39, further comprising forming the polymer with a third monomeric component, selected from the group consisting of carbon monoxide, sulfur dioxide, an anhydride monomer, an unsaturated monocarboxylic acid, an olefin having from 2 to 8 carbon atoms, and a vinyl ester or a vinyl ether of an alkyl acid having from 4 to 21 carbon atoms.

38. A process for forming a golf ball, which golf ball comprises a cover, a core, and optionally a mantle situated between the cover and the core, which process comprises:

blending a saponified polymer with at least one oxa acid to form a saponified polymer/oxa acid blend; and

forming at least one layer of a golf ball core or mantle from the saponified polymer/oxa acid blend.

40. The process according to claim 38, further comprising forming the mixture of the inorganic metal base and the molten polymer at a temperature such that the mixture has a viscosity that remains substantially unchanged from that of the molten polymer.

42. A process for forming a golf ball, which comprises:

blending a saponified polymer with at least one oxa acid to form a saponified polymer/oxa acid blend; and

forming at least one layer of a golf ball from the saponified polymer/oxa acid blend, wherein the at least one layer has a foamed structure.

43. The process according to claim 42, further comprising:

forming a polymer comprising a first olefinic monomeric component having from 2 to 8 carbon atoms and a second monomeric component comprising an unsaturated carboxylic acid based acrylate class ester having from 4 to 22 carbon atoms;

applying a sufficient amount of heat to the polymer to convert the polymer to a substantially molten state;

forming a mixture by adding an inorganic metal base to the molten polymer; and

saponifying the mixture to form a saponified polymer,

wherein a sufficient amount of the inorganic metal base is added to the molten polymer in forming the mixture to obtain a degree of saponification of the polymer ranging between about 1 and 50 percent.

44. The process according to claim 43, further comprising forming the mixture of the inorganic metal base and the molten polymer at a temperature such that the mixture has a viscosity that remains substantially unchanged from that of the molten polymer.

45. The process according to claim 43, further comprising forming the polymer with a third monomeric component, selected from the group consisting of carbon monoxide, sulfur dioxide, an anhydride monomer, an unsaturated monocarboxylic acid, an olefin having from 2 to 8 carbon atoms, and a vinyl ester or a vinyl ether of an alkyl acid having from 4 to 21 carbon atoms.