Water based oil dispersant

• US 6,261,463 B1
• Filed: 03/04/1999
• Issued: 07/17/2001
• Est. Priority Date: 03/04/1999
• Status: Expired due to Term

• Current Assignee: US Polychemical Holding Corporation
• Original Assignee: Polychemical Corporation
• Inventors: Jacob, Savarimuthu M., Bergman, Robert E. Jr.
• Primary Examiner(s): Metzmaier, Daniel S.
• Application Number:
  US09/262,100
• Time in Patent Office: 866 Days
• Field of Search: 516/58, 516/65, 516/69, 210/749, 210/693, 210/925, 510/365, 510/506
• US Class Current: 210/749
• CPC Class Codes: C02F 1/682 by addition of chemical compounds for dispersing an oily layer on water
• CPC Class Codes: C09K 23/017 Mixtures of compounds
• CPC Class Codes: C09K 3/32 for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
• CPC Class Codes: Y10S 210/925 using chemical agent

Abstract

An effective and non-toxic oil spill dispersant combines a predominately oil-soluble surfactant (eg., polyethylene glycol mono-oleate) with a predominately water-soluble surfactant (eg., cocoamide) and a co-solvent for coupling a mixture of the predominately oil-soluble surfactant and the oil spill, with the predominately water-soluble surfactant. Water is included in the combination to help advance the interaction between the predominately oil-soluble surfactant and the predominately water-soluble surfactant as well as the co-solvent. The water component also helps reduce the viscosity of the dispersant to allow it to be pumped under pressure.

Claims

1. A method for dispersing a petrochemical spill on a body of water, comprising:

providing a dispersant which contains about 35 to about 85 percent by weight of an oil-soluble surfactant combination of a type and in a quantity to form a mixture with petrochemical for the spill, the oil-soluble surfactant combination comprising a plurality of oil-soluble surfactants which are each non-ionic and have a different hydrophilic and lipophilic balance, the oil-soluble surfactant combination including poly ethylene glycol mono-oleate, about 8 to about 32 percent by weight of at least one water-soluble surfactant of a type and in a quantity to emulsify the mixture with water from the body of water, said at least one water-soluble surfactant comprising cocoamide, about 4 to about 16 percent by weight of a co-solvent for coupling the mixture with the water-soluble surfactant to help emulsify the petrochemical into the body of water, and about zero to about 50 percent by weight water; and

supplying an effective amount of the dispersant onto the body of water at the spill, for dispersing the spill by emulsifying at least some of the petrochemical into the body of water.

2. A method according to claim 1, including supplying the dispersant to the petrochemical spill in an amount of about one part by weight dispersant to about 5 to 100 parts by weight petrochemical.

3. A method according to claim 1, wherein the oil-soluble surfactant combination includes at least one surfactant have a hydrophilic and lipophilic balance averaging about 10 to about 18.

4. A method according to claim 1, including a sufficient amount of said water in the dispersant to result in a viscosity for the dispersant in the range of about 75 to about 200 cP.

5. A method according to claim 1, wherein the water-soluble surfactant further comprises at least one surfactant that is anionic in addition to said cocoamide.

6. A method according to claim 1, wherein the co-solvent is soluble in the petrochemical, in water and in the surfactants of the dispersant.

7. A dispersant for dispersing a petrochemical spill on a body of water, the dispersant comprising:

about 35 to about 85 percent by weight of an oil-soluble surfactant combination of a type and in a quantity to form a mixture with petrochemical from the spill, the oil-soluble surfactant combination comprising a plurality of oil-soluble surfactants which are each non-ionic and have a different hydrophilic and lipophilic balance, the oil-soluble surfactant combination including poly ethylene glycol mono-oleate;

about 8 to about 32 percent by weight of at least one water-soluble surfactant of a type and in a quantity to emulsify the mixture with water from the body of water, said at least one water-soluble surfactant comprising cocoamide;

about 4 to about 16 percent by weight of a non-petroleum co-solvent for coupling the mixture with the water-soluble surfactant to help emulsify the petrochemical into the body of water; and

about zero to about 50 percent by weight water.

8. A dispersant according to claim 7, including a sufficient amount of said water in the dispersant to result in a viscosity for the dispersant in the range of about 75 to about 200 cP.

9. A dispersant according to claim 8, wherein the oil-soluble surfactant combination has a hydrophilic and lipophilic balance averaging about 10 to about 18.

10. A dispersant according to claim 9, wherein the water-soluble surfactant further comprises a surfactant that is anionic in addition to said cocoamide.

11. A dispersant according to claim 7, wherein the co-solvent is soluble in the petrochemical, in water and in the surfactants of the dispersant.

12. A dispersant according to claim 7, wherein the ratio of poly ethylene glycol mono-oleate to all other surfactants in the dispersant is about 5:

1 to 1;

5.

13. A dispersant according to claim 7, wherein the oil-soluble surfactant combination includes poly oxyethylene tallow amine.

14. A dispersant according to claim 13 wherein the oil-soluble surfactant combination includes poly ethoxylated, linear secondary alcohol.

15. A dispersant for dispersing a petrochemical spill on a body of water, the dispersant comprising:

an oil-soluble surfactant combination comprising a plurality of oil-soluble surfactants which are each non-ionic and have a different hydrophilic and lipophilic balance, the oil-soluble surfactant combination comprising a poly ethoxylated surfactant and poly ethylene glycol mono-oleate, the oil-soluble surfactant combination being of a type and in a quantity to form a mixture with petrochemical from the spill;

a water-soluble surfactant combination comprising an anionic surfactant and cocoamide, and being of a type and in a quantity to emulsify the mixture with water from the body of water;

a ratio of poly ethylene glycol mono-oleate to all other surfactants in the dispersant being about 5;

1 to 1;

5; and

a non-petroleum co-solvent for coupling the mixture with the water-soluble surfactant combination to help emulsify the petrochemical into the body of water.