Aqueous injection molding binder composition and molding process

• US 6,262,150 B1
• Filed: 06/20/2000
• Issued: 07/17/2001
• Est. Priority Date: 06/20/2000
• Status: Expired due to Term

• Current Assignee: FRAM Group IP, LLC
• Original Assignee: Honeywell International Inc.
• Inventors: Fanelli, Anthony, Duyckinck, Richard, Behi, Mohammad
• Primary Examiner(s): SANDERS, KRIELLION ANTIONETTE
• Application Number:
  US09/597,136
• Time in Patent Office: 392 Days
• Field of Search: 524/27, 524/405, 524/413, 524/428, 524/430, 524/439, 524/442, 527/300, 106/162
• US Class Current: 524/27
• CPC Class Codes: B22F 1/10 Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
• CPC Class Codes: B22F 1/108 Mixtures obtained by warm mixing
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 3/225 by injection molding
• CPC Class Codes: C04B 35/632 Organic additives
• CPC Class Codes: C04B 35/636 Polysaccharides or derivatives thereof

Abstract

This invention provides a composition and a process for forming sintered, molded articles having improved dimensional stability. More particularly, this invention pertains to a composition having a sugar additive that increases the solids loading potential of the composition and a process for forming injection molded articles therefrom. Increasing the solids loading potential of the composition, enables the formation of metal or ceramic articles attaining about 98-99% of their theoretical maximum density, without cracking or shrinking significantly during sintering.

Claims

1. A composition for forming molded articles comprising:

a) at least one metal powder, at least one ceramic powder, or a combination thereof;

b) a gel forming polysaccharide binder; and

c) a sugar.

2. The composition of claim 1 further comprising a solvent.

3. The composition of claim 1 wherein said at least one ceramic powder is selected from the group consisting of oxides, borides, nitrides, silicides, and carbides of metals and nonmetals, and mixtures thereof.

4. The composition of claim 1 wherein said at least one metal powder is selected from the group consisting of copper, aluminum, gold, titanium, tungsten, tantalum iron, silver, nickel, metal alloys, intermetallic compounds and mixtures thereof.

5. The composition of claim 1 wherein said metal powder comprises stainless steel.

6. The composition of claim 1 wherein the sugar is selected from the group consisting of glucose, sucrose, dextrose and fructose.

7. The composition of claim 1 wherein the sugar comprises glucose.

8. The composition of claim 1 wherein the binder comprises an agaroid.

9. The composition of claim 8 wherein said agaroid is agar.

10. The composition of claim 1 wherein said solvent comprises water.

11. The composition of claim 1 wherein said powder is present in an amount ranging from about 50% to about 92% by weight of the composition.

12. The composition of claim 1 wherein said gel forming binder is present in an amount ranging from about 1.5% to about 10% by weight of the composition.

13. The composition of claim 1 wherein said sugar is present in an amount ranging from about 0.5% to about 6% by weight of the composition.

14. The composition of claim 1 wherein the weight ratio of said binder to said sugar ranges from about 0.2 to about 3.5.

15. The composition of claim 1 further comprising a gel strengthening agent.

16. The composition of claim 1 further comprising a gel strengthening agent selected from the group consisting of calcium borate, potassium borate, magnesium borate, zinc borate and mixtures thereof.

17. A process for forming molded articles comprising:

A) forming a fluid composition comprising;

i) at least one ceramic powder, at least one metal powder, or a combination thereof;

ii) a gel forming polysaccharide binder;

iii) a sugar; and

iv) a solvent;

B) molding the composition under conditions sufficient to form a solid molded article; and

C) sintering the molded article.

18. The process of claim 17 wherein said composition is molded at a temperature ranging from about 80°

C. to about 95°

C.

19. The process of claim 17 wherein said molding is conducted in an injection molding device.

20. The process of claim 17 wherein said molded article is sintered at a temperature ranging from about 1200 °

C. to about 1450°

C.

21. The process of claim 17 wherein said at least one ceramic powder is selected from the group consisting of oxides, borides, nitrides, silicides, and carbides of metals and nonmetals, and mixtures thereof.

22. The process of claim 17 wherein the at least one metal powder is selected from the group consisting of copper, aluminum, gold, silver, nickel, metal alloys, intermetallic compounds and mixtures thereof.

23. The process of claim 17 wherein said powder comprises stainless steel.

24. The process of claim 17 wherein said sugar is selected from the group consisting of glucose, sucrose, dextrose and fructose.

25. The process of claim 17 wherein the sugar comprises glucose.

26. The process of claim 17 wherein said binder comprises an agaroid.

27. The process of claim 17 wherein said binder comprises agar.

28. The process of claim 17 wherein said solvent comprises water.

29. The process of claim 17 wherein said powder is present in the composition in an amount ranging from about 50% to about 92% by weight of the composition.

30. The process of claim 17 wherein said gel forming binder is present in an amount ranging from about 1.5% to about 10% by weight of the composition.

31. The process of claim 17 wherein said sugar is present in an amount ranging from about 0.5% to about 6% by weight of the composition.

32. The process of claim 17 wherein the weight ratio of said binder to said sugar ranges from about 0.2 to about 3.5.

33. The process of claim 17 wherein said composition further comprises a gel strengthening agent.

34. The process of claim 17 wherein said composition further comprises a gel strengthening agent selected from the group consisting of calcium borate, potassium borate, magnesium borate, zinc borate and mixtures thereof.

35. An article produced by the process of claim 17.

36. A process for forming molded articles comprising:

A) forming a fluid composition comprising;

i) at least one ceramic powder, at least one metal powder, or a combination thereof;

ii) a gel forming polysaccharide binder;

iii) a sugar; and

iv) a solvent; and

B) molding the composition under conditions sufficient to form a solid molded article.

37. An article produced by the process of claim 36.