Particles dispersed w/polymer dispersant having liquid soluble and cross-linkable insoluble segments

• US 6,262,152 B1
• Filed: 06/29/1999
• Issued: 07/17/2001
• Est. Priority Date: 10/06/1998
• Status: Expired due to Term

• Current Assignee: DuPont Electronics, Inc. (DuPont de Nemours, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Visscher, Karyn B., Fryd, Michael
• Primary Examiner(s): SELLERS, ROBERT E
• Application Number:
  US09/342,808
• Time in Patent Office: 749 Days
• Field of Search: 523/205, 524/533, 524/90, 524/210, 524/388, 524/389, 524/391, 524/413, 524/430, 524/440, 524/441, 524/548, 524/558, 525/123
• US Class Current: 524/90
• CPC Class Codes: B01J 13/0034 Additives, e.g. in view of promoting stabilisation or peptisation
• CPC Class Codes: B01J 13/0039 Post treatment
• CPC Class Codes: B01J 13/0086 Preparation of sols by physical processes colloid mills B02C
• CPC Class Codes: B01J 13/16 Interfacial polymerisation
• CPC Class Codes: C08G 18/6254 Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
• CPC Class Codes: C08G 18/6283 Polymers of nitrogen containing compounds having carbon-to-carbon double bonds C08G18/6262, C08G18/6266 take precedence
• CPC Class Codes: C09B 67/0013 with polymeric coatings
• CPC Class Codes: C09B 67/0084 Dispersions of dyes
• CPC Class Codes: C09B 67/009 polymeric dispersing agent
• CPC Class Codes: C09D 11/326 characterised by the pigment dispersant
• CPC Class Codes: C09D 17/00 Pigment pastes, e.g. for mixing in paints artists' paints C09D5/06
• CPC Class Codes: C09D 5/027 Dispersing agents anti-settling agents C09D7/45
• CPC Class Codes: C09K 23/16 Amines or polyamines
• CPC Class Codes: C09K 23/54 Silicon compounds

Abstract

Dispersions containing a liquid vehicle (which can be aqueous, semi-aqueous or non-aqueous), organic or inorganic particles (or mixtures) that are insoluble in the liquid vehicle and a polymeric dispersant, preferably a structured polymeric dispersant, having one or more segments soluble in the liquid vehicle and one or more segments insoluble in the liquid vehicle, have improved stability when the insoluble segment(s) contains cross-linking groups which are cross-linked to itself or a cross-linking compound such as a polyfunctional monomer, oligomer or polymer to form an encapsulation network that entraps the particles which are particularly useful for paints or inks in coating and printing applications.

Claims

1. A dispersion of particles in a liquid vehicle, comprising:

(a) a liquid vehicle selected from the group consisting of water, organic solvents and combinations thereof, wherein the vehicle comprises at least 50% by weight of water;

(b) particles that are at least substantially insoluble in the liquid vehicle;

(c) a polymer dispersant having at least one segment soluble in the liquid vehicle and at least one segment insoluble in the liquid vehicle, said insoluble segment having cross-linkable moieties; and

(d) wherein the cross-linkable moieties on the insoluble segment of the polymer dispersant are cross-linked such that the insoluble segment of the polymer dispersant forms a cross-linked polymer matrix with the particles entrapped therein.

2. The dispersion of claim 1, wherein the particle comprises a pigment.

3. The dispersion of claim 1, wherein the cross-linkable moieties on the at least one insoluble segment of the polymer comprise hydroxyl groups and wherein the dispersion further comprises a diisocyante as a cross-linkable component.

4. The dispersion of claim 1, further comprising a cross-linkable component having a cross-linking moiety selected from the group consisting of amine, anhydride, acid, phenolic, hydroxyl, N-methylol, aldehyde, acetoacetoxy, isocyanate, epoxide, ester, isocyanate, aldehyde, activated allyl and water.

5. The dispersion of claim 1, wherein the cross-linkable moieties on the at least one insoluble segment of the polymeric dispersant are selected from the group consisting of epoxy, hydroxyl, anhydride, acid, cyclic carbonate, activated allyl, amine, silane, silicate, silanol, silicone and imine.

6. The dispersion of claim 1, further comprising a catalyst to facilitate cross-linking.

7. The dispersion of claim 6, wherein said catalyst is selected from the group consisting of 2,2,2-diaminobicyclooctane, dibutyltin dilaurate, tributyl amine, trioctyl amine, tridodecyl amine and dimethyldodecyl amine.

8. A dispersion of particles in a liquid vehicle, comprising:

a) a liquid vehicle selected from the group consisting of water, organic solvents and combinations thereof;

b) particles that are at least substantially insoluble in the liquid vehicle;

c) a polymer dispersant having at least one segment soluble in the liquid vehicle and at least one segment insoluble in the liquid vehicle, said insoluble segment having cross-linkable moieties;

d) wherein the cross-linkable moieties on the insoluble segment of the polymer dispersant are cross-linked such that the insoluble segment of the polymer dispersant forms a cross-linked polymer matrix with the particles entrapped therein; and

e) wherein the cross-linkable moieties comprise hydroxyl groups and wherein the dispersion further comprises a diisocyanate as a cross-linkable component.