Compositions having improved ignition resistance

• US 6,262,161 B1
• Filed: 08/12/1999
• Issued: 07/17/2001
• Est. Priority Date: 06/26/1997
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Wevers, Ronald, Kelley, David C., Reynolds, Ian, Field, Arnold W., Cheung, Yunwa W., Guest, Martin J., Van Volkenburgh, William R., Kjellqvist, Jerker B. I., Betso, Stephen R., Remenar, Richard M., Keen, Fiona E.
• Primary Examiner(s): Cain, Edward J.
• Application Number:
  US09/374,097
• Time in Patent Office: 705 Days
• Field of Search: 524/425, 524/430, 524/431, 524/433, 524/436, 524/441, 524/442, 524/444, 524/445, 524/447, 524/449, 524/451
• US Class Current: 524/425
• CPC Class Codes: B32B 27/28 comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
• CPC Class Codes: C08J 2323/08 Copolymers of ethene C08J2323/16 takes precedence
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C08K 13/02 Organic and inorganic ingredients
• CPC Class Codes: C08K 3/01 characterized by their specific function
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 23/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C08L 23/0838 Copolymers of ethene with aromatic monomers
• CPC Class Codes: C08L 2314/06 Metallocene or single site catalysts
• CPC Class Codes: C08L 25/00 Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 25/08 Copolymers of styrene C08L29/08, C08L35/06, C08L55/02 take precedence
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials

Abstract

The present invention relates to compositions having enhanced ignition resistance, comprising:

(A) from about 5 to about 90 percent by weight of at least one substantially random interpolymer;

(B) from about 10 to about 94.9 percent by weight of at least one filler selected from ammonium polyphosphate, magnesium hydroxide, calcium hydroxide, and aluminum trihydrate; and

(C) at least one component selected from;

(1) about 5 to about 50 percent by weight of at least one filler; or

(2) about 0.5 to about 20 percent by weight of at least one metal borate, and, optionally, about 0.5 to about 10 percent by weight of at least one processing aid; or

(3) about 0.1 to about 15 percent by weight of at least one initiator or at least one coupling agent; or

(4) about 0.1 to about 20 percent by weight of at least one hindered amine stabilizer.

Claims

1. A composition comprising

(A) from about 5 to about 90 weight percent by weight of at least one substantially random interpolymer prepared by polymerizing ethylene and/or one or more α

-olefin monomers with one or more vinyl or vinylidene aromatic monomers, and optionally with other polymerizable ethylenically unsaturated monomer(s);

(B) from about 10 to about 94.9 percent by weight of at least one filler selected from ammonium polyphosphate, magnesium hydroxide, calcium hydroxide, and aluminum trihydrate; and

(C) one or more components selected from the group consisting of

(1) about 5 to about 50 weight percent by weight of at least one filler selected from talc, calcium carbonate, glass fibers, marble dust, cement dust, clay, feldspar, silica or glass, fumed silica, silicates, alumina, magnesium oxide, antimony oxide, zinc oxide, barium sulfate, aluminum silicate, calcium silicate, titanium oxides, glass microspheres, mica, clays, wollastonite, and chalk;

(2) about 0.5 to about 20 percent by weight of at least one metal borate selected from the metal borates of Group IIA, and, optionally, about 0.5 to about 10 percent by weight of at least one processing aid selected from the group consisting of polydimethylsiloxane, organopolysiloxanes, tartaric acid, stearic acid, zinc stearic, waxes, and high melt flow polyolefins;

(3) about 0.1 to about 15 percent by weight of at least one initiator or at least one coupling agent selected from the group consisting of organic peroxides, silanes, titanates, zirconates, multifunctional vinyl compounds and organic azides;

(4) about 0.1 to about 20 percent by weight of at least one hindered amine stabilizer;

wherein the amounts of (A), (B) and (C) are based on the total weight of (A), (B) and (C).

2. The composition of claim 1 wherein the interpolymer is prepared by polymerizing

(a) from about 35 to about 99.5 mole percent of ethylene and/or one or more α -olefin monomers;

(b) from about 0.5 to about 65 mole percent of one or more vinyl or vinylidene aromatic monomers; and

(c) optionally other polymerizable ethylenically unsaturated monomer(s).

3. The composition of claim 1 wherein said interpolymer is an interpolymer of ethylene and styrene or an interpolymer of ethylene, styrene and one or more C₃ to C₁₀ α

-olefin monomers.

4. The composition of claim 2 wherein said interpolymer is an interpolymer of ethylene and styrene or an interpolymer of ethylene, styrene and one or more C₃ to C₁₀ α

-olefin monomers.

5. The composition of claim 1 wherein said interpolymer is prepared using a metallocene catalyst and is an interpolymer of ethylene and styrene or an interpolymer of ethylene, styrene and one or more C₃ to C₁₀ α

-olefin monomers.

6. The composition of claim 1 wherein Component (B) is present in an amount of from about 20 to about 80 weight percent and is selected from aluminum trihydrate, magnesium hydroxide, calcium hydroxide, ammonium polyphosphate, and a mixture thereof and wherein Component (C)(1) is present in an amount of from about 5 to about 50 weight percent and is one or more fillers selected from talc, calcium carbonate, barium sulfate, silicates, clay, and a mixture thereof, based on the total weight of the interpolymer(s) and the filler(s).

7. The composition of claim 1 wherein Component (B) is present in an amount of from about 20 to about 80 weight percent and is selected from aluminum trihydrate, magnesium hydroxide, calcium hydroxide, ammonium polyphosphate, and mixtures thereof and wherein Component (C)(2) is present in an amount of from about 0.5 to about 20 weight percent and is zinc borate, and the processing aid is polydimethylsiloxane and/or tartaric acid.

8. The composition of claim 1 wherein Component (B) is present in an amount of from about 20 to about 80 weight percent and is selected from aluminum trihydrate, magnesium hydroxide, calcium hydroxide, ammonium polyphosphate, and mixtures thereof and wherein Component (C)(3) is present in an amount of from about 0.5 to about 10 weight percent and is selected from organic peroxides, silanes, titanates, zirconates, multifunctional vinyl compounds, organic azides, and mixtures thereof.

9. The composition of claim 8 wherein the coupling agent couples at least a portion of at least one filler to at least a portion of at least one interpolymer.

10. The composition of claim 1 wherein Component (B) is present in an amount of from about 20 to about 80 weight percent and is selected from aluminum trihydrate, magnesium hydroxide, calcium hydroxide, ammonium polyphosphate, and mixtures thereof and Component (C)(4) is present in an amount of from about 0.5 to about 10 weight percent.

11. The composition of any one of claims 1-10 comprising from about 0.1 to about 84.9 weight percent of one or more additional polymeric components, based on the total weight of the composition.

12. A fabricated article made from the polymer composition of any one of claims 1-11.

13. The fabricated article of claim 12 in the form of a film or sheet or multilayered structure.

14. The fabricated article of claim 12 in the shape of a floor, wall or ceiling covering.

15. The fabricated article of claim 12 in the form of a foam or in the form of fibers.

16. The fabricated article of claim 12 in the form of a cable, a wire or cable assembly, a junction box, a conduit, a cable tray, a cable support, an electrical union or joint, or an electrical device.

17. The fabricated article of claim 12 made by injection molding, compression molding, extrusion, or blow molding.

18. The fabricated article of claim 12 in which the one or more additional polymeric components are crosslinked.

21. The composition of claims 1-20 which further comprises from about 0.1 to about 10 weight percent oxidized polyethylene.

22. The composition of claim 1 comprising about 5 to about 20 weight percent of an ethylene acrylic acid copolymer, wherein Component (B) is present in an amount of from about 20 to about 80 weight percent and is selected from aluminum trihydrate, magnesium hydroxide, and mixtures thereof and wherein Component (C)(2) is present in an amount of from about 0.5 to about 20 weight percent and is zinc borate, and the processing aid is polydimethylsiloxane and/or tartaric acid.

19. A product made by the process of thermomixing:

(A) from about 5 to about 90 weight percent by weight of at least one substantially random interpolymer prepared by polymerizing one or more α

-olefin monomers with one or more vinyl or vinylidene aromatic monomers, and optionally with other polymerizable ethylenically unsaturated monomer(s);

(B) from about 10 to about 94.9 percent by weight of at least one filler selected from ammonium polyphosphate, magnesium hydroxide, calcium hydroxide, and aluminum trihydrate; and

(C) one or more components selected from the group consisting of

(1) about 5 to about 50 weight percent by weight of at least one filler selected from talc, calcium carbonate, glass fibers, marble dust, cement dust, clay, feldspar, silica or glass, fumed silica, silicates, alumina, magnesium oxide, antimony oxide, zinc oxide, barium sulfate, aluminum silicate, calcium silicate, titanium oxides, glass microspheres, mica, clays, wollastonite, and chalk;

(2) about 0.5 to about 20 percent by weight of at least one metal borate selected from the metal borates of Group IIA, and, optionally, about 0.5 to about 10 percent by weight of at least one processing aid selected from the group consisting of polydimethylsiloxane, organopolysiloxanes, tartaric acid, stearic acid, zinc stearic, waxes, and high melt flow polyolefins;

(3) about 0.1 to about 15 percent by weight of at least one coupling agent or at least one initiator selected from the group consisting of organic peroxides, silanes, titanates, zirconates, multifunctional vinyl compounds and organic azides;

(4) about 0.1 to about 20 percent by weight of at least one hindered amine stabilizer;

wherein the amounts of (A), (B) and (C) are based on the total weight of (A), (B) and (C).

20. A product derived from the mixture comprising:

(A) from about 5 to about 90 weight percent by weight of at least one substantially random interpolymer prepared by polymerizing one or more α

-olefin monomers with one or more vinyl or vinylidene aromatic monomers, and optionally with other polymerizable ethylenically unsaturated monomer(s);

(B) from about 10 to about 94.9 percent by weight of at least one filler selected from ammonium polyphosphate, magnesium hydroxide, calcium hydroxide, and aluminum trihydrate; and

(C) one or more components selected from the group consisting of

(1) about 5 to about 50 weight percent by weight of at least one filler selected from talc, calcium carbonate, glass fibers, marble dust, cement dust, clay, feldspar, silica or glass, fumed silica, silicates, alumina, magnesium oxide, antimony oxide, zinc oxide, barium sulfate, aluminum silicate, calcium silicate, titanium oxides, glass microspheres, mica, clays, wollastonite, and chalk;

(2) about 0.5 to about 20 percent by weight of at least one metal borate selected from the metal borates of Group IIA, and, optionally, about 0.5 to about 10 percent by weight of at least one processing aid selected from the group consisting of polydimethylsiloxane, organopolysiloxanes, tartaric acid, stearic acid, zinc stearic, waxes, and high melt flow polyolefins;

(3) about 0.1 to about 15 percent by weight of at least one initiator or at least one coupling agent selected from the group consisting of organic peroxides, organic azides, silanes, titanates, zirconates, and multifunctional vinyl compounds; and

(4) about 0.1 to about 20 percent by weight of at least one hindered amine stabilizer;

wherein the amounts of (A), (B) and (C) are based on the total weight of (A), (B) and (C).