Process for dry synthesis and continuous separation of a fatty acid methyl ester reaction product

• US 6,262,285 B1
• Filed: 06/24/1999
• Issued: 07/17/2001
• Est. Priority Date: 06/24/1999
• Status: Expired due to Term

• Current Assignee: Crown Iron Works Company (CPM Holdings, Inc.)
• Original Assignee: Crown Iron Works Company (CPM Holdings, Inc.)
• Inventors: McDonald, William M.
• Primary Examiner(s): Carr, Deborah D.
• Application Number:
  US09/339,436
• Time in Patent Office: 754 Days
• Field of Search: 584/216, 584/169
• US Class Current: 554/169
• CPC Class Codes: C11C 1/10 by distillation
• CPC Class Codes: C11C 3/003 by esterification of fatty acids with alcohols C11C3/02 takes precedence

Abstract

A continuous separation of fatty acid methyl esters (FAME) from glycerol in a low pressure dry transesterification process for vegetable oil is provided. Improved purity of the FAME and the glycerol fractions are achieved via the use of continuous decantation so as to thereby eliminate the need for a water wash step for the FAME fraction. Excess methanol from the FAME and the glycerol fractions is readily recovered in a dry vacuum extraction process. Water which has been inadvertently introduced into the process is removed from the recovered excess methanol by desiccant columns equipped with molecular sieves instead of the traditional energy and capital intensive fractionation processes practiced for this purpose.

Claims

1. A low pressure process for the dry synthesis and continuous separation of products from the transesterification of triglycerides, comprising the steps of:

(a) providing a catalyst at a first predetermined rate and providing methanol at a second predetermined rate;

(b) mixing said catalyst and said methanol to form a feed solution;

(c) providing triglycerides at a third predetermined rate;

(d) mixing said triglycerides with said feed solution at a pressure, temperature and rate sufficient to produce a transesterified product having methyl ester and glycerol fractions, each of said fractions having a methanol component;

(e) continuously separating said methyl ester fraction from said glycerol fraction by decantation in a manner so as to produce a dry methyl ester fraction substantially free of glycerol, thereby eliminating washing of glycerol from said dry methyl ester fraction; and

(f) recovering excess methanol from each of said fractions using a dry vacuum system so as to produce a clean methyl ester product from one of said fractions, a crude glycerin product from the other of said fractions and recovered excess methanol substantially free of water from each of said fractions.

2. The process of claim 1 wherein said catalyst is an alkali catalyst.

3. The process of claim 1 further comprising the step of removing any water that may be present in said recovered excess methanol to thereby ensure that said recovered excess methanol remains dry.

4. The process of claim 3 wherein said step of removing any water that may be present in said recovered excess methanol comprises adsorption.

5. The process of claim 4 wherein said adsorption is accomplished using molecular sieves.

6. The process of claim 4 further comprising the step of providing the dry recovered excess methanol for combination with said catalyst and said methanol to form said feed solution.